An efficient generation method and remarkable reactivities of 3-triflyloxybenzyne

Modular synthesis of bis- and tris-1,2,3-triazoles by permutable sequential azide–aryne and azide–alkyne cycloadditions

(2014) Suguru Yoshida et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tandem [4 + 2]/[2 + 2] Cycloaddition Reactions Involving Indene or Benzofurans and Arynes

(2014) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors

(2014) Boris Michel et al.   ORGANIC LETTERS

Three-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSO

(2014) Feng-Lei Liu et al.   ORGANIC LETTERS

Transition-Metal-Free C–S Bond Formation: A Facile Access to Aryl Sulfones from Sodium Sulfinates via Arynes

(2014) Virat G. Pandya et al.   ORGANIC LETTERS

Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes

(2013) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O→Cvinyland N→CvinylTrifluoromethanesulfonyl Migration Reactions

(2013) Xiu-Hua Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Aromatic Compounds by One-Pot Benzyne Generation and Nucleophilic Fluorination

(2013) Takashi Ikawa et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Tandem thia-Fries rearrangement – cyclisation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate benzyne precursors

(2013) Catherine Hall et al.   CHEMICAL COMMUNICATIONS

Synthesis of Diverse Aromatic Oxophosphorus Compounds by the Michaelis–Arbuzov-type Reaction of Arynes

(2013) Suguru Yoshida et al.   CHEMISTRY LETTERS

Generation of Arynes Triggered by Sulfoxide–Metal Exchange Reaction of ortho-Sulfinylaryl Triflates

(2013) Suguru Yoshida et al.   CHEMISTRY LETTERS

Regiocomplementary Cycloaddition Reactions of Boryl- and Silylbenzynes with 1,3-Dipoles: Selective Synthesis of Benzo-Fused Azole Derivatives

(2013) Takashi Ikawa et al.   JOURNAL OF ORGANIC CHEMISTRY

ortho-Selective nucleophilic addition of amines to 3-borylbenzynes: synthesis of multisubstituted anilines by the triple role of the boryl group

(2013) Akira Takagi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Generation of Arynes via Ate Complexes of Arylboronic Esters with an ortho-Leaving Group

(2013) Yuto Sumida et al.   ORGANIC LETTERS

A Closer Look at Aryne Chemistry: Details that Remain Mysterious

(2013) Chunrui Wu et al.   Asian Journal of Organic Chemistry

Catalytic Generation of Arynes and Trapping by Nucleophilic Addition and Iodination

(2012) Toshiyuki Hamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arynes and Cyclohexyne in Natural Product Synthesis

(2012) Christian M. Gampe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Development of an Intramolecular Aryne Ene Reaction and Application to the Formal Synthesis of (±)-Crinine

(2012) David A. Candito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-Silylarynes

(2012) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The hexadehydro-Diels–Alder reaction

(2012) Thomas R. Hoye et al.   NATURE

Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model

(2012) Adam E. Goetz et al.   Nature Chemistry

Use of benzynes for the synthesis of heterocycles

(2012) Anton V. Dubrovskiy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Three-Component Coupling of Arynes and Organic Bromides

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzannulated Bicycles by Three-Component Aryne Reactions

(2011) Kevin M. Allan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines

(2011) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A regioselective synthesis of poly-substituted aryl triflones through self-promoting three component reaction

(2011) Hikaru Yanai et al.   CHEMICAL COMMUNICATIONS

Overturning Indolyne Regioselectivities and Synthesis of Indolactam V

(2011) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Domino Process for Benzyne Preparation: Dual Activation ofo-(Trimethylsilyl)phenols by Nonafluorobutanesulfonyl Fluoride

(2011) Takashi Ikawa et al.   ORGANIC LETTERS

Diversity-oriented synthesis leads to an effective class of bifunctional linchpins uniting anion relay chemistry (ARC) with benzyne reactivity

(2011) A. B. Smith et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Preparation and Regioselective Diels-Alder Reactions of Borylbenzynes: Synthesis of Functionalized Arylboronates

(2010) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Reactions of Highly Substituted Arynes

(2010) Pamela M. Tadross et al.   ORGANIC LETTERS

Decoupling Deprotonation from Metalation: Thia-Fries Rearrangement

(2008) Alan M. Dyke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride

(2008) Tsuneyuki Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY