Journal
CHEMISTRY LETTERS
Volume 43, Issue 1, Pages 116-118Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130899
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Funding
- MEXT, Japan
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Arynes were efficiently generated from readily available ortho-sulfinylaryl triflates by the treatment with phenylmagnesium bromide in tetrahydrofuran at -78 degrees C. Aryne generation was initiated by a rapid sulfoxide-metal exchange reaction, followed by the immediate elimination of the ortho-OTf group. Various arynophiles efficiently reacted with arynes generated by this method within 10 min, providing the corresponding adducts in high yields.
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