Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

(2014) Chunfa Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion

(2014) Feng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Reevaluation of the Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation Supported by the Crystalline Sponge Method for X-ray Analysis

(2014) Ekaterina V. Vinogradova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

(2014) Jie Sheng et al.   CHEMICAL COMMUNICATIONS

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

(2014) Quentin Lefebvre et al.   CHEMICAL COMMUNICATIONS

Catalytic enantioselective trifluoromethylthiolation of oxindoles using shelf-stable N-(trifluoromethylthio)phthalimide and a cinchona alkaloid catalyst

(2014) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

Electrophilic Trifluoromethylthiolation of Carbonyl Compounds

(2014) Sébastien Alazet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF3

(2014) Pavlo Nikolaienko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion

(2014) Xi Wang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides

(2014) Sheng-Qing Zhu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Mediated Trifluoromethylthiolation of α-Diazoesters

(2014) Mingyou Hu et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Trifluoromethylthiolation of Benzylic C–H Bonds via Nondirected Oxidative C(sp3)–H Activation

(2014) Chao Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds

(2014) Chunfa Xu et al.   ORGANIC LETTERS

Copper-Catalyzed Synthesis of α-Trifluoromethylthio-Substituted Ketones

(2014) Yangjie Huang et al.   ORGANIC LETTERS

In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles

(2014) Xing-Li Zhu et al.   ORGANIC LETTERS

Silver-Mediated Radical Aryltrifluoromethylthiolaton of Activated Alkenes

(2014) Feng Yin et al.   ORGANIC LETTERS

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

(2014) Grégory Danoun et al.   Chemical Science

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

(2013) Xueqiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation

(2013) Teerawut Bootwicha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

(2013) Grégory Landelle et al.   Beilstein Journal of Organic Chemistry

Generation of 4-((trifluoromethyl)thio)-2H-benzo[e][1,2]thiazine 1,1-dioxides via a reaction of trifluoromethanesulfanylamide with 2-(2-alkynyl)benzenesulfonamide

(2013) Qing Xiao et al.   CHEMICAL COMMUNICATIONS

Synthesis of 3-((trifluoromethyl)thio)indoles via a reaction of 2-alkynylaniline with trifluoromethanesulfanylamide

(2013) Jie Sheng et al.   CHEMICAL COMMUNICATIONS

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Copper-Catalyzed Trifluoromethyl Thiolation-Mild and Efficient Synthesis of Trifluoromethyl Thioethers

(2013) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations

(2013) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

(2013) Yu-Dong Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Convenient Metal-Free Reagent for the Generation and Capture of Trifluoromethanethiol

(2013) Shi-Guang Li et al.   ORGANIC LETTERS

Electrophilic Trifluoromethylthiolation of Allylsilanes with Trifluoromethanesulfanamide

(2013) Jianbo Liu et al.   ORGANIC LETTERS

Silver-mediated fluorination, trifluoromethylation, and trifluoromethylthiolation of arynes

(2013) Kung-Pern Wang et al.   Chemical Science

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequential Electrophilic Trifluoromethanesulfanylation–Cyclization of Tryptamine Derivatives: Synthesis of C(3)-Trifluoromethanesulfanylated Hexahydropyrrolo[2,3-b]indoles

(2012) Yi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Promoted Sulfenylation of sp2 C–H Bonds

(2012) Ly Dieu Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

(2011) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes

(2009) Aurélien Ferry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS