Basic CuCO3/ligand as a new catalyst for 'on water' borylation of Michael acceptors, alkenes and alkynes: application to the efficient asymmetric synthesis of β-alcohol type sitagliptin side chain

Investigation of “On Water” Conditions Using a Biphasic Fluidic Platform

(2012) Sonia Mellouli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron Containing Compounds as Protease Inhibitors

(2012) Reem Smoum et al.   CHEMICAL REVIEWS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper(II)-Catalyzed Silyl Conjugate Addition to α,β-Unsaturated Conjugated Compounds: Brønsted Base-Assisted Activation of Si–B Bond in Water

(2012) Joseph A. Calderone et al.   ORGANIC LETTERS

Unexpected Copper(II) Catalysis: Catalytic Amine Base Promoted β-Borylation of α,β-Unsaturated Carbonyl Compounds in Water

(2012) Steven B. Thorpe et al.   ORGANIC LETTERS

Copper-Catalyzed Double Borylation of Silylacetylenes: Highly Regio- and Stereoselective Synthesis of Syn-Vicinal Diboronates

(2012) Ho-Young Jung et al.   ORGANIC LETTERS

DFT Studies on the Mechanisms of the Platinum-Catalyzed Diboration of Acyclic α,β-Unsaturated Carbonyl Compounds

(2012) Bowen Liu et al.   ORGANOMETALLICS

Novel and enantioselective syntheses of (R)- and (S)-3-hydroxy-4-(2,4,5-trifluorophenyl)butanoic acid: a synthon for sitagliptin and its derivatives

(2012) Meryem Fistikci et al.   TETRAHEDRON

Asymmetric synthesis of (−)-(R)-sitagliptin

(2012) Stephen G. Davies et al.   TETRAHEDRON LETTERS

Copper-Catalyzed Borylation Reactions of Alkynes and Arynes

(2011) Hiroto Yoshida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Synthesis of Diboranes(4)

(2011) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sitagliptin Manufacture: A Compelling Tale of Green Chemistry, Process Intensification, and Industrial Asymmetric Catalysis

(2011) Aman A. Desai   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Green chemistry oriented organic synthesis in water

(2011) Marc-Olivier Simon et al.   CHEMICAL SOCIETY REVIEWS

The Boron Imprint into Combined Catalytic Organic Reactions

(2011) Amadeu Bonet et al.   CURRENT ORGANIC CHEMISTRY

Synthesis of Copper Pigments, Malachite and Verdigris: Making Tempera Paint

(2011) Sally D. Solomon et al.   JOURNAL OF CHEMICAL EDUCATION

Structure and Reactivity of a Preactivated sp2–sp3Diboron Reagent: Catalytic Regioselective Boration of α,β-Unsaturated Conjugated Compounds

(2011) Ming Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Copper-catalyzed boration of activated alkynes. Chiral boranes via a one-pot copper-catalyzed boration and reduction protocol

(2011) Ho-Young Jung et al.   TETRAHEDRON

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligandless Copper-Catalyzed β-Boration of α,β-Unsaturated Compounds in Aqueous Solution

(2010) Hee-Sung Chea et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water”

(2010) Richard N. Butler et al.   CHEMICAL REVIEWS

Natural and Synthetic Small Boron-Containing Molecules as Potential Inhibitors of Bacterial and Fungal Quorum Sensing

(2010) Valery M. Dembitsky et al.   CHEMICAL REVIEWS

Boron Conjugate Additions on Electron Deficient Olefins Towards Selective 1,3- Difunctionalization

(2010) Amadeu Bonet et al.   CURRENT ORGANIC CHEMISTRY

The asymmetric synthesis of Sitagliptin, a selective dipeptidyl peptidase IV inhibitor for the treatment of type 2 diabetes

(2010) Feng Liu et al.   JOURNAL OF CHEMICAL RESEARCH-S

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Copper-Catalyzed Hydroboration of Styrenes

(2009) Dongwan Noh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Organic Synthesis “On Water”

(2009) Arani Chanda et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric induction on β-boration of α,β-unsaturated compounds: an inexpensive approach

(2009) Vanesa Lillo et al.   DALTON TRANSACTIONS

Therapeutic potential of boron-containing compounds

(2009) Stephen J Baker et al.   Future Medicinal Chemistry

Aerobic oxidative iodination of ketones catalysed by sodium nitrite “on water” or in a micelle-based aqueous system

(2009) Gaj Stavber et al.   GREEN CHEMISTRY

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Higher Reactivity of B2cat2versus B2pin2in Copper(I)-Catalyzed Alkene Diboration Reactions

(2008) Li Dang et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS

α-Amido boronic acids: A synthetic challenge and their properties as serine protease inhibitors

(2007) Donald S. Matteson   MEDICINAL RESEARCH REVIEWS