Journal
ORGANIC LETTERS
Volume 11, Issue 3, Pages 653-655Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802759j
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Funding
- Grant-in-Aid for Young Scientists (B)
- Grant-in-Aid for Scientific Research (A)
- Targeted Proteins Research Program of the Ministry of Education. Culture, Sports, Science, and Technology, Japan
- JSPS fellowship
- Grants-in-Aid for Scientific Research [20249002] Funding Source: KAKEN
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Chiral diether ligand-controlled asymmetric conjugate addition of a lithium amide to cyclopentenecarboxylate and subsequent in situ alkylation gave a chiral cyclopentane derivative bearing a quaternary carbon with high enantio- and diastereoselectivity. The cyclopentane derivative was converted successfully to (-)-aspidospermidine.
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