A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides

Palladium-Catalyzed Direct Arylation of Methyl Sulfoxides with Aryl Halides

(2013) Tiezheng Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Direct Intermolecular α-Arylation of Amides with Aryl Chlorides

(2013) Bing Zheng et al.   ORGANIC LETTERS

Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

(2013) Nicholas C. Bruno et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct α-Arylation of Methyl Sulfones with Aryl Bromides

(2013) Bing Zheng et al.   ORGANIC LETTERS

Selective Palladium-Catalyzed Suzuki-Miyaura Reactions of Polyhalogenated Heteroarenes

(2012) Renzo Rossi et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Cross-Coupling of Aryl Triflates to the Benzylic Position of Benzylamines

(2012) Genette I. McGrew et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 3-Fluoro-3-aryl Oxindoles: Direct Enantioselective α Arylation of Amides

(2012) Linglin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts

(2012) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel oxoisoaporphine-based inhibitors of acetyl- and butyrylcholinesterase and acetylcholinesterase-induced beta-amyloid aggregation

(2012) Huang Tang et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Addressing Challenges in Palladium-Catalyzed Cross-Coupling Reactions Through Ligand Design

(2012) Rylan J. Lundgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Class of P,N-Type “PhMezole-phos” Ligands: Applications in Palladium-Catalyzed Suzuki Coupling of Aryl Chlorides

(2012) Shun Man Wong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C(sp3)–H Arylation of Diarylmethanes at Room Temperature: Synthesis of Triarylmethanes via Deprotonative-Cross-Coupling Processes

(2012) Jiadi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Methylene C(sp3)–H Bond Activation with a Pd(II) Catalyst

(2012) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Synthesis of Oxindoles by Potassium tert-Butoxide-Promoted Intramolecular α-Arylation

(2012) Astrid Beyer et al.   ORGANIC LETTERS

Synthesis of Enantiomerically Enriched 3-Amino-2-oxindoles through a Palladium-Mediated Asymmetric Intramolecular Arylation of α-Ketimino Amides

(2012) Päivi Tolstoy et al.   ORGANIC LETTERS

Copper-Catalyzed Arylation of o-Bromoanilides: Highly Flexible Synthesis of Hexahydropyrroloindole Alkaloids

(2012) Yongyun Zhou et al.   ORGANIC LETTERS

Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions

(2012) Nicholas C. Bruno et al.   Chemical Science

Additive effects on palladium-catalyzed deprotonative-cross-coupling processes (DCCP) of sp3C–H bonds in diarylmethanes

(2012) Ana Bellomo et al.   Chemical Science

The Growing Impact of Catalysis in the Pharmaceutical Industry

(2011) Carl A. Busacca et al.   ADVANCED SYNTHESIS & CATALYSIS

Total Synthesis of the Protein Phosphatase 2A Inhibitor Lactodehydrothyrsiferol

(2011) Dane J. Clausen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and synthesis of 6,6-fused heterocyclic amides as raf kinase inhibitors

(2011) Savithri Ramurthy et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

(2011) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Efficient Intramolecular Hydroarylation Catalysed by BiIII Triflate

(2011) Bastien Cacciuttolo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct, Metal-Free Amination of Heterocyclic Amides/Ureas with NH-Heterocycles and N-Substituted Anilines in POCl3

(2011) Xiaohu Deng et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Allylic Substitution with (η6-Arene–CH2Z)Cr(CO)3-Based Nucleophiles

(2011) Jiadi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Palladium Catalyzed Asymmetric Addition of Oxindoles and Allenes: An Atom-Economical Versatile Method for the Construction of Chiral Indole Alkaloids

(2011) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarboxylative Arylation of Potassium Cyanoacetate: Synthesis of α-Diaryl Nitriles from Aryl Halides

(2011) Pui Yee Yeung et al.   ORGANIC LETTERS

Synthesis of ChiralN-Heterocyclic Carbene Ligands with Rigid Backbones and Application to the Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides

(2011) Lantao Liu et al.   ORGANIC LETTERS

Efficient cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by a palladium-indolylphosphine complex

(2011) Pui Yee Yeung et al.   TETRAHEDRON LETTERS

Use of precatalysts greatly facilitate palladium-catalyzed alkynylations in batch and continuous-flow conditions

(2011) Wei Shu et al.   Chemical Science

Fischer Indole Synthesis with Organozinc Reagents

(2010) Benjamin A. Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Polyarylated Methanes through Cross-Coupling of Tricarbonylchromium-Activated Benzyllithiums

(2010) Genette I. McGrew et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Inherently chiral concave molecules—from synthesis to applications

(2010) Agnieszka Szumna   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct Arylation of Heteroarenes with Aryl Mesylates

(2010) Chau Ming So et al.   CHEMISTRY-A EUROPEAN JOURNAL

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Cross-Coupling of C(sp3)-H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis

(2010) Masayuki Wasa et al.   ISRAEL JOURNAL OF CHEMISTRY

Catalytic Enantioselective Construction of β-Quaternary Carbons via a Conjugate Addition of Cyanide to β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds

(2010) Yuta Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Intramolecular Cyanoamidation: (+)-Horsfiline, (−)-Coerulescine, and (−)-Esermethole

(2010) Venkata Jaganmohan Reddy et al.   ORGANIC LETTERS

Highly Chemo- and Enantioselective Synthesis of 3-Allyl-3-aryl Oxindoles via the Direct Palladium-Catalyzed α-Arylation of Amides

(2010) Xinjun Luan et al.   ORGANIC LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Cross-Coupling of Aryl Halides Using Organotitanium Nucleophiles

(2009) Hang Wai Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Michael and Mannich Reactions of 3-Aryloxindoles

(2009) Rongjun He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure–activity studies of echinomycin antibiotics against drug-resistant and biofilm-forming Staphylococcus aureus and Enterococcus faecalis

(2009) Aaron M. Socha et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Asymmetric construction of quaternary stereocenters by direct organocatalytic amination of 3-substituted oxindoles

(2009) Zi-Qing Qian et al.   CHEMICAL COMMUNICATIONS

Organocatalytic asymmetric allylic alkylation of oxindoles with Morita–Baylis–Hillman carbonates

(2009) Kun Jiang et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Enantioselective α-Arylation and α-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand

(2009) Alexander M. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of SM-130686 Based on the Development of Asymmetric Cu(I)F Catalysis To Access 2-Oxindoles Containing a Tetrasubstituted Carbon

(2009) Daisuke Tomita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thiourea-Catalyzed Highly Enantio- and Diastereoselective Additions of Oxindoles to Nitroolefins: Application to the Formal Synthesis of (+)-Physostigmine

(2009) Tommy Bui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Homodinuclear Mn(III)2−Schiff Base Complex for Catalytic Asymmetric 1,4-Additions of Oxindoles to Nitroalkenes

(2009) Yuko Kato et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective and Organocatalytic α-Amination of 2-Oxindoles

(2009) Liang Cheng et al.   ORGANIC LETTERS

Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products

(2009) Barry Trost et al.   SYNTHESIS-STUTTGART

The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3and PCy3as Ligands

(2008) Gregory C. Fu   ACCOUNTS OF CHEMICAL RESEARCH

Alkaloids fromDaphniphyllum oldhami

(2008) Shu-Zhen Mu et al.   JOURNAL OF NATURAL PRODUCTS

Cyclosporins fromMycelium sterilaeMS 2929

(2008) Marek Kuzma et al.   JOURNAL OF NATURAL PRODUCTS

An Improved System for the Palladium-Catalyzed Borylation of Aryl Halides with Pinacol Borane

(2008) Kelvin L. Billingsley et al.   JOURNAL OF ORGANIC CHEMISTRY

Orthogonal Pd- and Cu-Based Catalyst Systems for C- and N-Arylation of Oxindoles

(2008) Ryan A. Altman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Meerwein−Eschenmoser Claisen Rearrangement: Asymmetric Synthesis of Allyl Oxindoles

(2008) Elizabeth C. Linton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Matching the Chirality of Monodentate N-Heterocyclic Carbene Ligands: A Case Study on Well-Defined Palladium Complexes for the Asymmetric α-Arylation of Amides

(2008) Xinjun Luan et al.   ORGANIC LETTERS

Palladium-Catalyzed α-Arylation of Oxindoles

(2008) Matthew J. Durbin et al.   ORGANIC LETTERS

Enantioselective Synthesis of 3,3-Disubstituted Oxindoles through Pd-Catalyzed Cyanoamidation

(2008) Yoshizumi Yasui et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

(2008) Fumitoshi Kakiuchi et al.   SYNTHESIS-STUTTGART