Journal
TETRAHEDRON
Volume 68, Issue 29, Pages 5824-5828Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.05.014
Keywords
Asymmetric epoxidation; Asymmetric hydroxylation; Hydrogen peroxide; Iodobenzene diacetate; Chiral iron porphyrins; Water-soluble iron porphyrins; Styrenes
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The asymmetric epoxidation of styrene derivatives by H2O2 (or UHP) to give optically active epoxides (ee up to 81%) and hydroxylation of alkanes to give optically active secondary alcohols (ee up to 78%) were carried out in methanol and water using chiral water-soluble iron porphyrins as catalysts. (C) 2012 Elsevier Ltd. All rights reserved.
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