Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities

Kinetic Mechanism of Phenylalanine Hydroxylase: Intrinsic Binding and Rate Constants from Single-Turnover Experiments

(2013) Kenneth M. Roberts et al.   BIOCHEMISTRY

Intermediate P* from Soluble Methane Monooxygenase Contains a Diferrous Cluster

(2013) Rahul Banerjee et al.   BIOCHEMISTRY

Chiral Iron Catalysts for Asymmetric Synthesis

(2013) Kovuru Gopalaiah   CHEMICAL REVIEWS

Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide

(2013) Hassan Srour et al.   COORDINATION CHEMISTRY REVIEWS

The FeIII(H2O2) Complex as a Highly Efficient Oxidant in Sulfoxidation Reactions: Revival of an Underrated Oxidant in Cytochrome P450

(2013) Binju Wang et al.   Journal of Chemical Theory and Computation

Peroxidase activity of a myoglobin mutant with three distal histidines forming a metal-binding site: Implications for the cross-reactivity of cytochrome c oxidase

(2013) Ying-Wu Lin et al.   JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC

Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts

(2013) Olaf Cussó et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of High-Spin and Low-Spin Nonheme FeIII–OOH Complexes in O–O Bond Homolysis and H-Atom Abstraction Reactivities

(2013) Lei V. Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rate-Determining Water-Assisted O–O Bond Cleavage of an FeIII-OOH Intermediate in a Bio-inspired Nonheme Iron-Catalyzed Oxidation

(2013) Williamson N. Oloo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic studies of an unprecedented enzyme-catalysed 1,2-phosphono-migration reaction

(2013) Wei-chen Chang et al.   NATURE

Nonheme Iron Oxidant Formed in the Presence of H2O2 and Acetic Acid Is the Cyclic Ferric Peracetate Complex, Not a Perferryloxo Complex

(2013) Yong Wang et al.   ACS Catalysis

Molecularly enlarged S,S-BnTsDPEN ligands for iron-catalyzed asymmetric olefin epoxidation reactions using hydrogen peroxide

(2013) Vital A. Yazerski et al.   Catalysis Science & Technology

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non-Heme Iron Catalysts

(2012) Bin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

[FeIV═O(TBC)(CH3CN)]2+: Comparative Reactivity of Iron(IV)-Oxo Species with Constrained Equatorial Cyclam Ligation

(2012) Samuel A. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation

(2012) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes

(2012) Kyung-Bin Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible O–O Bond Scission of Peroxodiiron(III) to High-Spin Oxodiiron(IV) in Dioxygen Activation of a Diiron Center with a Bis-tpa Dinucleating Ligand as a Soluble Methane Monooxygenase Model

(2012) Masahito Kodera et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective water-soluble iron–porphyrin-catalyzed epoxidation with aqueous hydrogen peroxide and hydroxylation with iodobenzene diacetate

(2012) Paul Le Maux et al.   TETRAHEDRON

Asymmetric vanadium- and iron-catalyzed oxidations: new mild (R)-modafinil synthesis and formation of epoxides using aqueous H2O2 as a terminal oxidant

(2012) Kerstin A. Stingl et al.   TETRAHEDRON

Asymmetric Epoxidations with H2O2 on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study

(2012) Oleg Y. Lyakin et al.   ACS Catalysis

Dioxygen Activation in Soluble Methane Monooxygenase

(2011) Christine E. Tinberg et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones

(2011) Mei Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Mechanistic Studies of Reactions of Peroxodiiron(III) Intermediates in T201 Variants of Toluene/o-Xylene Monooxygenase Hydroxylase

(2011) Woon Ju Song et al.   BIOCHEMISTRY

A new efficient ironcatalyst for olefinepoxidation with hydrogen peroxide

(2011) Elena A. Mikhalyova et al.   CHEMICAL COMMUNICATIONS

Application of Designed Enzymes in Organic Synthesis

(2011) Gernot A. Strohmeier et al.   CHEMICAL REVIEWS

Enantioenriched Compounds via Enzyme-Catalyzed Redox Reactions

(2011) Mélanie Hall et al.   CHEMICAL REVIEWS

A combined experimental and computational study on the sulfoxidation by high-valent iron bispidine complexes

(2011) Madhavan Jaccob et al.   DALTON TRANSACTIONS

Iron Coordination Chemistry of N2Py2 Ligands Substituted by Carboxylic Moieties and Their Impact on Alkene Oxidation Catalysis

(2011) Frédéric Oddon et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Scandium Ion-Enhanced Oxidative Dimerization andN-Demethylation ofN,N-Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex

(2011) Jiyun Park et al.   INORGANIC CHEMISTRY

Biocatalysis as an alternative for the production of chiral epoxides: A comparative review

(2011) Hui Lin et al.   JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC

Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones

(2011) Yasuhiro Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Topology Effect on the Reactivity of a Mononuclear Nonheme Iron(IV)-Oxo Complex in Oxygenation Reactions

(2011) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex

(2011) Jiyun Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalysis using iron complexes – ‘Ruthenium Lite’?

(2011) Muftah Darwish et al.   Catalysis Science & Technology

Single Turnover Kinetics of Tryptophan Hydroxylase: Evidence for a New Intermediate in the Reaction of the Aromatic Amino Acid Hydroxylases

(2010) Jorge Alex Pavon et al.   BIOCHEMISTRY

Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives

(2010) Giorgio De Faveri et al.   CHEMICAL SOCIETY REVIEWS

Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

(2010) Olga V. Makhlynets et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Halogenation of Alkanes: Modeling of Nonheme Halogenases by Experiment and DFT Calculations

(2010) Peter Comba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Uses of Iron Catalysts in Organic Reactions

(2010) Liu et al.   CURRENT ORGANIC CHEMISTRY

Catalytic enantioselective epoxidation of olefins by chiral mono-faced strapped porphyrin with nitrogen blocking ligand

(2010) Qizhi Ren et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Chiral "basket handle" binaphthyl porphyrins: synthesis, catalytic epoxidation and NMR conformational studies

(2010) Eric Rose et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+

(2010) Yuma Morimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Million-fold activation of the [Fe2(µ-O)2] diamond core for C–H bond cleavage

(2010) Genqiang Xue et al.   Nature Chemistry

Definition of the intermediates and mechanism of the anticancer drug bleomycin using nuclear resonance vibrational spectroscopy and related methods

(2010) L. V. Liu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Sustainability in Catalysis - Concept or Contradiction?

(2010) Bernd Plietker   SYNLETT

Water as an Oxygen Source in the Generation of Mononuclear Nonheme Iron(IV) Oxo Complexes

(2009) Yong-Min Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes

(2009) Eric J. Klinker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Measurement of Intrinsic Rate Constants in the Tyrosine Hydroxylase Reaction

(2009) Bekir E. Eser et al.   BIOCHEMISTRY

Reductive elimination of superoxide: Structure and mechanism of superoxide reductases

(2009) Ana Filipa Pinto et al.   BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS

P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations

(2009) Sason Shaik et al.   CHEMICAL REVIEWS

Contrasting Effects of Axial Ligands on Electron-Transfer Versus Proton-Coupled Electron-Transfer Reactions of Nonheme Oxoiron(IV) Complexes

(2009) Shunichi Fukuzumi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Epoxidation of Terminal Olefins with Binaphthyl Strapped Porphyrin Catalysts: (-( Stacking Interaction and Steric Effects on the Enantioselectivities

(2009) Qizhi REN et al.   CHINESE JOURNAL OF CHEMISTRY

Contrastingcis andtrans Effects on the Reactivity of Nonheme Oxoiron(IV) Complexes

(2008) Yuming Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Asymmetric Olefincis-Dihydroxylation with 97 % Enantiomeric Excess

(2008) Ken Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A chiral iron-sexipyridine complex as a catalyst for alkene epoxidation with hydrogen peroxide

(2008) Ho-Lun Yeung et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts

(2008) O. Andrea Wong et al.   CHEMICAL REVIEWS

Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

(2008) Arkaitz Correa et al.   CHEMICAL SOCIETY REVIEWS

Biomimetic Iron-Catalyzed Asymmetric Epoxidation of Aromatic Alkenes by Using Hydrogen Peroxide

(2008) Feyissa Gadissa Gelalcha et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Hydrogenation, Hydride Transfer, and Hydrosilylation: An Alternative to Precious-Metal Complexes?

(2008) Sylvain Gaillard et al.   ChemSusChem

Asymmetric Epoxidation of Electron-Deficient Olefins

(2008) David Diez et al.   CURRENT ORGANIC SYNTHESIS

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

Further insights into the mechanism of the reaction of activated bleomycin with DNA

(2008) M. S. Chow et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA