Asymmetric one-pot reactions using heterogeneous chemical catalysis: recent steps towards sustainable processes

Integration of aerobic oxidation and intramolecular asymmetric aza-Friedel–Crafts reactions with a chiral bifunctional heterogeneous catalyst

(2017) Hong-Gang Cheng et al.   Chemical Science

9-Amino(9-deoxy) epi -cinchona alkaloid-tethered aluminium phosphonate architectures for heterogeneous cooperative catalysis: asymmetric aldol and double-Michael cascade reaction

(2017) Guangxin Xie et al.   Molecular Catalysis

Enantioselective tandem reaction over a site-isolated bifunctional catalyst

(2016) Jianyou Xu et al.   CHEMICAL COMMUNICATIONS

Harnessing the Versatility of Continuous-Flow Processes: Selective and Efficient Reactions

(2016) István M. Mándity et al.   CHEMICAL RECORD

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

A Cinchona Alkaloid-Functionalized Mesostructured Silica for Construction of Enriched Chiral β-Trifluoromethyl-β-Hydroxy Ketones over An Epoxidation-Relay Reduction Process

(2016) Cuibao Li et al.   Chemistry-An Asian Journal

Highly selective multifunctional nanohybrid catalysts for the one-pot synthesis of α,β-epoxy-chalcones

(2016) Dana-Georgiana Crivoi et al.   JOURNAL OF CATALYSIS

Diastereoselective synthesis of isoxazolidines and spiroisoxazolidines via catalytic 1,3-dipolar cycloaddition reactions in the presence of Fe 3 O 4 - l -proline nanoparticles as a magnetic organocatalyst

(2016) Javad Safaei-Ghomi et al.   TETRAHEDRON LETTERS

A Polymer-Coated Rhodium/Diamine-Functionalized Silica for Controllable Reaction Switching in Enantioselective Tandem Reduction–Lactonization of Ethyl 2-Acylarylcarboxylates

(2016) Lingyu Kong et al.   ACS Catalysis

Integrated Heterogeneous Metal/Enzymatic Multiple Relay Catalysis for Eco-Friendly and Asymmetric Synthesis

(2016) Carlos Palo-Nieto et al.   ACS Catalysis

Yolk–shell-structured mesoporous silica: a bifunctional catalyst for nitroaldol–Michael one-pot cascade reaction

(2016) Juzeng An et al.   Catalysis Science & Technology

Cyclopalladated Azo-linked Porous Polymers in C-C Bond Forming Reactions

(2016) Chao Xu et al.   ChemistrySelect

One-pot Selective Dihydroxylation of Limonene Combining Metal and Enzyme Catalysis

(2016) Chiara Palumbo et al.   ChemistrySelect

Integrated Process of Aerobic Oxidation-Olefination-Asymmetric CC Bond Formation Catalyzed by Robust Heterogeneous Gold/Palladium and Chirally Modified Rhodium Nanoparticles

(2015) Hiroyuki Miyamura et al.   ADVANCED SYNTHESIS & CATALYSIS

The Use of Porous Palladium(II)-polyimine in Cooperatively- catalyzed Highly Enantioselective Cascade Transformations

(2015) Chao Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

l-Proline-functionalized Fe3O4nanoparticles as a novel magnetic chiral catalyst for the direct asymmetric Mannich reaction

(2015) Javad Safaei-Ghomi et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Advances in Immobilized Organocatalysts for the Heterogeneous Asymmetric Direct Aldol Reactions

(2015) Mihály Bartók   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Heterogeneous Chemoenzymatic Catalyst Combinations for One-Pot Dynamic Kinetic Resolution Applications

(2015) Otto Långvik et al.   ChemCatChem

One-pot relay reduction–isomerization of β-trifluoromethylated-α,β-unsaturated ketones to chiral β-trifluoromethylated saturated ketones over combined catalysts in aqueous medium

(2015) Xuelin Xia et al.   GREEN CHEMISTRY

Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations

(2015) Tanyu Cheng et al.   GREEN CHEMISTRY

Chemoenzymatic Dynamic Kinetic Resolution: A Powerful Tool for the Preparation of Enantiomerically Pure Alcohols and Amines

(2015) Oscar Verho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined heterogeneous metal/organic catalysts for eco-friendly synthesis

(2015) Armando Córdova   PURE AND APPLIED CHEMISTRY

Asymmetric Organocatalysis in Continuous Flow: Opportunities for Impacting Industrial Catalysis

(2015) Iuliana Atodiresei et al.   ACS Catalysis

Three consecutive steps over the chirally modified Pt surface: asymmetric catalytic cascade reaction of 2-nitrophenylpyruvates

(2015) György Szőllősi et al.   Catalysis Science & Technology

One-pot synthesis of (R)-2-acetoxy-1-indanone from 1,2-indanedione combining metal catalyzed hydrogenation and chemoenzymatic dynamic kinetic resolution

(2015) Otto Långvik et al.   Catalysis Science & Technology

Pt—cinchonidine catalyzed asymmetric catalytic cascade reaction of 2-nitrophenylpyruvates in flow system

(2015) Lenke Kovács et al.   Journal of Flow Chemistry

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Heterogeneous Synergistic Catalysis for Asymmetric Cascade Transformations

(2014) Luca Deiana et al.   ADVANCED SYNTHESIS & CATALYSIS

Combined Heterogeneous Metal/Chiral Amine: Multiple Relay Catalysis for Versatile Eco-Friendly Synthesis

(2014) Luca Deiana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multisite Organic-Inorganic Hybrid Catalysts for the Direct Sustainable Synthesis of GABAergic Drugs

(2014) Antonio Leyva-Pérez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Site-Isolated Organoruthenium-/Organopalladium-Bifunctionalized Periodic Mesoporous Organosilica Catalyzes Cascade Asymmetric Transfer Hydrogenation and Suzuki Cross-Coupling

(2014) Dacheng Zhang et al.   ChemCatChem

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Asymmetric Allylation of Ketones and Subsequent Tandem Reactions Catalyzed by a Novel Polymer-Supported Titanium-BINOLate Complex

(2014) Jagjit Yadav et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hollow-Shell-Structured Nanospheres: A Recoverable Heterogeneous Catalyst for Rhodium-Catalyzed Tandem Reduction/Lactonization of Ethyl 2-Acylarylcarboxylates to Chiral Phthalides

(2014) Rui Liu et al.   Chemistry-An Asian Journal

Combining the ‘two worlds’ of chemocatalysis and biocatalysis towards multi-step one-pot processes in aqueous media

(2014) Harald Gröger et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Chemoenzymatic Dynamic Kinetic Resolution of Primary Amines Using a Recyclable Palladium Nanoparticle Catalyst Together with Lipases

(2014) Karl P. J. Gustafson et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient and Highly Enantioselective Aerobic Oxidation–Michael–Carbocyclization Cascade Transformations by Integrated Pd(0)-CPG Nanoparticle/Chiral Amine Relay Catalysis

(2014) Armando Córdova et al.   SYNTHESIS-STUTTGART

Convergent Catalysis: Asymmetric Synthesis of Dihydroquinolines Using a Combined Metal Catalysis and Organocatalysis Approach

(2014) Magnus Rueping et al.   ACS Catalysis

Cascade Reactions Catalyzed by Bionanostructures

(2014) Marco Filice et al.   ACS Catalysis

l-Proline-Grafted Mesoporous Silica with Alternating Hydrophobic and Hydrophilic Blocks to Promote Direct Asymmetric Aldol and Knoevenagel–Michael Cascade Reactions

(2014) Zhe An et al.   ACS Catalysis

Combination of Asymmetric Organo- and Biocatalytic Reactions in Organic Media Using Immobilized Catalysts in Different Compartments

(2014) Marcel Heidlindemann et al.   ACS Catalysis

Heterogeneous Catalysis for Tandem Reactions

(2014) Maria J. Climent et al.   ACS Catalysis

Catalysis by metal–organic frameworks: proline and gold functionalized MOFs for the aldol and three-component coupling reactions

(2014) Liu Lili et al.   RSC Advances

Recent developments in one-pot tandem oxidation process coupling reactions

(2014) Vineet Jeena et al.   RSC Advances

Enantio-Relay Catalysis Constructs Chiral Biaryl Alcohols over Cascade Suzuki Cross-Coupling-Asymmetric Transfer Hydrogenation

(2014) Dacheng Zhang et al.   Scientific Reports

Preparation of Optically Enriched 3-Hydroxy-3,4-dihydroquinolin-2(1H)-ones by Heterogeneous Catalytic Cascade Reaction over Supported Platinum Catalyst

(2013) György Szőllősi et al.   ADVANCED SYNTHESIS & CATALYSIS

A Palladium/Chiral Amine Co-catalyzed Enantioselective Dynamic Cascade Reaction: Synthesis of Polysubstituted Carbocycles with a Quaternary Carbon Stereocenter

(2013) Guangning Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Carbon-Carbon Bond Formation under Continuous-Flow Conditions with Chiral Heterogeneous Catalysts

(2013) Tetsu Tsubogo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Synthesis of N-Protected β-Amino Malonates Catalyzed by Magnetically Separable Heterogeneous Rosin-Derived Amino Thiourea Catalysts: A Stereocontrolled Approach to β-Amino Acids

(2013) Hao Zhu et al.   ChemCatChem

A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C–C bond formation

(2013) Hiroyuki Miyamura et al.   CHEMICAL COMMUNICATIONS

Catalytic C–C Bond-Forming Multi-Component Cascade or Domino Reactions: Pushing the Boundaries of Complexity in Asymmetric Organocatalysis

(2013) Chandra M. R. Volla et al.   CHEMICAL REVIEWS

Chiral metal nanoparticle-catalyzed asymmetric C–C bond formation reactions

(2013) Tomohiro Yasukawa et al.   CHEMICAL SOCIETY REVIEWS

One-pot Synthesis and its Practical Application in Pharmaceutical Industry

(2013) Wenyi Zhao et al.   CURRENT ORGANIC SYNTHESIS

Stereoselective organic reactions promoted by immobilized chiral catalysts in continuous flow systems

(2013) Alessandra Puglisi et al.   GREEN CHEMISTRY

Asymmetric Organocatalytic Aldol Reaction in Water: Mechanistic Insights and Development of a Semi-Continuously Operating Process

(2013) Albrecht Berkessel et al.   SYNTHESIS-STUTTGART

Recent developments in enantioselective multicatalysed tandem reactions

(2013) Hélène Pellissier   TETRAHEDRON

In situ preparation of a multifunctional chiral hybrid organic–inorganic catalyst for asymmetric multicomponent reactions

(2013) Pilar García-García et al.   Chemical Science

Multistep One-Pot Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis

(2013) Carl A. Denard et al.   ACS Catalysis

Recent Developments of Cascade Reactions Involving ω-Transaminases

(2013) Robert C. Simon et al.   ACS Catalysis

Recent Advances in Asymmetric Catalysis in Flow

(2013) Dongbo Zhao et al.   ACS Catalysis

Effect of the Helical Tether of a Resin-Supported Peptide Catalyst for Friedel-Crafts-Type Alkylation in Water

(2012) Kengo Akagawa et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Developments in Asymmetric Organocatalytic Domino Reactions

(2012) Hélène Pellissier   ADVANCED SYNTHESIS & CATALYSIS

Recent Developments in Enantioselective Metal-Catalyzed Domino Reactions

(2012) Hervé Clavier et al.   ADVANCED SYNTHESIS & CATALYSIS

Organometal-bridged PMOs as efficiency and reusable bifunctional catalysts in one-pot cascade reactions

(2012) Jianlin Huang et al.   APPLIED CATALYSIS A-GENERAL

Asymmetric one-pot sequential Friedel–Crafts-type alkylation and α-oxyamination catalyzed by a peptide and an enzyme

(2012) Kengo Akagawa et al.   Beilstein Journal of Organic Chemistry

Heterogeneous asymmetric Henry–Michael one-pot reaction synergically catalyzed by grafted chiral bases and inherent achiral hydroxyls on mesoporous silica surface

(2012) Shanshan Yang et al.   CHEMICAL COMMUNICATIONS

Stereocontrolled Domino Reactions

(2012) Hélène Pellissier   CHEMICAL REVIEWS

Self-Supported Chiral Titanium Cluster (SCTC) as a Robust Catalyst for the Asymmetric Cyanation of Imines under Batch and Continuous Flow at Room Temperature

(2012) Abdul M. Seayad et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silicone-Supported Cinchona Alkaloid Derivatives as Insoluble Organocatalysts in the Enantioselective Dimerization of Ketenes

(2012) Damiano Cancogni et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The integration of flow reactors into synthetic organic chemistry

(2012) Ian R. Baxendale   JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY

N719 Dye-Sensitized Organophotocatalysis: Enantioselective Tandem Michael Addition/Oxyamination of Aldehydes

(2012) Hyo-Sang Yoon et al.   ORGANIC LETTERS

Asymmetric triple cascade organocatalytic reaction in water: construction of polyfunctional cyclohexene building blocks having multiple stereocenters

(2012) Yaomei Jia et al.   TETRAHEDRON-ASYMMETRY

Highly Enantioselective Cascade Transformations by Merging Heterogeneous Transition Metal Catalysis with Asymmetric Aminocatalysis

(2012) Luca Deiana et al.   Scientific Reports

Recent Advances in Palladium-Catalyzed Cascade Cyclizations

(2011) Tjøstil Vlaar et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Pot Reactions Accelerate the Synthesis of Active Pharmaceutical Ingredients

(2011) Carine Vaxelaire et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple Recipe for Sophisticated Cocktails: Organocatalytic One-Pot Reactions-Concept, Nomenclature, and Future Perspectives

(2011) Łukasz Albrecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A chiral metal–organic framework for sequential asymmetric catalysis

(2011) Feijie Song et al.   CHEMICAL COMMUNICATIONS

Continuous Flow System with a Polymer-Supported Dirhodium(II) Catalyst: Application to Enantioselective Carbonyl Ylide Cycloaddition Reactions

(2011) Koji Takeda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemo-bio catalyzed synthesis of R-1-phenylethyl acetate over bimetallic PdZn catalysts, lipase, and Ru/Al2O3. Part II

(2011) A. Kirilin et al.   KINETICS AND CATALYSIS

A one-pot catalysis: the strategic classification with some recent examples

(2011) Nitin T. Patil et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One-pot production of chiral α,β-epoxy ketones from benzaldehydes and acetophenones by recyclable poly(amino acid) catalysis

(2011) Wanrong Luo et al.   TETRAHEDRON

Combining bio- and chemo-catalysis: from enzymes to cells, from petroleum to biomass

(2011) Andrew C. Marr et al.   TRENDS IN BIOTECHNOLOGY

Simple Preparation of Dimeric Cinchona Alkaloid Derivatives on Polystyrene Supports and a Highly Enantioselective Catalytic Heterogeneous Dimerization of Ketenes

(2010) Ravindra P. Jumde et al.   ADVANCED SYNTHESIS & CATALYSIS

Next-Generation Catalysis for Renewables: Combining Enzymatic with Inorganic Heterogeneous Catalysis for Bulk Chemical Production

(2010) Peter N. R. Vennestrøm et al.   ChemCatChem

Dynamic Kinetic Resolution of Amines and Amino Acids by Enzyme-Metal Cocatalysis

(2010) Yunwoong Kim et al.   ChemCatChem

One-pot sequential alcohol oxidation and asymmetric α-oxyamination in aqueous media using recyclable resin-supported peptide catalyst

(2010) Kengo Akagawa et al.   CHEMICAL COMMUNICATIONS

Dynamic Kinetic Asymmetric Domino Oxa-Michael/Carbocyclization by Combination of Transition-Metal and Amine Catalysis: Catalytic Enantioselective Synthesis of Dihydrofurans

(2010) Shuangzheng Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Deracemisation methods

(2010) Nicholas J Turner   CURRENT OPINION IN CHEMICAL BIOLOGY

Chiral undecagold clusters: synthesis, characterization and investigation in catalysis

(2010) Eugen S. Andreiadis et al.   DALTON TRANSACTIONS

Cinchona methyl ethers as modifiers in the enantioselective hydrogenation of (E)-2,3-diphenylpropenoic acids over Pd catalyst

(2010) György Szőllősi et al.   JOURNAL OF CATALYSIS

Reactions of chlorine substituted (E)-2,3-diphenylpropenoic acids over cinchonidine-modified Pd: Enantioselective hydrogenation versus hydrodechlorination

(2010) György Szőllősi et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Concerning the Mechanism of the FeCl3-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway

(2010) Jeffrey F. Van Humbeck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic cascade reactions as a new tool in total synthesis

(2010) Christoph Grondal et al.   Nature Chemistry

Efficient Asymmetric α-Oxyamination of Aldehydes by Resin-Supported Peptide Catalyst in Aqueous Media

(2010) Kengo Akagawa et al.   ORGANIC LETTERS

Mechanism of the chemo–bio catalyzed cascade synthesis of R-1-phenylethyl acetate over Pd/Al2O3, lipase, and Ru-catalysts

(2010) Alexey Kirilin et al.   RESEARCH ON CHEMICAL INTERMEDIATES

Immobilized Complexes for Enantioselective Catalysis: When Will They Be Used in Industry?

(2010) Benoît Pugin et al.   TOPICS IN CATALYSIS

Pericyclic domino reactions: concise approaches to natural carbocyclic frameworks

(2009) Jason Poulin et al.   CHEMICAL SOCIETY REVIEWS

Dynamic Kinetic Asymmetric Transformation (DYKAT) by Combined Amine- and Transition-Metal-Catalyzed Enantioselective Cycloisomerization

(2009) Gui-Ling Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Domino Reactions

(2009) Andrea-Nekane Alba et al.   CURRENT ORGANIC CHEMISTRY

Suzuki-Miyaura cross-coupling catalyzed by protein-stabilized palladium nanoparticles under aerobic conditions in water: application to a one-pot chemoenzymatic enantioselective synthesis of chiral biaryl alcohols

(2009) A. Prastaro et al.   GREEN CHEMISTRY

Utilization of cascade chemo-bio catalysis for the synthesis of R-1-phenylethyl acetate

(2009) Päivi Mäki-Arvela et al.  

Exploiting Nanospace for Asymmetric Catalysis: Confinement of Immobilized, Single-Site Chiral Catalysts Enhances Enantioselectivity

(2008) John Meurig Thomas et al.   ACCOUNTS OF CHEMICAL RESEARCH

Up to 96% Enantioselectivities in the Hydrogenation of Fluorine Substituted (E)-2,3-Diphenylpropenoic Acids over Cinchonidine-Modified Palladium Catalyst

(2008) György Szőllősi et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Polyfunctionalized Mono-, Bi-, and Tricyclic Carbon Frameworksvia Organocatalytic Domino Reactions

(2008) Dieter Enders et al.   ADVANCED SYNTHESIS & CATALYSIS

One-pot utilization of heterogeneous and enzymatic catalysis: Synthesis of R-1-phenylethyl acetate from acetophenone

(2008) Päivi Mäki-Arvela et al.   CATALYSIS TODAY

Sustainable chemical technology through catalytic multistep reactions

(2008) Dmitry Yu. Murzin et al.   CHEMICAL ENGINEERING RESEARCH & DESIGN

Enantioselective Decarboxylation of β-Keto Esters with Pd/Amino Alcohol Systems: Successive Metal Catalysis and Organocatalysis

(2008) Pavel Kukula et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterogeneous Multifunctional Catalysts for Tandem Processes: An Approach toward Sustainability

(2008) François-Xavier Felpin et al.   ChemSusChem

Ruthenium and enzyme-catalyzed dynamic kinetic resolution of alcohols

(2008) R. Karvembu et al.   COMPTES RENDUS CHIMIE

Structural requirements for substrate in highly enantioselective hydrogenation over the cinchonidine-modified Pd/C

(2008) Takashi Sugimura et al.   JOURNAL OF CATALYSIS

Cascade approach for synthesis of R-1-phenyl ethyl acetate from acetophenone: Effect of support

(2008) Päivi Mäki-Arvela et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Asymmetric Reductive Acylation of Aromatic Ketoximes by Enzyme-Metal Cocatalysis

(2008) Kiwon Han et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Multi-Component Asymmetric Cascade Reactions Catalyzed by Soluble Star Polymers with Highly Branched Non-Interpenetrating Catalytic Cores

(2008) Yonggui Chi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the immobilization of chiral catalysts containing bis(oxazolines) and related ligands

(2007) José M. Fraile et al.   COORDINATION CHEMISTRY REVIEWS