Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines

(2018) Oleg V. Khazipov et al.   ORGANOMETALLICS

Influence of R–NHC Coupling on the Outcome of R–X Oxidative Addition to Pd/NHC Complexes (R = Me, Ph, Vinyl, Ethynyl)

(2017) Evgeniy G. Gordeev et al.   ORGANOMETALLICS

A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction

(2017) Alexander V. Astakhov et al.   ORGANOMETALLICS

Well-defined nickel and palladium precatalysts for cross-coupling

(2017) Nilay Hazari et al.   Nature Reviews Chemistry

Elusive Reaction Intermediates in Solution Explored by ESI-MS: Reverse Periscope for Mechanistic Investigations

(2016) Claudio Iacobucci et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis

(2016) Alexandre Nasr et al.   COORDINATION CHEMISTRY REVIEWS

Selective Formation of cis-N-Heterocyclic Carbene-PtII-Pnictogen Complexes and in vitro Evaluation of Their Cytotoxic Activities toward Cancer Cells

(2016) Mathilde Bouché et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki–Miyaura couplings

(2016) Elliot Steeples et al.   NEW JOURNAL OF CHEMISTRY

Nickel N-Heterocyclic Carbene-Catalyzed C–Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects

(2016) Vincent Ritleng et al.   ACS Catalysis

Palladium(0)/NHC-Catalyzed Reductive Heck Reaction of Enones: A Detailed Mechanistic Study

(2015) Saeed Raoufmoghaddam et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generating Active “L-Pd(0)” via Neutral or Cationic π-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure–Activity Studies in Challenging Cross-Coupling Reactions

(2015) A. J. DeAngelis et al.   JOURNAL OF ORGANIC CHEMISTRY

Recyclable Pd(0)-Pd(II) composites formed from Pd(II) dimers with NHC ligands under Suzuki–Miyaura conditions

(2015) Marta Górna et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System

(2015) York Schramm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Hydrolysis of Nickel(II) Complexes with N-Heterocyclic Carbene Ligands

(2015) Alexander V. Astakhov et al.   ORGANOMETALLICS

Water-Soluble Palladium(II) Complexes with Sulfonated N-Heterocyclic Carbenes in Suzuki Cross-Coupling and Hydrodehalogenation Reactions

(2015) Roberto Garrido et al.   ORGANOMETALLICS

Understanding Precatalyst Activation in Cross-Coupling Reactions: Alcohol Facilitated Reduction from Pd(II) to Pd(0) in Precatalysts of the Type (η3-allyl)Pd(L)(Cl) and (η3-indenyl)Pd(L)(Cl)

(2015) Patrick R. Melvin et al.   ACS Catalysis

Mechanism of Ni-NHC Catalyzed Hydrogenolysis of Aryl Ethers: Roles of the Excess Base

(2015) Liping Xu et al.   ACS Catalysis

Carboxylate Switch between Hydro- and Carbopalladation Pathways in Regiodivergent Dimerization of Alkynes

(2014) Olga V. Zatolochnaya et al.   CHEMISTRY-A EUROPEAN JOURNAL

The application of electrospray ionization mass spectrometry to homogeneous catalysis

(2014) Krista L. Vikse et al.   COORDINATION CHEMISTRY REVIEWS

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

One-Pot Synthesis of 7,9-Dialkylpurin-8-one Analogues: Broad Substrate Scope

(2013) Jian-Ping Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Oxygen-atom insertion of NHC–copper complex: The source of oxygen from N,N-dimethylformamide

(2013) Wei Zeng et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cyclic Thiourea/Urea Functionalized Triphenylamine-Based Dyes for High-Performance Dye-Sensitized Solar Cells

(2013) Zhisheng Wu et al.   ORGANIC LETTERS

Carbon–Heteroatom Coupling Using Pd-PEPPSI Complexes

(2013) Cory Valente et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Target-oriented analysis of gaseous, liquid and solid chemical systems by mass spectrometry, nuclear magnetic resonance spectroscopy and electron microscopy

(2013) V V Kachala et al.   RUSSIAN CHEMICAL REVIEWS

A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity

(2012) David Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions

(2012) Cory Valente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and characterization of para-pyridine linked NHC palladium complexes and their studies for the Heck–Mizoroki coupling reaction

(2012) Ya-Ming Liu et al.   DALTON TRANSACTIONS

General and Selective Head-to-Head Dimerization of Terminal Alkynes Proceeding via Hydropalladation Pathway

(2012) Claire Jahier et al.   ORGANIC LETTERS

NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

(2012) Yi Li et al.   TETRAHEDRON

Synthesis and Glutathione Peroxidase-like activity of N-heterocyclic carbene derived cationic diselenides

(2012) Sudesh T. Manjare et al.   TETRAHEDRON

A general method for the preparation of N-heterocyclic carbene–silver(I) complexes in water

(2012) Muhammad Jawwad Saif et al.   TRANSITION METAL CHEMISTRY

1,3-Dibenzyl-1H-benzimidazol-2(3H)-one

(2011) Youssef Kandri Rodi et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

(2011) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Stille Polycondensation for Synthesis of Functional Materials

(2011) Bridget Carsten et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union

(2011) George C. Fortman et al.   CHEMICAL SOCIETY REVIEWS

Pd-NHC Catalyzed Conjugate Addition versus the Mizoroki-Heck Reaction

(2011) Aditya L. Gottumukkala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Benzimidazoles by Phosphine-Mediated Reductive Cyclisation of ortho-Nitro-anilides

(2011) Jan Duchek et al.   HELVETICA CHIMICA ACTA

Synthesis of 2-Imidazolones and 2-Iminoimidazoles

(2011) Heather M. Lima et al.   ORGANIC LETTERS

Synthesis and catalytic properties of a heterocyclic–carbene complex of palladium

(2011) Yanhui Shi et al.   JOURNAL OF CHEMICAL RESEARCH

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzimidazol-2-ylidene Gold(I) Complexes Are Thioredoxin Reductase Inhibitors with Multiple Antitumor Properties

(2010) Riccardo Rubbiani et al.   JOURNAL OF MEDICINAL CHEMISTRY

A novel method for the synthesis of 2-imidazolones

(2010) Inas M. AlNashef et al.   TETRAHEDRON LETTERS

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

(2009) Christian Torborg et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis and Study of 5,5′-Bibenzimidazolylidenes and Their Bimetallic Complexes

(2009) Joyce A. V. Er et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

Online Mechanistic Investigations of Catalyzed Reactions by Electrospray Ionization Mass Spectrometry: A Tool to Intercept Transient Species in Solution

(2007) Leonardo S. Santos   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY