4.7 Article

Synthesis and structure of a ferrocenylboron dication

Journal

INORGANIC CHEMISTRY
Volume 47, Issue 17, Pages 7456-7458

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic800876p

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Funding

  1. DFG
  2. FCI

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Treatment of the borane Br(2)BFc (Fc = ferrocenyl) with the Lewis base 4-methylpyridine and Na[BAr4f] [Ar-f = 3,5-(CF3)(2)C6H3] afforded the boron dication [FcB(NC5H4-4-Me)(3)][BAr4f](2). This compound is a rare example of a structurally characterized boron dication.

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