An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation

Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity

(2018) Hao Wang et al.   CHEMICAL COMMUNICATIONS

Bis(dinitrogen)cobalt(−1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes

(2018) Yafei Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation

(2017) Ryuji Imayoshi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N-heterocyclic silylenes as powerful steering ligands in catalysis

(2017) Saeed Raoufmoghaddam et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes

(2017) Javier Fajardo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction

(2017) Ryoichi Araake et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic N2 Reduction to Silylamines and Thermodynamics of N2 Binding at Square Planar Fe

(2017) Demyan E. Prokopchuk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

(2016) Hiromasa Tanaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Bis(silylene)-Substituted ortho -Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes

(2016) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

(2016) Tomoyuki Kosai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclic Amino(Ylide) Silylene: A Stable Heterocyclic Silylene with Strongly Electron-Donating Character

(2016) Isabel Alvarado-Beltran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

(2016) Yoshiaki Tanabe et al.   CHEMICAL RECORD

High-Spin Iron(I) and Iron(0) Dinitrogen Complexes Supported by N-Heterocyclic Carbene Ligands

(2016) Zhenwu Ouyang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

(2016) Mikko M. Hänninen et al.   DALTON TRANSACTIONS

Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

(2016) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

(2016) Peter J. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

(2016) Shogo Kuriyama et al.   Nature Communications

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes

(2015) Sean F. McWilliams et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cover Picture: Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper (Chem. Eur. J. 1/2016)

(2015) Christian Matheis et al.   CHEMISTRY-A EUROPEAN JOURNAL

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

(2015) Yoshiaki Nishibayashi   INORGANIC CHEMISTRY

Binding of dinitrogen to an iron–sulfur–carbon site

(2015) Ilija Čorić et al.   NATURE

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes

(2014) Burgert Blom et al.   ORGANOMETALLICS

Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity

(2014) Daniel Gallego et al.   ORGANOMETALLICS

N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

(2014) Burgert Blom et al.   Inorganic Chemistry Frontiers

The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions

(2013) Timur Kandemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Developing more sustainable processes for ammonia synthesis

(2013) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis-N-Heterocyclic Carbene (NHC) Stabilized η6-Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand

(2012) Konstantin Junold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molybdenum(0) dinitrogen complexes with polydentate phosphine ligands for synthetic nitrogen fixation: Geometric and electronic structure contributions to reactivity

(2012) Henning Broda et al.   COORDINATION CHEMISTRY REVIEWS

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Aromatic Ylide-Stabilized Carbocyclic Silylene

(2011) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

(2010) Justin L. Crossland et al.   COORDINATION CHEMISTRY REVIEWS

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

(2010) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Stabilized 1-Silacyclopenta-2,4-dienylidenes

(2010) Yihua Gao et al.   ORGANOMETALLICS

A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex

(2009) Wei Yang et al.   INORGANIC CHEMISTRY

The Synthesis of (η3-C3H5)Pd{Si[N(tBu)CH]2}Cl and the Catalytic Property for Heck Reaction

(2008) Ming Zhang et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE