Recent Developments on the Use of Group 13 Metal Complexes in Catalysis

Aluminum Aryloxide Compounds as Very Active Catalysts for Glycidyl Methacrylate Selective Ring-Opening Polymerization

(2018) M. Teresa Muñoz et al.   ChemCatChem

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

(2018) Victoria A. Pollard et al.   CHEMICAL COMMUNICATIONS

Aluminum-Catalyzed Hydroboration of Alkenes

(2018) Alessandro Bismuto et al.   ACS Catalysis

Control of Ligand pKa Values Tunes the Electrocatalytic Dihydrogen Evolution Mechanism in a Redox-Active Aluminum(III) Complex

(2017) Tobias J. Sherbow et al.   INORGANIC CHEMISTRY

Ring-Opening Polymerization of Epoxides: Facile Pathway to Functional Polyethers via a Versatile Organoaluminum Initiator

(2017) Christina G. Rodriguez et al.   MACROMOLECULES

Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C–F Bonds

(2017) Amit K. Jaiswal et al.   ORGANIC LETTERS

Catalytic Reduction of Carbon Dioxide Using Cationic Organoaluminum and -Gallium Compounds

(2017) Mahmoud Saleh et al.   ORGANOMETALLICS

Synthesis and crystal structures of guanidinatoaluminum complexes and catalytic study for MPV reduction

(2017) Hongfei Han et al.   POLYHEDRON

Four-fold increase in epoxide polymerization rate with change of alkyl-substitution on mono-μ-oxo-dialuminum initiators

(2017) R. C. Ferrier et al.   Polymer Chemistry

Substrate-Triggered Stereoselective Preparation of Highly Substituted Organic Carbonates

(2017) Victor Laserna et al.   ACS Catalysis

New Tricks for an Old Dog: Aluminum Compounds as Catalysts in Reduction Chemistry

(2017) Georgii I. Nikonov   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Aluminum Hydride Catalyzed Hydroboration of Alkynes

(2016) Alessandro Bismuto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Study of Formic Acid Dehydrogenation Catalyzed by AlIII -Bis(imino)pyridine

(2016) Qian-Qian Lu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unprecedented Carbonato Intermediates in Cyclic Carbonate Synthesis Catalysed by Bimetallic Aluminium(Salen) Complexes

(2016) José A. Castro-Osma et al.   ChemSusChem

A Bimetallic Aluminium(Salphen) Complex for the Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide

(2016) Xiao Wu et al.   ChemSusChem

An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

(2016) Zhi Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

End of Frustration: Catalytic Precision Polymerization with Highly Interacting Lewis Pairs

(2016) Maximilian G. M. Knaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts

(2016) Jiawei Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C6F5)3 Lewis Pairs: Structures of Intermediates, Kinetics, and Mechanism

(2016) Qianyi Wang et al.   MACROMOLECULES

Expanding the scope of gallium-catalyzed olefin epoxidation

(2016) Fraser Bronston et al.   POLYHEDRON

Aluminum Hydrides Stabilized by N-Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane

(2016) Daniel Franz et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Hydrosilylation of Olefins Catalyzed by Well-Defined Cationic Aluminum Complexes: Lewis Acid versus Insertion Mechanisms

(2016) Kayla Jakobsson et al.   ACS Catalysis

Catalytic applications of [IPr·GaX2][SbF6] and related species

(2016) Bastien Michelet et al.   Organic Chemistry Frontiers

Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

(2015) Joseph A. B. Abdalla et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Silane-Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis

(2015) Jiawei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer

(2015) Emily J. Thompson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Aluminum Hydride That Functions like a Transition-Metal Catalyst

(2015) Zhi Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Characterization, and Catalytic Activity of a Series of Aluminium–Amidate Complexes

(2015) Kevin P. Yeagle et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

(2015) Shyeni Paul et al.   CHEMICAL COMMUNICATIONS

Dibromoindium(iii) cations as a π-Lewis acid: characterization of [IPr·InBr2][SbF6] and its catalytic activity towards alkynes and alkenes

(2015) Bastien Michelet et al.   CHEMICAL COMMUNICATIONS

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

(2015) Yann Sarazin et al.   CHEMICAL REVIEWS

The Golden Age of Transfer Hydrogenation

(2015) Dong Wang et al.   CHEMICAL REVIEWS

Aluminium-catalysed intramolecular hydroamination of aminoalkenes: computational perusal of alternative pathways for aminoalkene activation

(2015) Sven Tobisch   DALTON TRANSACTIONS

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

(2015) James W. Comerford et al.   GREEN CHEMISTRY

Synthesis and Characterization of α-Diimine Complexes of Group 13 Metals and Their Catalytic Activity toward the Epoxidation of Alkenes

(2015) Connor A. Koellner et al.   INORGANIC CHEMISTRY

Bidentate N, O-aluminum complexes: Synthesis, characterization and catalytic study for MPV reduction reactions

(2015) Yupeng Hua et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Aluminum Alkyl Complexes Supported by Bidentate N,N Ligands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines

(2015) Yun Wei et al.   ORGANOMETALLICS

Three asymmetric guanidinato metal complexes: Synthesis, crystal structures and their use as pre-catalysts in the Meerwein–Ponndorf–Verley reduction

(2015) Hong-Fei Han et al.   POLYHEDRON

New Procedures for Catalytic Carbophilic Activation by Gold and Gallium π-Acids

(2015) Vincent Gandon et al.   SYNLETT

Aluminum(salen) Complexes as Catalysts for the Kinetic Resolution of Terminal Epoxides via CO2 Coupling

(2015) Michael North et al.   ACS Catalysis

Recent Advances in the Catalytic Preparation of Cyclic Organic Carbonates

(2015) Carmen Martín et al.   ACS Catalysis

Carbon Dioxide as a Protecting Group: Highly Efficient and Selective Catalytic Access to Cycliccis-Diol Scaffolds

(2014) Victor Laserna et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Epoxide Polymerization and Copolymerization

(2014) M. Ian Childers et al.   CHEMICAL REVIEWS

A Well-Defined Monomeric Aluminum Complex as an Efficient and General Catalyst in the Meerwein-Ponndorf-Verley Reduction

(2014) Brian McNerney et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gallium-Assisted Transfer Hydrogenation of Alkenes

(2014) Bastien Michelet et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Janus-Headed Lewis Superacid: Simple Access to, and First Application of Me3Si-F-Al(ORF)3

(2014) Michael Rohde et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of a Halide-Free Aluminium-Based Catalyst for the Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide

(2014) Jose A. Castro-Osma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Well-defined organo-gallium complexes as Lewis acids for molecular catalysis: Structure–stability–activity relationships

(2014) Christophe Bour et al.   COORDINATION CHEMISTRY REVIEWS

Aluminum Compounds Containing Pyrrole-Imine Ligand Systems - Synthesis, Characterization, Structure Elucidation, Ring-Opening Polymerization, and Catalytic Meerwein-Ponndorf-Verley Reaction

(2014) Shu-Ya Hsu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Indium-Catalyzed Hydroamination/Hydrosilylation of Terminal Alkynes and Aromatic Amines through a One-Pot, Two-Step Protocol

(2014) Norio Sakai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bifunctional Aluminum Catalyst for CO2 Fixation: Regioselective Ring Opening of Three-Membered Heterocyclic Compounds

(2014) Wei-Min Ren et al.   JOURNAL OF ORGANIC CHEMISTRY

Chain Propagation and Termination Mechanisms for Polymerization of Conjugated Polar Alkenes by [Al]-Based Frustrated Lewis Pairs

(2014) Jianghua He et al.   MACROMOLECULES

Mechanistic Aspects of Initiation and Deactivation in N-Heterocyclic Olefin Mediated Polymerization of Acrylates with Alane as Activator

(2014) Yin-Bao Jia et al.   MACROMOLECULES

Structure, Stability, and Catalytic Activity of Fluorine-Bridged Complexes IPr·GaCl2(μ-F)EFn–1 (EFn– = SbF6–, PF6–, or BF4–)

(2014) Christophe Bour et al.   ORGANOMETALLICS

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates

(2013) Samuel Dagorne et al.   COORDINATION CHEMISTRY REVIEWS

Dual catalysis: new approaches for the polymerization of lactones and polar olefins

(2013) Estefanía Piedra-Arroni et al.   DALTON TRANSACTIONS

A Powerful Aluminum Catalyst for the Synthesis of Highly Functional Organic Carbonates

(2013) Christopher J. Whiteoak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Univalent Gallium Salts of Weakly Coordinating Anions: Effective Initiators/Catalysts for the Synthesis of Highly Reactive Polyisobutylene

(2013) Martin R. Lichtenthaler et al.   ORGANOMETALLICS

CO2 Activation with Bulky Neutral and Cationic Phenoxyalanes

(2013) Rudolf J. Wehmschulte et al.   ORGANOMETALLICS

Deoxygenative Reduction of Carbon Dioxide to Methane, Toluene, and Diphenylmethane with [Et2Al]+ as Catalyst

(2012) Manish Khandelwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic Gallium(III) Halide Complexes: A New Generation of π-Lewis Acids

(2012) Shun Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

(2012) Yuetao Zhang et al.   DALTON TRANSACTIONS

Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT

(2012) Lei Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Discrete N,O,N-Supported Gallium Amido Complex for the Intermolecular Hydroamination of Terminal Alkynes

(2012) Frédéric Hild et al.   ORGANOMETALLICS

Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-Component Aluminum-Salen Complexes

(2012) Dawei Tian et al.   ACS Catalysis

Synthesis and Reactions of N-Heterocyclic Carbene Boranes

(2011) Dennis P. Curran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of Alkynes to a Gallium Bis-Amido Complex: Imitation of Transition-Metal-Based Catalytic Systems

(2011) Igor L. Fedushkin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Cationic organoaluminum compounds as intramolecular hydroamination catalysts

(2011) Manish Khandelwal et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Aqueous cationic olefin polymerization using tris(pentafluorophenyl)gallium and aluminum

(2011) Robert T. Mathers et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex

(2011) Jürgen Koller et al.   ORGANOMETALLICS

Aluminium-catalyzed intramolecular hydroamination of aminoalkenes

(2010) Jürgen Koller et al.   CHEMICAL COMMUNICATIONS

Synthesis, Characterization, and Reactivity of Aluminum Alkyl/Amide Complexes Supported by Guanidinate and Monoanionic OCO-Pincer Ligands

(2010) Jürgen Koller et al.   ORGANOMETALLICS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS