Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 44, Pages 14488-14492Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404139
Keywords
alkenes; cyclization; gallium; homogeneous catalysis; hydrogenation
Categories
Funding
- UPS
- CNRS
- MESR
- IUF
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We report a rare case of alkene transfer hydrogenation using a main-group compound instead of a transition-metal complex as catalyst. We disclosed that 1,4-cyclohexadiene can be used as H-2 surrogate towards olefin reduction in the presence of [IPrGaCl2][SbF6]. Hydrogenative cyclizations have also been carried out because this cationic gallium complex is also a potent hydroarylation catalyst.
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