Engineering the Frontier Orbitals of a Diazadiborinine for Facile Activation of H2 , NH3 , and an Isonitrile

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

Addition of dihydrogen to a borylborenium center

(2018) Junhao Zheng et al.   Chemical Science

Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)

(2017) Nana Tsukahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Stabilized Boranthrene as a Metal-Free Platform for the Activation of Small Molecules

(2017) Jordan W. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrostatic Catalyst Generated from Diazadiborinine for Carbonyl Reduction

(2017) Di Wu et al.   Chem

Reversible Dihydrogen Activation by Reduced Aryl Boranes as Main-Group Ambiphiles

(2016) Esther von Grotthuss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dihydrogen Complexation

(2016) Robert H. Crabtree   CHEMICAL REVIEWS

Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds

(2016) Merle Arrowsmith et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative 1,1-addition reactions of vicinal phosphane/borane frustrated Lewis pairs

(2016) Allan Jay P. Cardenas et al.   COORDINATION CHEMISTRY REVIEWS

Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles

(2016) Wei Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ring Contraction of a Pinacolatoboryl Group To Form a 1,2-Oxaboretane Ring: Reaction of Unsymmetrical Diborane(4) with 2,6-Dimethylphenyl Isocyanide

(2016) Yuhei Katsuma et al.   ORGANOMETALLICS

The broadening reach of frustrated Lewis pair chemistry

(2016) D. W. Stephan   SCIENCE

Ambiphilic boron in 1,4,2,5-diazadiborinine

(2016) Baolin Wang et al.   Nature Communications

From an Electron-Rich Bis(boraketenimine) to an Electron-Poor Diborene

(2015) Julian Böhnke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiple complexation of CO and related ligands to a main-group element

(2015) Holger Braunschweig et al.   NATURE

Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene

(2015) Di Wu et al.   Chemical Science

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres

(2015) Di Wu et al.   Nature Communications

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen

(2014) Nicole Dettenrieder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

(2014) Fatme Dahcheh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent

(2014) Hiroki Asakawa et al.   Nature Communications

Remarkable coordination behavior of alkyl isocyanides toward unsaturated vicinal frustrated P/B Lewis pairs

(2013) Olga Ekkert et al.   Chemical Science

Mechanistic Studies on the Metal-Free Activation of Dihydrogen by Antiaromatic Pentarylboroles

(2012) Adrian Y. Houghton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Addition reactions to the intramolecular mesityl2P–CH2–CH2–B(C6F5)2 frustrated Lewis pair

(2010) Cornelia M. Mömming et al.   DALTON TRANSACTIONS

A Stable Doubly Hydrogen-Bridged Butterfly-Shaped Diborane(4) Compound

(2010) Yoshiaki Shoji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Activation by Antiaromatic Pentaarylboroles

(2010) Cheng Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

(2009) Y. Peng et al.   SCIENCE

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION