Natural inspirations for metal–ligand cooperative catalysis

The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

(2017) Alexander Dauth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel pincer model of the active site of lactate racemase involves ligand participation in hydride transfer

(2017) Tao Xu et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Dihydrogen Complexation

(2016) Robert H. Crabtree   CHEMICAL REVIEWS

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Alternative Mechanistic Strategy for Enzyme Catalysis in a Ni-Dependent Lactate Racemase (LarA): Intermediate Destabilization by the Cofactor

(2016) Xiaoyong Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Functional Model of [Fe]-Hydrogenase

(2016) Tao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase

(2016) Deborah Brazzolotto et al.   Nature Chemistry

A structural view of synthetic cofactor integration into [FeFe]-hydrogenases

(2016) J. Esselborn et al.   Chemical Science

Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere

(2015) Thomas B. Rauchfuss   ACCOUNTS OF CHEMICAL RESEARCH

How the [NiFe4S4] Cluster of CO Dehydrogenase Activates CO2and NCO−

(2015) Jochen Fesseler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hybrid [FeFe]-Hydrogenases with Modified Active Sites Show Remarkable Residual Enzymatic Activity

(2015) Judith F. Siebel et al.   BIOCHEMISTRY

A Novel Nickel Pincer Complex in the Active Site of Lactate Racemase

(2015) Tao Xu et al.   CHEMBIOCHEM

Toward Functional Type III [Fe]-Hydrogenase Biomimics for H2Activation: Insights from Computation

(2015) Kevin A. Murray et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen-activating models of hydrogenases

(2015) Tao Xu et al.   COORDINATION CHEMISTRY REVIEWS

Beyond H2: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis

(2015) Cameron M Moore et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Mechanism of hydrogen activation by [NiFe] hydrogenases

(2015) Rhiannon M Evans et al.   Nature Chemical Biology

Reconstitution of [Fe]-hydrogenase using model complexes

(2015) Seigo Shima et al.   Nature Chemistry

A tethered niacin-derived pincer complex with a nickel-carbon bond in lactate racemase

(2015) B. Desguin et al.   SCIENCE

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

(2014) Bojana Ginovska-Pangovska et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase

(2014) Mehmet Can et al.   CHEMICAL REVIEWS

Bio-Inspired Transition Metal-Organic Hydride Conjugates for Catalysis of Transfer Hydrogenation: Experiment and Theory

(2014) Alex McSkimming et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen-activation mechanism of [Fe] hydrogenase revealed by multi-scale modeling

(2014) Arndt Robert Finkelmann et al.   Chemical Science

And the Winner is…︁Azadithiolate: An Amine Proton Relay in the [FeFe] Hydrogenases

(2013) David Schilter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystal Structures of [Fe]-Hydrogenase in Complex with Inhibitory Isocyanides: Implications for the H2-Activation Site

(2013) Haruka Tamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Fe]-Hydrogenase and Models that Contain IronAcyl Ligation

(2013) Katherine M. Schultz et al.   Chemistry-An Asian Journal

Kinetic Modeling of Hydrogen Conversion at [Fe] Hydrogenase Active-Site Models

(2013) Arndt R. Finkelmann et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

(2013) Julian Esselborn et al.   Nature Chemical Biology

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Molecular Electrocatalysts for the Oxidation of Hydrogen and the Production of Hydrogen - The Role of Pendant Amines as Proton Relays

(2011) Daniel L. DuBois et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Structure and Function of [Fe]-Hydrogenase and its Iron-Guanylylpyridinol (FeGP) Cofactor

(2010) Seigo Shima et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−Hδ−···Hδ+−O, Bond and Methenyl-H4MPT+Triggered Hydride Transfer

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS

The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site

(2008) S. Shima et al.   SCIENCE