Crystal Structures of [Fe]-Hydrogenase in Complex with Inhibitory Isocyanides: Implications for the H2-Activation Site

Reversible Protonation of a Thiolate Ligand in an [Fe]-Hydrogenase Model Complex

(2012) Dafa Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Pyridinol Acyl Cofactor in the Active Site of [Fe]-hydrogenase Evidenced by the Reactivity of Model Complexes

(2012) Bowen Hu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Biomimetic Models for the Active Site of [Fe]Hydrogenase Featuring an Acylmethyl(hydroxymethyl)pyridine Ligand

(2012) Li-Cheng Song et al.   INORGANIC CHEMISTRY

A Five-Coordinate Iron Center in the Active Site of [Fe]-Hydrogenase: Hints from a Model Study

(2011) Dafa Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insight into the Mechanism of Dihydrogen-Heterolysis at Cyclopentadienone Iron Complexes and Subsequent CX Hydrogenation

(2011) Adrian von der Höh et al.   ChemCatChem

Evidence for acyl–iron ligation in the active site of [Fe]-hydrogenase provided by mass spectrometry and infrared spectroscopy

(2011) Seigo Shima et al.   DALTON TRANSACTIONS

Iron-Chromophore Circular Dichroism of [Fe]-Hydrogenase: The Conformational Change Required for H2 Activation

(2010) Seigo Shima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Fe]-Hydrogenase Models Featuring Acylmethylpyridinyl Ligands

(2010) Dafa Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Third Hydrogenase: A Ferracyclic Carbamoyl with Close Structural Analogy to the Active Site of Hmd

(2010) Peter J. Turrell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The iron-site structure of [Fe]-hydrogenase and model systems: an X-ray absorption near edge spectroscopy study

(2010) Marco Salomone-Stagni et al.   DALTON TRANSACTIONS

Structure and Function of [Fe]-Hydrogenase and its Iron-Guanylylpyridinol (FeGP) Cofactor

(2010) Seigo Shima et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Isocyanides inhibit [Fe]-hydrogenase with very high affinity

(2010) Seigo Shima et al.   FEBS LETTERS

Iron Acyl Thiolato Carbonyls: Structural Models for the Active Site of the [Fe]-Hydrogenase (Hmd)

(2010) Aaron M. Royer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Third Hydrogenase: More Natural Organometallics

(2010) Joseph A. Wright et al.   ORGANOMETALLICS

The Crystal Structure of an [Fe]-Hydrogenase-Substrate Complex Reveals the Framework for H2Activation

(2009) Takeshi Hiromoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The crystal structure of C176A mutated [Fe]-hydrogenase suggests an acyl-iron ligation in the active site iron complex

(2009) Takeshi Hiromoto et al.   FEBS LETTERS

Reactions ofortho-Lithiophenyl (-Hetaryl) Isocyanides with Carbonyl Compounds: Rearrangements of 2-Metalated 4H-3,1-Benzoxazines

(2009) Alexander V. Lygin et al.   JOURNAL OF ORGANIC CHEMISTRY

Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−Hδ−···Hδ+−O, Bond and Methenyl-H4MPT+Triggered Hydride Transfer

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site

(2008) S. Shima et al.   SCIENCE