Advancements in Aminofluorination of Alkenes and Alkynes: Convenient Access to β-Fluoroamines

Regioselective Radical Aminofluorination of Styrenes

(2014) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles

(2014) Antonio Arcadi et al.   Beilstein Journal of Organic Chemistry

Silver-catalyzed one-pot cyclization/fluorination of 2-alkynylanilines: highly efficient synthesis of structurally diverse fluorinated indole derivatives

(2014) Lei Yang et al.   CHEMICAL COMMUNICATIONS

Divergent Reaction Mechanisms in the Aminofluorination of Alkenes

(2014) Wangqing Kong et al.   CHIMIA

Pd-Catalyzed Intramolecular Aminohydroxylation of Alkenes with Hydrogen Peroxide as Oxidant and Water as Nucleophile

(2014) Haitao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competition between sp3-C–N vs sp3-C–F Reductive Elimination from PdIV Complexes

(2014) Mónica H. Pérez-Temprano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Intramolecular Olefin Aminofluorination

(2014) Deng-Fu Lu et al.   ORGANIC LETTERS

Boron Trifluoride Etherate Functioning as a Fluorine Source in an Iodosobenzene-Mediated Intramolecular Aminofluorination of Homoallylic Amines

(2014) Jian Cui et al.   ORGANIC LETTERS

Iodoarene-catalyzed fluorination and aminofluorination by an Ar-I/HF·pyridine/mCPBA system

(2014) Satoru Suzuki et al.   Chemical Science

Palladium-Catalyzed Oxidative Aminofluorination of Styrenes

(2013) Haitao Zhu et al.   ACTA CHIMICA SINICA

Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes Using Anionic Phase-Transfer Catalysis

(2013) Hunter P. Shunatona et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Migratory Insertion of Alkenes into Metal-Oxygen and Metal-Nitrogen Bonds

(2013) Patrick S. Hanley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Enantioselective Aminofluorination of Alkenes

(2013) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes

(2013) Tao Wu et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Intramolecular Fluorooxylation of Styrenes

(2013) Zheliang Yuan et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes

(2013) Nikki A. Cochrane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Anion Phase-Transfer Catalysis Applied to the Direct Enantioselective Fluorinative Dearomatization of Phenols

(2013) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media

(2013) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Synthesis of 1-(Trifluoromethyl)-4-fluoro-1,2-dihydroisoquinolines and 4,4-Difluoro-1,2,3,4-tetrahydroisoquinolines

(2013) Qilun Liu et al.   ORGANIC LETTERS

An Efficient Synthesis of Fluorinated Azaheterocycles by Aminocyclization of Alkenes

(2013) Hai-Tsang Huang et al.   ORGANIC LETTERS

Double Annulative Cascade of Tryptophan-Containing Peptides Triggered by Selectfluor

(2013) Bret Tréguier et al.   ORGANIC LETTERS

One-Pot Gold-Catalyzed Aminofluorination of Unprotected 2-Alkynylanilines

(2013) Antonio Arcadi et al.   ORGANIC LETTERS

Palladium-catalyzed intermolecular fluoroesterification of styrenes: exploration and mechanistic insight

(2013) Haihui Peng et al.   Chemical Science

Transition-metal-free, room-temperature radical azidofluorination of unactivated alkenes in aqueous solution

(2013) Zhaodong Li et al.   Organic Chemistry Frontiers

Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen

(2012) Wanqing Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Polycomponent Metal-Catalyzed Aliphatic, Allylic, and Benzylic Fluorination

(2012) Steven Bloom et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes

(2012) Joy M. Racowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Doubly Axially Chiral Phosphoric Acid Catalyst for the Asymmetric Tandem Oxyfluorination of Enamides

(2012) Takashi Honjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 3-Fluoropyrrolidines and 4-Fluoropyrrolidin-2-ones from Allylic Fluorides

(2012) Lorraine E. Combettes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-Catalyzed Aminohalogenation of FluorinatedN′-Aryl-N-Propargyl Amidines for the Synthesis of Imidazole Derivatives under Mild Conditions

(2012) Shan Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines

(2012) Lorraine E. Combettes et al.   JOURNAL OF FLUORINE CHEMISTRY

Ring Expansion of Cyclic β-Amino Alcohols Induced by Diethylaminosulfur Trifluoride: Synthesis of Cyclic Amines with a Tertiary Fluorine at C3

(2012) Bruno Anxionnat et al.   JOURNAL OF ORGANIC CHEMISTRY

Fe(III)/NaBH4-Mediated Free Radical Hydrofluorination of Unactivated Alkenes

(2012) Timothy J. Barker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorination of Enamides: Access to α-Fluoroimines Using an Anionic Chiral Phase-Transfer Catalyst

(2012) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free intramolecular aminofluorination of alkenes mediated by PhI(OPiv)2/hydrogen fluoride–pyridine system

(2012) Qing Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition metal-catalyzed fluorination of multi carbon–carbon bonds: new strategies for fluorinated heterocycles

(2012) Guosheng Liu   ORGANIC & BIOMOLECULAR CHEMISTRY

Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines

(2012) Tao Xu et al.   ORGANIC LETTERS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Recent Developments in Palladium-Catalyzed Alkene Aminoarylation Reactions for the Synthesis of Nitrogen Heterocycles

(2012) John Wolfe et al.   SYNTHESIS-STUTTGART

Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes

(2011) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Enantioselective Fluorocyclizations

(2011) Oscar Lozano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal catalysis and nucleophilic fluorination

(2011) Charlotte Hollingworth et al.   CHEMICAL COMMUNICATIONS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Gold-Catalyzed Carbon−Heteroatom Bond-Forming Reactions

(2011) A. Corma et al.   CHEMICAL REVIEWS

Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant

(2011) Guoyin Yin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Intramolecular Aminofluorination of Styrenes

(2011) Tao Xu et al.   CHINESE JOURNAL OF CHEMISTRY

Aziridines from Intramolecular Alkene Aziridination of Sulfamates: Reactivity toward Carbon Nucleophiles. Application to the Synthesis of Spisulosine and Its Fluoro Analogue

(2011) Guillaume Malik et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

A Novel Synthesis of Fluorinated Pyrazoles via Gold(I)-Catalyzed Tandem Aminofluorination of Alkynes in the Presence of Selectfluor

(2011) Jianqiang Qian et al.   ORGANIC LETTERS

Electrophilic Fluorination of Group 10 Organometallic Complexes: Chemistry beyond Oxidative Addition

(2011) Arkadi Vigalok   ORGANOMETALLICS

Steric Crowding Makes Challenging Csp3–F Reductive Eliminations Feasible

(2011) Shu-Bin Zhao et al.   ORGANOMETALLICS

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

C(sp3)–F reductive elimination from alkylgold(iii) fluoride complexes

(2011) Neal P. Mankad et al.   Chemical Science

Gold-Catalyzed Synthesis of α-Fluoro Acetals and α-Fluoro Ketones from Alkynes

(2010) Teresa de Haro et al.   ADVANCED SYNTHESIS & CATALYSIS

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

(2010) Teresa de Haro et al.   CHEMICAL COMMUNICATIONS

Fluorocyanation of Enamines

(2010) Alexander D. Dilman et al.   JOURNAL OF ORGANIC CHEMISTRY

Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry

(2010) Ariela W. Kaspi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes

(2010) Shuifa Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Late-Stage Fluorination

(2010) Pingping Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of β-Fluoroamines from β-Amino Alcohols: Application to the Synthesis of LY503430

(2010) Béranger Duthion et al.   ORGANIC LETTERS

Organocatalytic Enantioselective Olefin Aminofluorination

(2010) Chandrakumar Appayee et al.   ORGANIC LETTERS

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

Electrophilic Fluorocyclization of Allyl Silanes

(2009) Susan C. Wilkinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Mediated Reactions for Csp2F Bond Construction: The State of Play

(2009) John M. Brown et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis

(2009) Kilian Muñiz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Mannich Reaction of Fluorinated Ketoesters with a Tryptophan-Derived Bifunctional Thiourea Catalyst

(2009) Xiao Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Fluorinated β-Amino Acid Derivatives by an Asymmetric Mannich Reaction and Selective Deacylation/Decarboxylation Reactions

(2009) Yuanhang Pan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Synthesis of Monofluoroγ-Lactones and Pyrrolidine Derivatives via Electrophilic Fluorination of Allenoic Acids and Amides

(2009) Haifeng CUI et al.   CHINESE JOURNAL OF CHEMISTRY

Silver-Mediated Fluorination of Functionalized Aryl Stannanes

(2009) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid, General Access to Chiral β-Fluoroamines and β,β-Difluoroamines via Organocatalysis

(2009) Olugbeminiyi O. Fadeyi et al.   ORGANIC LETTERS

Regio- and Stereoselective Synthesis of Fluoroalkenes by Directed Au(I) Catalysis

(2009) Benjamin C. Gorske et al.   ORGANIC LETTERS

Fluorination of Boronic Acids Mediated by Silver(I) Triflate

(2009) Takeru Furuya et al.   ORGANIC LETTERS

Palladium‐Catalyzed Oxidative Cyclization of Enynes with Hydrogen Peroxide as the Oxidant

(2008) Guoyin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Alkoxyhalogenation of β-Hydroxy-α,α-Difluoroynones

(2008) Marie Schuler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Antibacterial Activity of Novel Pyrido[1,2,3-de][1,4]benzoxazine-6-carboxylic Acid Derivatives Carrying the 3-Cyclopropylaminomethyl-4-substituted-1-pyrrolidinyl Group as a C-10 Substituent

(2008) Yoshikazu Asahina et al.   JOURNAL OF MEDICINAL CHEMISTRY

Kinesin Spindle Protein (KSP) Inhibitors. 9. Discovery of (2S)-4-(2,5-Difluorophenyl)-N-[(3R,4S)-3-fluoro-1-methylpiperidin-4-yl]-2-(hydroxymethyl)-N-methyl-2-phenyl-2,5-dihydro-1H-pyrrole-1-carboxamide (MK-0731) for the Treatment of Taxane-Refractory Cancer

(2008) Christopher D. Cox et al.   JOURNAL OF MEDICINAL CHEMISTRY

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

InX3-catalyzed haloamidation of vinyl arenes: a facile synthesis of α-bromo- and α-fluoroamides

(2008) J.S. Yadav et al.   TETRAHEDRON LETTERS