New Life for Diazoacetonitrile (N2CHCN): in situ Generation and Practical Synthesis of CN-Pyrazoles

Three-component synthesis of C2F5-substituted pyrazoles from C2F5CH2NH2·HCl, NaNO2and electron-deficient alkynes

(2015) Pavel K Mykhailiuk   Beilstein Journal of Organic Chemistry

Three-component synthesis of fluorinated pyrazoles from fluoroalkylamines, NaNO2 and electron-deficient alkynes

(2015) Pavel K. Mykhailiuk   ORGANIC & BIOMOLECULAR CHEMISTRY

Microwave-assisted preparation of 4-amino-3-cyano-5-methoxycarbonyl-N-arylpyrazoles as building blocks for the diversity-oriented synthesis of pyrazole-based polycyclic scaffolds

(2015) Laurent Le Corre et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Diastereoselective Synthesis of Vicinally Bis(trifluoromethylated) Alkylboron Compounds through Successive Insertions of 2,2,2-Trifluorodiazoethane

(2014) Gary A. Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of C2F5CHN2In Situ and Its First Reaction: [3+2] Cycloaddition with Alkenes

(2014) Pavel K. Mykhailiuk    CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products

(2014) Heng-Ying Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Taming Hazardous Chemistry in Flow: The Continuous Processing of Diazo and Diazonium Compounds

(2014) Benjamin J. Deadman et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Trifluoromethyl-Substituted 3-Azabicyclo[n.1.0]alkanes: Advanced Building Blocks for Drug Discovery

(2014) Olexiy S. Artamonov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Specific 1,2-Hydride Shift in the Boron Trifluoride Catalyzed Reactions of Aromatic Aldehydes with Diazoacetonitrile: Simple Synthesis of β-Ketonitriles

(2014) Zhanhui Yang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of CF3-Substituted Pyrazolines/Pyrazoles from Electron-Deficient Alkenes/Alkynes and CF3CHN2Generated in situ: Optimized Synthesis of Tris(trifluoromethyl)pyrazole

(2014) Evgeniy Y. Slobodyanyuk et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Direct Copper-Promoted Three-Component Entry to Trifluoromethylketoximes

(2014) Shuai Wang et al.   ORGANIC LETTERS

Regioselective Cycloaddition of Trifluorodiazoethane with Electron-Deficient Allenic Esters and Ketones: Access to CF3-Substituted Pyrazolines and Pyrazoles

(2014) Fa-Guang Zhang et al.   ORGANIC LETTERS

Synthesis of Functionalized Cyanopyrazoles via Magnesium Bases

(2014) Allan Dishington et al.   ORGANIC LETTERS

Synthesis and Applications of α-Trifluoromethylated Alkylboron Compounds

(2013) O. Andreea Argintaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Cycloaddition of Alkynes with CF3CHN2: Highly Regioselective Synthesis of 3-Trifluoromethylpyrazoles

(2013) Feng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ethyl diazoacetate synthesis in flow

(2013) Mariëlle M E Delville et al.   Beilstein Journal of Organic Chemistry

Continuous flow synthesis of toxic ethyl diazoacetate for utilization in an integrated microfluidic system

(2013) Ram Awatar Maurya et al.   GREEN CHEMISTRY

Synthesis of Trifluoromethylated Isoxazolidines: 1,3-Dipolar Cycloaddition of Nitrosoarenes, (Trifluoromethyl)diazomethane, and Alkenes

(2013) Gary A. Molander et al.   ORGANIC LETTERS

Homologative Trifluoromethylation of Acetals

(2013) Erick Carreira et al.   SYNTHESIS-STUTTGART

A Facile Parallel Synthesis of Trifluoroethyl-Substituted Alkynes

(2012) Cui-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Activation of Diazo Compounds Using Electron-Rich, Defined Iron Complexes for Carbene-Transfer Reactions

(2012) Michael S. Holzwarth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Cyclopropanation with Glycine Ethyl Ester Hydrochloride in Water

(2012) Bill Morandi et al.   ORGANIC LETTERS

Preparation of Trifluoromethyl-Substituted Aziridines with in Situ Generated CF3CHN2

(2012) Stefan A. Künzi et al.   ORGANIC LETTERS

Synthesis of Trifluoroethyl-Substituted Ketones from Aldehydes and Cyclohexanones

(2011) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Preparation of Trifluoromethyl Substituted Vinyl- and Alkynylcyclopropanes

(2011) Bill Morandi et al.   ORGANIC LETTERS

Expedient Preparation of Trifluoromethyl-Substituted Benzofuranols

(2011) Bill Morandi et al.   ORGANIC LETTERS

Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Cyclopropenation of Alkynes: Synthesis of Trifluoromethyl-Substituted Cyclopropenes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-Component Reaction Using the Bestmann-Ohira Reagent: A Regioselective Synthesis of Phosphonyl Pyrazole Rings

(2010) Kishor Mohanan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetics and regioselectivity in the Diels–Alder reaction of fulleroids vs. methanofullerene and C60

(2010) Naohiko Ikuma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron-Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane

(2009) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Syntheses of Diazo Compounds

(2009) Gerhard Maas   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent development of reactions with α-diazocarbonyl compounds as nucleophiles

(2009) Yan Zhang et al.   CHEMICAL COMMUNICATIONS

Synthesis of Trifluoromethyl‐Substituted Proline Analogues as19F NMR Labels for Peptides in the Polyproline II Conformation

(2008) Pavel K. Mykhailiuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION