4.7 Article

Direct Allylation of Quinones with Allylboronates

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 80, Issue 6, Pages 3343-3348

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00264

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Funding

  1. Swedish Research Council (VR)
  2. Knut och Alice Wallenbergs Foundation

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Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.

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