A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Approach To Construct Unsymmetrical Biaryls through Oxidative Coupling Reactions of Aromatic Primary Alcohols and Arylboronic Acids with a Rhodium Catalyst

(2016) Xiaobo Yu et al.   ORGANOMETALLICS

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols

(2015) Naoki Ishida et al.   CHEMICAL COMMUNICATIONS

Chiral Cationic CpxRu(II) Complexes for Enantioselective Yne-Enone Cyclizations

(2015) David Kossler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation

(2015) Fedor Romanov-Michailidis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

(2015) Tiffany Piou et al.   NATURE

Rhodium(III)-Catalyzed C–H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate

(2015) Tomislav Rovis et al.   SYNLETT

Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

(2015) Todd K. Hyster et al.   Chemical Science

Cobalt(III)-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds through β-Carbon Cleavage of Alcohols

(2015) Erhan Ozkal et al.   ACS Catalysis

Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions

(2014) Yuki Hoshino et al.   ADVANCED SYNTHESIS & CATALYSIS

Ligand-Controlled Regiodivergent Pathways of Rhodium(III)-Catalyzed Dihydroisoquinolone Synthesis: Experimental and Computational Studies of Different Cyclopentadienyl Ligands

(2014) Matthew D. Wodrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective C–H Bond Addition of Pyridines to Alkenes Catalyzed by Chiral Half-Sandwich Rare-Earth Complexes

(2014) Guoyong Song et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes

(2014) Tiffany Piou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steric and Electronic Effects Influencing β-Aryl Elimination in the Pd-catalyzed Carbon–Carbon Single Bond Activation of Triarylmethanols

(2013) James R. Bour et al.   JOURNAL OF ORGANIC CHEMISTRY

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploitation of Rh(i)–Rh(iii) cycles in enantioselective C–C bond cleavages: access to β-tetralones and benzobicyclo[2.2.2]octanones

(2013) Laetitia Souillart et al.   Chemical Science

Recent Advances in the Metal-Catalyzed Ring Expansions of Three- and Four-Membered Rings

(2013) Daniel J. Mack et al.   ACS Catalysis

Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

(2012) Klaus Ruhland   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Ring Opening of Benzocyclobutenols with Site-Selectivity Complementary to Thermal Ring Opening

(2012) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Synthesis of Group 9 Metal-Olefin Complexes with Identical Ligand Frameworks and Comparison of their Catalytic Activity in [2+2+2] Cycloaddition and other Addition Reactions

(2011) Nico Weding et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic [2+2+1] Cross-Cyclotrimerization of Silylacetylenes and Two Alkynyl Esters To Produce Substituted Silylfulvenes

(2011) Yu Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cptprovide complementary selectivity

(2011) Todd K. Hyster et al.   CHEMICAL COMMUNICATIONS

Synthesis of 3,3-disubstituted α-tetralones by rhodium-catalysed reaction of 1-(2-haloaryl)cyclobutanols

(2011) Naoki Ishida et al.   CHEMICAL COMMUNICATIONS

A Density Dependent Dispersion Correction

(2011) Stephan N. Steinmann et al.   CHIMIA

A generalized-gradient approximation exchange hole model for dispersion coefficients

(2011) Stephan N. Steinmann et al.   JOURNAL OF CHEMICAL PHYSICS

Comprehensive Benchmarking of a Density-Dependent Dispersion Correction

(2011) Stephan N. Steinmann et al.   Journal of Chemical Theory and Computation

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis

(2011) Todd K. Hyster et al.   Chemical Science

The COSMO and COSMO-RS solvation models

(2011) Andreas Klamt   Wiley Interdisciplinary Reviews-Computational Molecular Science

Palladium-Catalyzed Arylative Ring-Opening Reactions of Norbornenols: Entry to Highly Substituted Cyclohexenes, Quinolines, and Tetrahydroquinolines

(2010) Michael Waibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Rhodium(I)-Catalyzed Enantioselective Activation of Cyclobutanols: Formation of Cyclohexane Derivatives with Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   CHEMISTRY-A EUROPEAN JOURNAL

A System-Dependent Density-Based Dispersion Correction

(2010) Stephan N. Steinmann et al.   Journal of Chemical Theory and Computation

Palladium-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols Bearing a Trisubstituted Double Bond: Application to Chirality Transfer from Hydroxylated Carbon to Benzylic One

(2010) Ryota Wakabayashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis

(2009) Hideki Yorimitsu et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3-Alkynyl-1-indanones

(2008) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C−H and C−C Bond Cleavages

(2007) Toshihiko Uto et al.   JOURNAL OF ORGANIC CHEMISTRY