1,3,2-Diazaborolyl Anions - From Laboratory Curiosities to Versatile Reagents in Synthesis

A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene

(2016) Takuto Ohsato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Boryl-Substituted Diphosphene: Synthesis, Structure, and Reaction with n -Butyllithium To Form a Stabilized Adduct by pπ-pπ Interaction

(2016) Shun-suke Asami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stabilization of a two-coordinate, acyclic diaminosilylene (ADASi): completion of the series of isolable diaminotetrylenes, :E(NR2)2 (E = group 14 element)

(2016) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Regioselective Catalytic and Stepwise Routes to Bulky, Functional-Group-Appended, and Luminescent 1,2-Azaborinines

(2016) Marius Schäfer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

(2016) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Qualitative Analysis of a “Bora-Brook Rearrangement”: The Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group

(2016) Haruki Kisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles

(2016) Wei Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Isolation, structure and reactivity of a scandium boryl oxycarbene complex

(2016) Baoli Wang et al.   Chemical Science

Cobalt Boryl Complexes: Enabling and Exploiting Migratory Insertion in Base-Metal-Mediated Borylation

(2015) René Frank et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Borylation using an Air-Stable Zinc Boryl Reagent: Systematic Access to Elusive Acylboranes

(2015) Jesús Campos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium bis(diazaborolyl): old neighbors finally shake hands

(2015) T. Arnold et al.   CHEMICAL COMMUNICATIONS

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

(2015) Deepak Dange et al.   CHEMICAL COMMUNICATIONS

The role of 2,3-dihydro-1-H-1,3,2-diazaboroles in luminescent molecules

(2015) Lothar Weber et al.   COORDINATION CHEMISTRY REVIEWS

Selective B–B bond activation in an unsymmetrical diborane(4) by [(Me3P)4Rh–X] (X = Me, OtBu): a switch of mechanism?

(2015) C. Borner et al.   DALTON TRANSACTIONS

Reactivity of Boryl- and Silyl-Substituted Carbenoids toward Alkynes: Insertion and Cycloaddition Chemistry

(2015) Andrey V. Protchenko et al.   ORGANOMETALLICS

Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and iPr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes

(2015) Keita Tanoue et al.   ORGANOMETALLICS

Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen

(2014) Nicole Dettenrieder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective CH Activation at theortho-Position

(2014) Sabrina I. Kalläne et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Reagent for the One-Step Preparation of Potassium Acyltrifluoroborates (KATs) from Aryl- and Heteroarylhalides

(2014) Gábor Erős et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heavy metal boryl chemistry: complexes of cadmium, mercury and lead

(2014) Andrey V. Protchenko et al.   CHEMICAL COMMUNICATIONS

A bidentate boryl ligand: syntheses of platinum and iridium complexes

(2014) H. Schubert et al.   CHEMICAL COMMUNICATIONS

Antiaromaticity to Aromaticity: From Boroles to 1,2-Azaborinines by Ring Expansion with Azides

(2014) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

BN Heterosuperbenzenes: Synthesis and Properties

(2014) Xiao-Ye Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Half-sandwich scandium boryl complexes bearing a silylene-linked cyclopentadienyl-amido ligand

(2014) Baoli Wang et al.   DALTON TRANSACTIONS

Reactivity of boryllithium with AlMe3, AlEt3, and GaMe3, including the synthesis of a lanthanum heterogallate complex

(2014) Nicole Dettenrieder et al.   DALTON TRANSACTIONS

Versatile reactivity of a rhodium(i) boryl complex towards ketones and imines

(2014) Sabrina I. Kalläne et al.   DALTON TRANSACTIONS

Selective Synthesis of Unsymmetrical Diboryl PtIIand Diaminoboryl CuIComplexes by B-B Activation of Unsymmetrical Diboranes(4) {pinB-B[(NR)2C6H4]}

(2014) Corinna Borner et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Circumventing Redox Chemistry: Synthesis of Transition Metal Boryl Complexes from a Boryl Nucleophile by Decarbonylation

(2014) René Frank et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Bond Formation and Reductive Bond Cleavage at Main Group Metal Centers: Reactivity of Five-Valence-Electron MX2 Radicals

(2014) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable GaX2, InX2 and TlX2 radicals

(2014) Andrey V. Protchenko et al.   Nature Chemistry

Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing a Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation

(2014) Takuma Miyada et al.   ORGANOMETALLICS

Half-Sandwich Rare-Earth-Metal Alkylaluminate Complexes Bearing Peripheral Boryl Ligands

(2014) Nicole Dettenrieder et al.   ORGANOMETALLICS

Arrested B–H Activation en Route to Installation of a PBP Pincer Ligand on Ruthenium and Osmium

(2014) Anthony F. Hill et al.   ORGANOMETALLICS

Synthesis and chemoselective ligations of MIDA acylboronates with O-Me hydroxylamines

(2014) Hidetoshi Noda et al.   Chemical Science

Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion

(2013) David A. Ruiz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphines with N-heterocyclic boranyl substituents

(2013) M. Kaaz et al.   DALTON TRANSACTIONS

Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia

(2013) Michael Teltewskoi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

(2013) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

BN isosteres of indole

(2013) Eric R. Abbey et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Oxygenation of a Ruthenium Complex Bearing a PBP-Pincer Ligand Inducing the Formation of a Boronato Ligand with a Weak Ru–O Bond

(2013) Takuma Miyada et al.   ORGANOMETALLICS

Organoaluminum Boryl Complexes

(2012) Nicole Dettenrieder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

(2012) Aaron M. Dumas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Azaborine Chemistry

(2012) Patrick G. Campbell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

(2012) Hayato Ogawa et al.   DALTON TRANSACTIONS

Rare Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide

(2011) Shihui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−

(2011) Eduard Bernhardt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Group 3 and Lanthanide Boryl Compounds: Syntheses, Structures, and Bonding Analyses of Sc−B, Y−B, and Lu−B σ-Coordinated NHC Analogues

(2011) Liban M. A. Saleh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

(2010) Michael Teltewskoi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion

(2010) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

(2010) Julien Monot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Boryl Anion: Syntheses and Properties of Novel Borylmetals

(2010) Makoto Yamashita et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†

(2010) José Vicente et al.   ORGANOMETALLICS

Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes†

(2010) Anthony F. Hill et al.   ORGANOMETALLICS

Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

(2009) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Iron Acyl Complexes Modeling the Active Site of [Fe]-Hydrogenase

(2009) Dafa Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium−Ethylene Complexes

(2009) Yasutomo Segawa et al.   ORGANOMETALLICS

A Linear, Anionic Dimetalloborylene Complex

(2008) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments of Boryl Anions: Boron Analogues of Carbanion

(2008) Makoto Yamashita et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

B-N as a C-C substitute in aromatic systems

(2008) Michael J.D Bosdet et al.   CANADIAN JOURNAL OF CHEMISTRY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2-Azaborolyl-Ligated Half-Sandwich Complexes of Scandium(III) and Lutetium(III): Synthesis, Structures, and Syndiotactic Polymerization of Styrene†

(2008) Xiangdong Fang et al.   ORGANOMETALLICS

Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes

(2008) Makoto Yamashita et al.   PURE AND APPLIED CHEMISTRY