Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine

Cyclic Hypervalent Iodine Reagents for Atom-Transfer Reactions: Beyond Trifluoromethylation

(2016) Yifan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Synthetic Applications of Hypervalent Iodine Compounds

(2016) Akira Yoshimura et al.   CHEMICAL REVIEWS

Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies

(2016) Xiangcheng Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Induced Alkoxyl Radical Generation Enables Selective C(sp3)–C(sp3) Bond Cleavage and Functionalizations

(2016) Kunfang Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry

(2016) Takashi Koike et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds

(2016) Yaxin Wang et al.   Chemical Science

Direct alkylation of heteroarenes with unactivated bromoalkanes using photoredox gold catalysis

(2016) T. McCallum et al.   Chemical Science

Metal-Free Oxidative Decarbonylative Coupling of Aliphatic Aldehydes with Azaarenes: Successful Minisci-Type Alkylation of Various Heterocycles

(2015) Ren-Jin Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Sunlight-Driven Decarboxylative Alkynylation of α-Keto Acids with Bromoacetylenes by Hypervalent Iodine Reagent Catalysis: A Facile Approach to Ynones

(2015) Hui Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

(2015) Mirna El Khatib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room-Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents

(2015) Franck Le Vaillant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Alkynylation and Carbonylative Alkynylation of Carboxylic Acids Enabled by Visible-Light Photoredox Catalysis

(2015) Quan-Quan Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System

(2015) York Schramm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

Regioselective Metal-Free Cross-Coupling of Quinoline N-Oxides with Boronic Acids

(2015) Luis Bering et al.   ORGANIC LETTERS

Nickel-Catalyzed Selective Oxidative Radical Cross-Coupling: An Effective Strategy for Inert Csp3–H Functionalization

(2015) Dong Liu et al.   ORGANIC LETTERS

DFT as a Powerful Predictive Tool in Photoredox Catalysis: Redox Potentials and Mechanistic Analysis

(2015) Taye B. Demissie et al.   ORGANOMETALLICS

Hypervalent Iodine(III) in Direct Carbon–Hydrogen Bond Functionalization

(2015) Andrey Antonchick et al.   SYNLETT

Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis

(2014) Hanchu Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

(2014) Daniel A. DiRocco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct α-Arylation of Ethers through the Combination of Photoredox-Mediated CH Functionalization and the Minisci Reaction

(2014) Jian Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free CH Bond Activation of Branched Aldehydes with a Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis: Successful Trapping with Electron-Deficient Olefins

(2014) Shin A. Moteki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Chemoselective Deboronative Alkynylation under Biomolecule-Compatible Conditions

(2014) Hanchu Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions

(2013) Heike Schönherr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Selective Oxidative Cross-Coupling of Simple Alkanes with Heteroarenes

(2013) Andrey P. Antonchick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver catalyzed decarboxylative direct C2-alkylation of benzothiazoles with carboxylic acids

(2013) Wei-Ming Zhao et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Synthesis and Minisci Reactions of Organotrifluoroborato Building Blocks

(2013) Marc Presset et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C–H Activation/Cross-Coupling of Pyridine N-Oxides with Nonactivated Secondary Alkyl Bromides

(2013) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

When C–H bond functionalization meets visible-light photoredox catalysis

(2013) Jin Xie et al.   TETRAHEDRON LETTERS

Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

(2012) Yusuke Yasu et al.   ADVANCED SYNTHESIS & CATALYSIS

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Practical C−H Functionalization of Quinones with Boronic Acids

(2011) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Palladium-Catalyzed Minisci Reaction with Simple Alcohols

(2011) Camille A. Correia et al.   ORGANIC LETTERS

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Minisci reactions: Versatile CH-functionalizations for medicinal chemists

(2011) Matthew A. J. Duncton   MedChemComm

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Privileged scaffolds for library design and drug discovery

(2010) Matthew E Welsch et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Estimation of Standard Reduction Potentials of Halogen Atoms and Alkyl Halides

(2010) Abdirisak A. Isse et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleohomolytic Substitution at Boron: A Computational Approach

(2008) Claudio Carra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY