Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

(2016) Javad Amani et al.   ORGANIC LETTERS

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

(2015) Mirna El Khatib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Electron Transmetalation: Synthesis of 1,1-Diaryl-2,2,2-trifluoroethanes by Photoredox/Nickel Dual Catalytic Cross-Coupling

(2015) DaWeon Ryu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organotrifluoroborates: Another Branch of the Mighty Oak

(2015) Gary A. Molander   JOURNAL OF ORGANIC CHEMISTRY

Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

(2015) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis

(2015) Naoki Noto et al.   ORGANIC LETTERS

Boron chemistry in a new light

(2015) Guillaume Duret et al.   Chemical Science

Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis

(2015) Yanjie Li et al.   Organic Chemistry Frontiers

Generation of Arylated Quinones by Iron-Catalyzed Oxidative Arylation of Phenols: Formal Synthesis of Phellodonin, Sarcodonin ε, Leucomelone and Betulinan A

(2014) Arghya Deb et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis

(2014) Kazuki Miyazawa et al.   ADVANCED SYNTHESIS & CATALYSIS

Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α-Trifluoromethylated Ketones from Aromatic Alkenes

(2014) Ren Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Induced Chemoselective Deboronative Alkynylation under Biomolecule-Compatible Conditions

(2014) Hanchu Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids

(2014) Yusuke Yasu et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Visible-light radical reaction designed by Ru- and Ir-based photoredox catalysis

(2014) Takashi Koike et al.   Inorganic Chemistry Frontiers

The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

(2013) Kazuki Miyazawa et al.   CHEMICAL COMMUNICATIONS

Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis

(2013) Yusuke Yasu et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Copper-Catalyzed Oxidative Heck Reactions between Alkyltrifluoroborates and Vinyl Arenes

(2013) Timothy W. Liwosz et al.   ORGANIC LETTERS

Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

(2013) Yusuke Yasu et al.   ORGANIC LETTERS

Recent Applications of Organic Dyes as Photoredox Catalysts in Organic Synthesis

(2013) David A. Nicewicz et al.   ACS Catalysis

Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

(2012) Yusuke Yasu et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aggregation induced emission (AIE) of trifluoromethyl substituted distyrylbenzenes

(2012) Zhengwei Shi et al.   CHEMICAL COMMUNICATIONS

Photoorganocatalysis. What for?

(2012) Davide Ravelli et al.   CHEMICAL SOCIETY REVIEWS

Design of Potent and Selective Hybrid Inhibitors of the Mitotic Kinase Nek2: Structure–Activity Relationship, Structural Biology, and Cellular Activity

(2012) Paolo Innocenti et al.   JOURNAL OF MEDICINAL CHEMISTRY

Determination of the Structural Features of a Long-Lived Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion

(2012) Manabu Hoshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

FeSO4-promoted direct arylation of benzoquinones with ArB(OH)2 or ArBF3K

(2012) Kimihiro Komeyama et al.   TETRAHEDRON LETTERS

Selective photocatalytic reactions with organic photocatalysts

(2012) Shunichi Fukuzumi et al.   Chemical Science

Practical C−H Functionalization of Quinones with Boronic Acids

(2011) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Radical Cyclizations with Arylboronic Acids and Trifluoroborates

(2011) Jonathan W. Lockner et al.   ORGANIC LETTERS

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Selective photocatalytic aerobic bromination with hydrogen bromide via an electron-transfer state of 9-mesityl-10-methylacridinium ion

(2011) Kei Ohkubo et al.   Chemical Science

Oxidation of Alkyl Trifluoroborates: An Opportunity for Tin-Free Radical Chemistry

(2010) Geoffroy Sorin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

1,4-Bis(alkenyl)-2,5-dipiperidinobenzenes: Minimal Fluorophores Exhibiting Highly Efficient Emission in the Solid State

(2009) Masaki Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simultaneous production of p-tolualdehyde and hydrogen peroxide in photocatalytic oxygenation of p-xylene and reduction of oxygen with 9-mesityl-10-methylacridinium ion derivatives

(2009) Kei Ohkubo et al.   CHEMICAL COMMUNICATIONS

Ritter-type amidation of alkylboron derivatives with nitriles

(2009) Clément Cazorla et al.   TETRAHEDRON LETTERS

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS

Enantioselective Organo-SOMO Catalysis:  The α-Vinylation of Aldehydes

(2007) Hahn Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY