Hydrosilylation of Ketones, Imines and Nitriles Catalysed by Electrophilic Phosphonium Cations: Functional Group Selectivity and Mechanistic Considerations

Towards High-Performance Lewis Acid Organocatalysis

(2014) Lars Ratjen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates

(2013) Muhammad Sajid et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Natural triple excitations in local coupled cluster calculations with pair natural orbitals

(2013) Christoph Riplinger et al.   JOURNAL OF CHEMICAL PHYSICS

Reaction of a Bridged Frustrated Lewis Pair with Nitric Oxide: A Kinetics Study

(2013) José Clayston Melo Pereira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbonylation Reactions of Intramolecular Vicinal Frustrated Phosphane/Borane Lewis Pairs

(2013) Muhammad Sajid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic Organofluorophosphonium Salts

(2013) Manuel Pérez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

TBAF-catalyzed hydrosilylation for the reduction of aromatic nitriles

(2013) Christoph Bornschein et al.   NEW JOURNAL OF CHEMISTRY

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

The First Row Anomaly and Recoupled Pair Bonding in the Halides of the Late p-Block Elements

(2012) Thom H. Dunning et al.   ACCOUNTS OF CHEMICAL RESEARCH

Phosphorus as a Lewis Acid: CO2Sequestration with Amidophosphoranes

(2012) Lindsay J. Hounjet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

(2012) Shoubhik Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Binding Thermodynamics by Dispersion-Corrected Density Functional Theory

(2012) Stefan Grimme   CHEMISTRY-A EUROPEAN JOURNAL

The Lewis acidity of fluorophosphonium salts: access to mixed valent phosphorus(iii)/(v) species

(2012) Lindsay J. Hounjet et al.   DALTON TRANSACTIONS

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Metal-Free Activation of Dihydrogen by Antiaromatic Pentarylboroles

(2012) Adrian Y. Houghton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(II) triflate-catalyzed reduction of carboxylic acids to alcohols and reductive etherification of carbonyl compounds

(2012) Yin-Jie Zhang et al.   TETRAHEDRON

Selective Reduction of Carboxylic Acid Derivatives by Catalytic Hydrosilylation

(2011) Daniele Addis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex

(2011) Jürgen Koller et al.   ORGANOMETALLICS

A thorough benchmark of density functional methods for general main group thermochemistry, kinetics, and noncovalent interactions

(2011) Lars Goerigk et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The ORCA program system

(2011) Frank Neese   Wiley Interdisciplinary Reviews-Computational Molecular Science

Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV-Oxo Complexes

(2010) Kristine A. Nolin et al.   CHEMISTRY-A EUROPEAN JOURNAL

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance

(2010) Shoubhik Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic Reductions of Amides and Nitriles to Amines

(2010) Shoubhik Das et al.   TOPICS IN CATALYSIS

Phosphonium Salt Organocatalysis

(2009) Thomas Werner   ADVANCED SYNTHESIS & CATALYSIS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3-Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding

(2009) Daniel T. Hog et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Titanocene-Catalyzed Hydrosilylation of Imines: Experimental and Computational Investigations of the Catalytically Active Species

(2009) Heidrun Gruber-Woelfler et al.   ORGANOMETALLICS

A mild and efficient method for the reduction of nitriles

(2009) Stéphane Laval et al.   TETRAHEDRON LETTERS

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluoride Ion Chelation By a Bidentate Phosphonium/Borane Lewis Acid

(2008) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY