Examining the effects of additives and precursors on the reactivity of rhodium alkyl nitrenes generated from substituted hydroxylamines

A Missing Link in Multisubstituted Pyrrolidines: Remote Stereocontrol Forged by Rhodium‐Alkyl Nitrene

(2022) Xinxin Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source

(2021) Seung Youn Hong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalyst‐Controlled Chemoselective Nitrene Transfers

(2021) Hidetoshi Noda et al.   HELVETICA CHIMICA ACTA

Nitrene transfer catalysts for enantioselective C–N bond formation

(2021) Minsoo Ju et al.   Nature Reviews Chemistry

Imbuing an Old Heterocycle with the Power of Modern Catalysis: An Isoxazolidin-5-one Story

(2021) Hidetoshi Noda   CHEMICAL & PHARMACEUTICAL BULLETIN

Ligand-Enabled, Copper-Catalyzed Electrophilic Amination for the Asymmetric Synthesis of β-Amino Acids

(2021) Raj K. Tak et al.   ORGANIC LETTERS

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

(2020) Aaron Trowbridge et al.   CHEMICAL REVIEWS

O-Benzoylhydroxylamines as Alkyl Nitrene Precursors: Synthesis of Saturated N-Heterocycles from Primary Amines

(2020) Hidetoshi Noda et al.   ORGANIC LETTERS

Traceless Electrophilic Amination for the Synthesis of Unprotected Cyclic β-Amino Acids

(2019) Jin-Sheng Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Unprotected Spirocyclic β-Prolines and β-Homoprolines by Rh-Catalyzed C–H Insertion

(2019) Miguel Espinosa et al.   ORGANIC LETTERS

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Catalyst-Controlled Diastereoselective Synthesis of Cyclic Amines via C-H Functionalization

(2017) Sailu Munnuri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

(2017) Bidraha Bagh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Syntheses of Isoxazolidin-5-ones

(2017) Jean-François Brière et al.   SYNTHESIS-STUTTGART

Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity

(2016) Adrián Varela-Álvarez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation

(2016) Nathan C. Thacker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dirhodium-catalyzed C-H arene amination using hydroxylamines

(2016) M. P. Paudyal et al.   SCIENCE

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

(2015) Dawen Niu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

(2014) Edon Vitaku et al.   JOURNAL OF MEDICINAL CHEMISTRY

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

(2014) Hidetoshi Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins

(2014) Jawahar L. Jat et al.   SCIENCE

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Copper-Nitrene Complexes in Catalytic CH Amination

(2008) Yosra M. Badiei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

(2008) M. Mar Díaz-Requejo et al.   CHEMICAL REVIEWS

A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction

(2008) Kristin Williams Fiori et al.   TETRAHEDRON