Nitrene transfer catalysts for enantioselective C–N bond formation

Complementing Pyridine‐2,6‐bis(oxazoline) with Cyclometalated N‐Heterocyclic Carbene for Asymmetric Ruthenium Catalysis

(2020) Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rigidifying Ag(I) Complexes for Selective Nitrene Transfer

(2020) Minxue Huang et al.   ChemCatChem

A Chiral Phenanthroline Ligand with a Hydrogen-Bonding Site: Application to the Enantioselective Amination of Methylene Groups

(2020) Rajasekar Reddy Annapureddy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Enantioselective Propargylic C–H Bond Amination through Rational Ligand Design

(2020) Minsoo Ju et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C–H Amidation

(2020) Caitlin M. B. Farr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral-at-Ruthenium Catalyst Does the Job: Access to Enantioenriched 2-Imidazolidinones

(2020) Nicolaas P. van Leest et al.   Chem

Chiral paddle-wheel diruthenium complexes for asymmetric catalysis

(2020) Taku Miyazawa et al.   Nature Catalysis

Enantioselective Desymmetrization of 1,3‐Disubstituted Adamantane Derivatives via Rhodium‐Catalyzed C−H Bond Amination: Access to Optically Active Amino Acids Containing Adamantane Core

(2020) Risa Yasue et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium Pybox-Catalyzed Enantioselective Intramolecular C–H Amination of Sulfamoyl Azides en Route to Chiral Vicinal Diamines

(2020) Xin Nie et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioconvergent Amination of Racemic Tertiary C–H Bonds

(2020) Kai Lang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Radical C–H Amination

(2020) Li-Mei Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New-Generation D2-Symmetric Chiral Porphyrins for Co(II)-Based Metalloradical Catalysis: Catalyst Engineering via Distal Bridging

(2019) X. Peter Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*Co(III)/MPAA-Catalyzed Enantioselective Amidation of Ferrocenes Directed by Thioamides under Mild Conditions

(2019) Yan-Hua Liu et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed Enantioselective γ-Lactams Formation by Intramolecular C–H Amidation of 1,4,2-Dioxazol-5-ones

(2019) Qi Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intermolecular Benzylic C(sp3 )−H Amination

(2019) Ali Nasrallah et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions

(2019) Hao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution

(2019) Kai Lang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral 2-Aryl Ferrocene Carboxylic Acids for the Catalytic Asymmetric C(sp3)–H Activation of Thioamides

(2019) Daichi Sekine et al.   ORGANOMETALLICS

Tunable catalyst-controlled syntheses of β- and γ-amino alcohols enabled by silver-catalysed nitrene transfer

(2019) Minsoo Ju et al.   Nature Catalysis

Catalytic Enantioselective Methylene C(sp3 )−H Amidation of 8-Alkylquinolines Using a Cp*RhIII /Chiral Carboxylic Acid System

(2019) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C–H Amination

(2019) Yang Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Non-C2-Symmetric Chiral-at-Ruthenium Catalyst for Highly Efficient Enantioselective Intramolecular C(sp3)–H Amidation

(2019) Zijun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrene Transfer Reactions for Asymmetric C-H Amination: Recent Development

(2019) Hiroki Hayashi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Intermolecular C(sp3)–H Amination with Sulfamates for the Asymmetric Synthesis of Amines

(2019) Ali Nasrallah et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Carbenes and Nitrenes: Recent Developments in Fundamental Chemistry

(2018) Curt Wentrup   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Catalytic Radical Process for Enantioselective Amination of C(sp3 )−H Bonds

(2018) Chaoqun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

(2018) Seiya Fukagawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Intramolecular C(sp3 )−H Amination of 2-Azidoacetamides

(2018) Zijun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational advances aiding mechanistic understanding of silver-catalyzed carbene/nitrene/silylene transfer reactions

(2018) Jing Zhang et al.   COORDINATION CHEMISTRY REVIEWS

Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis

(2017) Yu Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inverting Steric Effects: Using “Attractive” Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer

(2017) Minxue Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis

(2017) Huiling Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity

(2017) Cale Weatherly et al.   ORGANOMETALLICS

Catalytic C–H amination at its limits: challenges and solutions

(2017) Damien Hazelard et al.   Organic Chemistry Frontiers

Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity

(2016) Adrián Varela-Álvarez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies

(2016) Nicholas S. Dolan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion

(2016) Deng-Fu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Synthetic Procedures for the Iron-Catalyzed Intermolecular Olefin Aminohydroxylation Using Functionalized Hydroxylamines

(2016) Hao Xu et al.   SYNTHESIS-STUTTGART

Iron(ii)-catalyzed asymmetric intramolecular olefin aminochlorination using chloride ion

(2015) Cheng-Liang Zhu et al.   Chemical Science

Synthesis of chiralN-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis

(2014) Jingran Tao et al.   Beilstein Journal of Organic Chemistry

Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C-H Amination Using Azide Compounds as Nitrene Precursors

(2014) Tatsuya Uchida et al.   CHEMICAL RECORD

Recent Advances in the Stereoselective Synthesis of Aziridines

(2014) Leonardo Degennaro et al.   CHEMICAL REVIEWS

Enantioselective Construction of 2,3-Dihydrofuro[2,3-b]quinolines through Supramolecular Hydrogen Bonding Interactions

(2014) Fangrui Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Controlled, Tunable Silver-Catalyzed C–H Amination

(2014) Juliet M. Alderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions

(2014) Josep Llaveria et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effective Synthesis of ChiralN-Fluoroaryl Aziridines through Enantioselective Aziridination of Alkenes with Fluoroaryl Azides

(2013) Li-Mei Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Intermolecular Benzylic and Allylic CH Bond Amination

(2013) Yota Nishioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

(2013) Thorsten Höke et al.   CHEMICAL COMMUNICATIONS

A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

(2013) Lourdes Maestre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into C–H Amination via Dicopper Nitrenes

(2013) Mae Joanne B. Aguila et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Asymmetric Intramolecular Aminohydroxylation of Indoles

(2013) Yong-Qiang Zhang et al.   ORGANIC LETTERS

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

(2012) Chungsik Kim et al.   CHEMICAL COMMUNICATIONS

Ru(CO)-salen-Catalyzed Synthesis of Enantiopure Aziridinyl Ketones and Formal Asymmetric Synthesis of (+)-PD 128907

(2012) Yasuaki Fukunaga et al.   ORGANIC LETTERS

Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams

(2011) Masami Ichinose et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Update 1 of:C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis

(2011) Giovanni Desimoni et al.   CHEMICAL REVIEWS

C–H Functionalization in organic synthesis

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Catalytic C–H amination: the stereoselectivity issue

(2011) Florence Collet et al.   CHEMICAL SOCIETY REVIEWS

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Diruthenium Catalyst for Selective, Intramolecular Allylic C–H Amination: Reaction Development and Mechanistic Insight Gained through Experiment and Theory

(2011) Mark Edwin Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination

(2011) Kathrin H. Hopmann et al.   ACS Catalysis

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

(2009) Velusamy Subbarayan et al.   CHEMICAL COMMUNICATIONS

Nitrene transfer reactions mediated by metallo-porphyrin complexes

(2009) Simone Fantauzzi et al.   DALTON TRANSACTIONS

Catalytic Asymmetric Synthesis of (-)-Ritodrine Hydrochloride via Silyl Enol Ether Amination Using Dirhodium(II) Tetrakis[tetrafluorophthaloyl-(S)-tert-leucinate]

(2009) Shunichi Hashimoto et al.   HETEROCYCLES

Examination of the Role of Taft-Type Steric Parameters in Asymmetric Catalysis

(2009) Matthew S. Sigman et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective CH Amination Using Cationic Ruthenium(II)-pybox Catalysts

(2008) Erika Milczek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

(2008) M. Mar Díaz-Requejo et al.   CHEMICAL REVIEWS

Cobalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide

(2008) Jess E. Jones et al.   JOURNAL OF ORGANIC CHEMISTRY

A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination

(2008) David N. Zalatan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction

(2008) Kristin Williams Fiori et al.   TETRAHEDRON

Asymmetric formal synthesis of (−)-pancracine via catalytic enantioselective C–H amination process

(2008) Masahiro Anada et al.   TETRAHEDRON