Catalytic C–H bond functionalisation chemistry: the case for quasi-heterogeneous catalysis

Heterogeneously Catalyzed Direct CH Thiolation of Heteroarenes

(2015) Suhelen Vásquez-Céspedes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Hydrolysis and Alcoholysis of Palladium Acetate

(2015) Robin B. Bedford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active NO x Ligands in Palladium-Mediated Processes

(2015) Ian J. S. Fairlamb   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Metal–organic frameworks catalyzed C–C and C–heteroatom coupling reactions

(2015) Amarajothi Dhakshinamoorthy et al.   CHEMICAL SOCIETY REVIEWS

Palladium nanocrystals stabilized by cucurbit[6]uril as efficient heterogeneous catalyst for direct C–H functionalization of polyfluoroarenes

(2015) Minna Cao et al.   JOURNAL OF CATALYSIS

A Pd(ii)/Mg–La mixed oxide catalyst for cyanation of aryl C–H bonds and tandem Suzuki–cyanation reactions

(2015) Ramineni Kishore et al.   NEW JOURNAL OF CHEMISTRY

Nanocrystalline magnesium oxide-stabilized palladium(0): an efficient and reusable catalyst for synthesis of N-(2-pyridyl)indoles

(2015) Police Vishnuvardhan Reddy et al.   NEW JOURNAL OF CHEMISTRY

Unified mild reaction conditions for C2-selective Pd-catalysed tryptophan arylation, including tryptophan-containing peptides

(2015) Alan J. Reay et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Selective N-Chelation-Directed C–H Activation Reactions Catalyzed by Pd(II) Nanoparticles Supported on Multiwalled Carbon Nanotubes

(2015) Sudha Korwar et al.   ORGANIC LETTERS

High-performance liquid chromatography coupled with mass spectrometry for analysis of ultrasmall palladium nanoparticles

(2015) Lei Zhang et al.   TALANTA

Direct arylation and heterogeneous catalysis; ever the twain shall meet

(2015) Rafael Cano et al.   Chemical Science

C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

(2015) Karl D. Collins et al.   Chemical Science

Spatial imaging of carbon reactivity centers in Pd/C catalytic systems

(2015) E. O. Pentsak et al.   Chemical Science

Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

(2015) Joseph J. Topczewski et al.   Chemical Science

Solid phase synthesis of functionalized indazoles using triazenes – scope and limitations

(2015) Ana Maria Garcia et al.   RSC Advances

Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions

(2015) Sheng Wang et al.   RSC Advances

Synthesis of binary solid solution Cu–Pd nanoparticles by DMF reduction for enhanced photoluminescence properties

(2015) Masashi Chiba et al.   Journal of Materials Chemistry C

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium Nanoparticle-Catalyzed Direct Ethynylation of Aliphatic Carboxylic Acid DerivativesviaC(sp3)H Bond Functionalization

(2014) Mohammad Al-Amin et al.   ADVANCED SYNTHESIS & CATALYSIS

The Origin of Shape Sensitivity in Palladium-Catalyzed Suzuki-Miyaura Cross Coupling Reactions

(2014) Gillian Collins et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd/C as a Catalyst for Completely Regioselective CH Functionalization of Thiophenes under Mild Conditions

(2014) Dan-Tam D. Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I) and palladium nanoparticles supported on ethylenediamine-functionalized cellulose as an efficient catalyst for the 1,3-dipolar cycloaddition/direct arylation sequence

(2014) Sajjad Keshipour et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Direct C sp2H and C sp3H Arylation Enabled by Heterogeneous Palladium Catalysts

(2014) Laurent Djakovitch et al.   ChemCatChem

A mild and selective Pd-mediated methodology for the synthesis of highly fluorescent 2-arylated tryptophans and tryptophan-containing peptides: a catalytic role for Pd0 nanoparticles?

(2014) Thomas J. Williams et al.   CHEMICAL COMMUNICATIONS

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

(2014) Robert H. Crabtree   CHEMICAL REVIEWS

C-2 Selective Arylation of Indoles with Heterogeneous Nanopalladium and Diaryliodonium Salts

(2014) Joel Malmgren et al.   CHEMISTRY-A EUROPEAN JOURNAL

The First Example of ortho-Arylation of Benzamides over Pd/Mesoporous Silica: A Novel Approach for Direct sp2 C–H Bond Activation

(2014) T. Parsharamulu et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Palladium-Nanoparticle-Catalyzed 1,7-Palladium Migration Involving C–H Activation, Followed by Intramolecular Amination: Regioselective Synthesis of N1-Arylbenzotriazoles and an Evaluation of Their Inhibitory Activity toward Indoleamine 2,3-Dioxygenase

(2014) Koji Takagi et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed C–H Arylations, Benzylations, and Alkylations with Organic Electrophiles and Beyond

(2014) Lutz Ackermann   JOURNAL OF ORGANIC CHEMISTRY

Stability, Oxidation, and Shape Evolution of PVP-Capped Pd Nanocrystals

(2014) Gillian Collins et al.   Journal of Physical Chemistry C

Formation and propagation of well-defined Pd nanoparticles (PdNPs) during C–H bond functionalization of heteroarenes: are nanoparticles a moribund form of Pd or an active catalytic species?

(2014) Christoph G. Baumann et al.   TETRAHEDRON

Enhanced Catalytic Activity of High-Index Faceted Palladium Nanoparticles in Suzuki–Miyaura Coupling Due to Efficient Leaching Mechanism

(2014) Gillian Collins et al.   ACS Catalysis

A highly efficient and recyclable Fe3O4 magnetic nanoparticle immobilized palladium catalyst for the direct C-2 arylation of indoles with arylboronic acids

(2014) Lei Zhang et al.   Catalysis Science & Technology

“Homeopathic” Palladium Nanoparticle Catalysis of Cross Carbon–Carbon Coupling Reactions

(2013) Christophe Deraedt et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Palladium-Nanoparticle and Silicon-Nanowire-Array Hybrid: A Platform for Catalytic Heterogeneous Reactions

(2013) Yoichi M. A. Yamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis in flow: Operando study of Pd catalyst speciation and leaching

(2013) John B. Brazier et al.   CATALYSIS TODAY

Direct CH Bond Arylation of Indoles with Aryl Boronic Acids Catalyzed by Palladium Nanoparticles Encapsulated in Mesoporous Metal-Organic Framework

(2013) Yuanbiao Huang et al.   ChemCatChem

Synthesis of 2,5-Diarylpyrroles by Ligand-Free Palladium-Catalyzed CH Activation of Pyrroles in Ionic Liquids

(2013) Peter Ehlers et al.   ChemCatChem

N,N-Dimethylformamide-stabilized palladium nanoclusters as catalyst for Migita–Kosugi–Stille cross-coupling reactions

(2013) Hiroki Yano et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Completely Regioselective Direct C–H Functionalization of Benzo[b]thiophenes Using a Simple Heterogeneous Catalyst

(2013) Dan-Tam D. Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arene–Metal π-Complexation as a Traceless Reactivity Enhancer for C–H Arylation

(2013) Paolo Ricci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stability, surface features, and atom leaching of palladium nanoparticles: toward prediction of catalytic functionality

(2013) Hadi Ramezani-Dakhel et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Direct catalytic C–H arylation of imidazo[1,2-a]pyridine with aryl bromides using magnetically recyclable Pd–Fe3O4 nanoparticles

(2013) Jaewoo Lee et al.   TETRAHEDRON

A key role for iodobenzene in the direct C–H bond functionalisation of benzoxazoles using PhI(OAc)2 mediated by a Pd(OAc)2/1,10-phenanthroline catalyst system: in situ formation of well-defined Pd nanoparticles

(2013) Thomas J. Williams et al.   TETRAHEDRON LETTERS

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous versus Homogeneous Palladium Catalysts for Cross-Coupling Reactions

(2012) Mario Pagliaro et al.   ChemCatChem

Catalysis by metal nanoparticles embedded on metal–organic frameworks

(2012) Amarajothi Dhakshinamoorthy et al.   CHEMICAL SOCIETY REVIEWS

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

(2012) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd2(dba)3 as a Precursor of Soluble Metal Complexes and Nanoparticles: Determination of Palladium Active Species for Catalysis and Synthesis

(2012) Sergey S. Zalesskiy et al.   ORGANOMETALLICS

Manganese compounds in the catalysis of organic reactions

(2012) R. I. Khusnutdinov et al.   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

On the appearance of nitrite anion in [PdX(OAc)L2] and [Pd(X)(C^N)L] syntheses (X = OAc or NO2): photocrystallographic identification of metastable Pd(η1-ONO)(C^N)PPh3

(2012) Somia E. Bajwa et al.   Chemical Science

Nitrate as a redox co-catalyst for the aerobic Pd-catalyzed oxidation of unactivated sp3-C–H bonds

(2012) Kara J. Stowers et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Dispersed Palladium-Polypyrrole Nanocomposites: In-Water Synthesis and Application for Catalytic Arylation of Heteroaromatics by Direct C-H Bond Activation

(2011) Veronika A. Zinovyeva et al.   ADVANCED FUNCTIONAL MATERIALS

CC Bond Formation via CH Activation and CN Bond Formation via Oxidative Amination Catalyzed by Palladium- Polyoxometalate Nanomaterials Using Dioxygen as the Terminal Oxidant

(2011) Leng Leng Chng et al.   ADVANCED SYNTHESIS & CATALYSIS

Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions

(2011) Megumi Hyotanishi et al.   CHEMICAL COMMUNICATIONS

Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions

(2011) Árpád Molnár   CHEMICAL REVIEWS

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts

(2011) Robert H. Crabtree   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Pd nanoparticles for C–C coupling reactions

(2011) Angelica Balanta et al.   CHEMICAL SOCIETY REVIEWS

Small Pd Nanoparticles Supported in Large Pores of Mesocellular Foam: An Excellent Catalyst for Racemization of Amines

(2011) Mozaffar Shakeri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium Nanoparticles Encapsulated in a Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles

(2011) Yuanbiao Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Fully Palladium-Mediated Construction of Phenanthrenes and Naphthoxindoles

(2011) Luma Nassar-Hardy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Identification of the Active Species Generated from Supported Pd Catalysts in Heck Reactions: An in situ Quick Scanning EXAFS Investigation

(2011) Sven Reimann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2?In OperandoXAFS, Kinetic, and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4Cluster-Based Benzene Hydrogenation Catalysis

(2011) Ercan Bayram et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A smart palladium catalyst in ionic liquid for tandem processes

(2011) Eva Raluy et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Speciation of Pd(OAc)2in ligandless Suzuki–Miyaura reactions

(2011) Luis A. Adrio et al.   Catalysis Science & Technology

Evidence for the Surface-Catalyzed Suzuki-Miyaura Reaction over Palladium Nanoparticles: An Operando XAS Study

(2010) Peter J. Ellis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorous silica gel-supported perfluoro-tagged palladium nanoparticles: an efficient and reusable catalyst for direct C-2 arylation of indoles

(2010) Liang Wang et al.   CHEMICAL COMMUNICATIONS

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

(2010) Petr Sehnal et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Cobalt-Catalyzed Cross-Coupling Reactions

(2010) Gérard Cahiez et al.   CHEMICAL REVIEWS

Surface catalysed Suzuki–Miyaura cross-coupling by Pd nanoparticles: an operando XAS study

(2010) Adam F. Lee et al.   DALTON TRANSACTIONS

Triethanolamine-Mediated Palladium-Catalyzed Regioselective C-2 Direct Arylation of Free NH-Pyrroles

(2010) Farnaz Jafarpour et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(0) nanoparticle-catalyzed sp2 C–H activation: a convenient route to alkyl–aryl ketones by direct acylation of aryl bromides and iodides with aldehydes

(2010) Laksmikanta Adak et al.   TETRAHEDRON LETTERS

Palladium(0) nanoparticles-catalyzed ligand-free direct arylation of benzothiazole via C–H bond functionalization

(2010) Debasree Saha et al.   TETRAHEDRON LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of Organomanganese(II) Compounds

(2009) Gérard Cahiez et al.   CHEMICAL REVIEWS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Ziegler-type hydrogenation catalysts made from group 8–10 transition metal precatalysts and AlR3 cocatalysts: A critical review of the literature

(2009) William M. Alley et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Pd(0)/Cu(I)-Mediated Direct Arylation of 2′-Deoxyadenosines: Mechanistic Role of Cu(I) and Reactivity Comparisons with Related Purine Nucleosides

(2009) Thomas E. Storr et al.   JOURNAL OF ORGANIC CHEMISTRY

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

(2009) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

A site selective C–H arylation of free-(NH2) adenines with aryl chlorides: Application to the synthesis of 6,8-disubstituted adenines

(2009) Sophian Sahnoun et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

(2008) Arkaitz Correa et al.   CHEMICAL SOCIETY REVIEWS

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective direct arylation of unprotected adenine nucleosides mediated by palladium and copper: insights into the reaction mechanism

(2008) Thomas E. Storr et al.   TETRAHEDRON

Microwave-assisted Pd(OH)2-catalyzed direct C−H arylation of free-(NH2) adenines with aryl halides

(2008) Sophian Sahnoun et al.   TETRAHEDRON LETTERS

First heterogeneously palladium-catalysed fully selective C3-arylation of free NH-indoles

(2008) Giuseppe Cusati et al.   TETRAHEDRON LETTERS