Direct arylation and heterogeneous catalysis; ever the twain shall meet

Sonogashira Cross-Coupling and Homocoupling on a Silver Surface: Chlorobenzene and Phenylacetylene on Ag(100)

(2015) Carlos Sanchez-Sanchez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

(2015) Karl D. Collins et al.   Chemical Science

The Origin of Shape Sensitivity in Palladium-Catalyzed Suzuki-Miyaura Cross Coupling Reactions

(2014) Gillian Collins et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd/C as a Catalyst for Completely Regioselective CH Functionalization of Thiophenes under Mild Conditions

(2014) Dan-Tam D. Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I) and palladium nanoparticles supported on ethylenediamine-functionalized cellulose as an efficient catalyst for the 1,3-dipolar cycloaddition/direct arylation sequence

(2014) Sajjad Keshipour et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Direct C sp2H and C sp3H Arylation Enabled by Heterogeneous Palladium Catalysts

(2014) Laurent Djakovitch et al.   ChemCatChem

Ligand-free direct C-arylation of heterocycles with aryl halides over a metal-organic framework Cu2(BPDC)2(BPY) as an efficient and robust heterogeneous catalyst

(2014) Hanh T.N. Le et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

The Flexible Surface Revisited: Adsorbate-Induced Reconstruction, Homocoupling, and Sonogashira Cross-Coupling on the Au(100) Surface

(2014) Carlos Sánchez-Sánchez et al.   Journal of Physical Chemistry C

Nano CuO-catalyzed C–H functionalization of 1,3-azoles with bromoarenes and bromoalkenes

(2014) Wu Zhang et al.   TETRAHEDRON

Formation and propagation of well-defined Pd nanoparticles (PdNPs) during C–H bond functionalization of heteroarenes: are nanoparticles a moribund form of Pd or an active catalytic species?

(2014) Christoph G. Baumann et al.   TETRAHEDRON

Copper nanoparticle heterogeneous catalytic ‘click’ cycloaddition confirmed by single-molecule spectroscopy

(2014) Matthew R. Decan et al.   Nature Communications

Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

(2014) Alexander F. Schmidt et al.   Catalysis Science & Technology

Completely Regioselective Direct C–H Functionalization of Benzo[b]thiophenes Using a Simple Heterogeneous Catalyst

(2013) Dan-Tam D. Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Direct catalytic C–H arylation of imidazo[1,2-a]pyridine with aryl bromides using magnetically recyclable Pd–Fe3O4 nanoparticles

(2013) Jaewoo Lee et al.   TETRAHEDRON

Towards applications of metal–organic frameworks in catalysis: C–H direct activation of benzoxazole with aryl boronic acids using Ni2(BDC)2(DABCO) as an efficient heterogeneous catalyst

(2013) Nam T. S. Phan et al.   Catalysis Science & Technology

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

(2012) Hongli Liu et al.   CHEMICAL COMMUNICATIONS

Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects

(2012) A. F. Schmidt et al.   KINETICS AND CATALYSIS

Simple kinetic method for distinguishing between homogeneous and heterogeneous mechanisms of catalysis, illustrated by the example of “ligand-free” Suzuki and Heck reactions of aryl iodides and aryl bromides

(2012) A. F. Schmidt et al.   KINETICS AND CATALYSIS

Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy

(2012) Inge L. C. Buurmans et al.   Nature Chemistry

State-of-the-art and challenges in theoretical simulations of heterogeneous catalysis at the microscopic level

(2012) Núria López et al.   Catalysis Science & Technology

Au-Pd Core-Shell Nanoparticles Catalyze Suzuki-Miyaura Reactions in Water through Pd Leaching

(2011) Ping-Ping Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts

(2011) Robert H. Crabtree   CHEMICAL REVIEWS

Palladium Nanoparticles Encapsulated in a Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles

(2011) Yuanbiao Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Fully Palladium-Mediated Construction of Phenanthrenes and Naphthoxindoles

(2011) Luma Nassar-Hardy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ligand-Free CuO Nanospindle Catalyzed Arylation of Heterocycle C–H Bonds

(2011) Wu Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Identification of the Active Species Generated from Supported Pd Catalysts in Heck Reactions: An in situ Quick Scanning EXAFS Investigation

(2011) Sven Reimann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

(2011) A. G. Sergeev et al.   SCIENCE

Evidence for the Surface-Catalyzed Suzuki-Miyaura Reaction over Palladium Nanoparticles: An Operando XAS Study

(2010) Peter J. Ellis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorous silica gel-supported perfluoro-tagged palladium nanoparticles: an efficient and reusable catalyst for direct C-2 arylation of indoles

(2010) Liang Wang et al.   CHEMICAL COMMUNICATIONS

Surface catalysed Suzuki–Miyaura cross-coupling by Pd nanoparticles: an operando XAS study

(2010) Adam F. Lee et al.   DALTON TRANSACTIONS

Triethanolamine-Mediated Palladium-Catalyzed Regioselective C-2 Direct Arylation of Free NH-Pyrroles

(2010) Farnaz Jafarpour et al.   JOURNAL OF ORGANIC CHEMISTRY

When is free really free?

(2010) Nicholas E. Leadbeater   Nature Chemistry

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Evidence for heterogeneous Sonogashira coupling of phenylacetylene and iodobenzene catalyzed by well defined rhodium nanoparticles

(2009) Vijay K. Kanuru et al.   DALTON TRANSACTIONS

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction

(2009) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A site selective C–H arylation of free-(NH2) adenines with aryl chlorides: Application to the synthesis of 6,8-disubstituted adenines

(2009) Sophian Sahnoun et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Dynamic adsorbate/reaction induced structural change of supported metal nanoparticles: heterogeneous catalysis and beyond

(2008) Mark A. Newton   CHEMICAL SOCIETY REVIEWS

Microwave-assisted Pd(OH)2-catalyzed direct C−H arylation of free-(NH2) adenines with aryl halides

(2008) Sophian Sahnoun et al.   TETRAHEDRON LETTERS

First heterogeneously palladium-catalysed fully selective C3-arylation of free NH-indoles

(2008) Giuseppe Cusati et al.   TETRAHEDRON LETTERS