Journal
INORGANIC CHEMISTRY
Volume 54, Issue 8, Pages 3797-3804Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic503043h
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- TUM Graduate School
- King Abdullah University of Saudi-Arabia [KSA-00069/UKC0020]
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An iron(II) complex with a cyclic tetradentate ligand containing four N-heterocyclic carbenes was synthesized and characterized by means of NMR and IR spectroscopies, as well as by single-crystal X-ray structure analysis. The iron center exhibits an octahedral coordination geometry with two acetonitrile ligands in axial positions, showing structural analogies with porphyrine-ligated iron complexes. The acetonitrile ligands can readily be substituted by other ligands, for instance, dimethyl sulfoxide, carbon monoxide, and nitric oxide. Cyclic voltammetry was used to examine the electronic properties of the synthesized compounds.
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