An unexpected leading role for [Fe2(CO)6(μ-pdt)] in our understanding of [FeFe]-H2ases and the search for clean hydrogen production

Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts

(2022) Holly Jayne Redman et al.   DALTON TRANSACTIONS

Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines

(2022) Eric S. Wiedner et al.   CHEMICAL REVIEWS

Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases

(2022) Andrea Mele et al.   MOLECULES

Bioinspired Molecular Electrocatalysts for H2 Production: Chemical Strategies

(2022) Lili Sun et al.   ACS Catalysis

Photodynamics of Asymmetric Di-Iron-Cyano Hydrogenases Examined by Time-Resolved Mid-Infrared Spectroscopy

(2021) Amber Meyers et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Carbonyl Displacement Reaction in Diiron Propane-Dithiolate Complex by Triphenylstibine: Crystal Structure of [Fe2(CO)6-n(SbPh3)n(μ-S2C3H6)] (n = 1 and 2)

(2021) Shafikul Islam et al.   JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

Ultrafast Electron Transfer from CdSe Quantum Dots to an [FeFe]-Hydrogenase Mimic

(2021) Alexander Schleusener et al.   Journal of Physical Chemistry Letters

The catalytic cycle of [FeFe] hydrogenase: A tale of two sites

(2021) James A. Birrell et al.   COORDINATION CHEMISTRY REVIEWS

The expanding utility of iron-sulfur clusters: Their functional roles in biology, synthetic small molecules, maquettes and artificial proteins, biomimetic materials, and therapeutic strategies

(2021) Amy E. Boncella et al.   COORDINATION CHEMISTRY REVIEWS

Catalytic systems mimicking the [FeFe]-hydrogenase active site for visible-light-driven hydrogen production

(2021) Juan Amaro-Gahete et al.   COORDINATION CHEMISTRY REVIEWS

A Tetranuclear Propane-1,3-Dithiolate Complex, [Fe2(CO)5{Ph2P(CH2)3}{(µ-SCH2)2CH2}]2, with a Bridging 1,6-Bis(diphenylphosphino)hexane Ligand

(2021) Md. Mahfujar Rohman et al.   JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

Influence of different solvents on structures and electronic properties of new Fe2S2 complexes containing bis(2-diphenylphosphinophenyl)ether

(2021) Ting-Hong Huang et al.   JOURNAL OF MOLECULAR STRUCTURE

Di-1-adamantylphosphine-containing diiron propane-1,3-dithiolate pentacarbonyl complex: Synthesis, structure, electrochemistry, and fungicidal activity

(2021) Lin Yan et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(μ-H)FeIIFeII] Complexes

(2020) Kavindu Dilshan Kariyawasam Pathirana et al.   INORGANIC CHEMISTRY

Crystal structure and electrocatalytic investigation of diiron azadiphosphine complex [Fe2(μ-pdt)(CO)4{(μ-Ph2P)2NH}] related to [FeFe]-hydrogenases

(2020) Jian-Rong Li et al.   Inorganic and Nano-Metal Chemistry

[FeFe]-hydrogenase active site mimics containing pyridyl-functionalized phosphine ligands: Synthesis, characterization and electrochemical investigation

(2020) Shu-Peng Hu et al.   INORGANICA CHIMICA ACTA

Insights into the two‐electron reductive process of [FeFe]H2ase biomimetics. Cyclic voltammetry and DFT investigation on chelates control of redox properties of [Fe2(CO)4(κ2‐chelate)(µ‐dithiolate)].

(2020) Philippe Schollhammer et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

(2020) Andrea Mele et al.   CHIMIA

Synthesis, characterization and electrochemical reductive properties of complexes [Fe2(CO)4(k2-PPh2NR2)(µ-dithiolate)] related to the H-cluster of [FeFe]-H2ases

(2020) Ahmad Hobballah et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Tris(2-thienyl)phosphine-substituted diiron propanedithiolate complexes: Synthesis, spectroscopy, crystal structures, electrochemistry, and fungicidal activity

(2020) Lin Yan et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Synthetic and Structural Studies of [FeFe]-Hydrogenase Models Containing a Butterfly Fe/E (E = S, Se, or Te) Cluster Core. Electrocatalytic H2 Evolution Catalyzed by [(μ-SeCH2)(μ-CH2NCH2Ph)]Fe2(CO)6

(2019) Li-Cheng Song et al.   ORGANOMETALLICS

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

(2019) Kristian E. Dalle et al.   CHEMICAL REVIEWS

Photodynamics of [FeFe]-Hydrogenase Model Compounds with Bidentate Heterocyclic Ligands

(2019) Wyatt Aaron Thornley et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Organometallic compounds as carriers of extraterrestrial cyanide in primitive meteorites

(2019) Karen E. Smith et al.   Nature Communications

Synthesis, molecular structures and electrochemical investigations of [FeFe]-hydrogenase biomimics [Fe2(CO)6-n(EPh3)n(μ-edt)] (E = P, As, Sb; n = 1, 2)

(2019) Shishir Ghosh et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Photoinduced Terminal Hydride of [FeFe]-Hydrogenase Biomimetic Complexes

(2019) Shuqiang Niu et al.   INORGANIC CHEMISTRY

Synthesis, characterization, and electrochemistry of five diiron propane-1,3-dithiolate complexes with substituted phosphine ligands

(2019) Lin Yan et al.   JOURNAL OF COORDINATION CHEMISTRY

Artificial water-soluble systems inspired by [FeFe]-hydrogenases for electro- and photocatalytic hydrogen production

(2019) Shang Gao et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Fabrication of covalently linked graphene-mediated [FeFe]-hydrogenases biomimetic photocatalytic hydrogen evolution system in aqueous solution

(2018) Rui-Xia Li et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Structural and Kinetic Studies of Intermediates of a Biomimetic Diiron Proton-Reduction Catalyst

(2018) Shihuai Wang et al.   INORGANIC CHEMISTRY

Preparation, characterization and photocatalytic properties of diiron mimic modified Nano Silica

(2018) Meng Cao et al.   INORGANICA CHIMICA ACTA

Ultrafast Photodynamics of Cyano-Functionalized [FeFe] Hydrogenase Model Compounds

(2018) Christopher J. Stromberg et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine

(2018) Hui Li et al.   MOLECULAR CRYSTALS AND LIQUID CRYSTALS

PNP-Chelated and -Bridged Diiron Dithiolate Complexes Fe2(μ-pdt)(CO)4{(Ph2P)2NR} Together with Related Monophosphine Complexes for the [2Fe]H Subsite of [FeFe]-Hydrogenases: Preparation, Structure, and Electrocatalysis

(2018) Pei-Hua Zhao et al.   ORGANOMETALLICS

The effect of a pendant amine in phosphine ligand on the structure and electrochemical property of diiron dithiolate complexes

(2018) Pei-Hua Zhao et al.   JOURNAL OF COORDINATION CHEMISTRY

Terminal Thiolate-Dominated H/D Exchanges and H2 Release: Diiron Thiol–Hydride

(2018) Xin Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H2 Activation in [FeFe]-Hydrogenase Cofactor Versus Diiron Dithiolate Models: Factors Underlying the Catalytic Success of Nature and Implications for an Improved Biomimicry

(2018) Federica Arrigoni et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dinuclear FeIIFeII Biomimetics for the Oxidized State Active Site of [FeFe]-Hydrogenases: Synthesis, Characterization, and Electrocatalytic H2 Production

(2018) Li-Cheng Song et al.   ORGANOMETALLICS

Diiron Dithiolate Hydrides Complemented with Proton-Responsive Phosphine-Amine Ligands

(2017) Michaela R. Carlson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Electrocatalytic Activity of [FeFe]-Hydrogenase Model Complexes with Non-Innocent Chelating Nitrogen-Donor Ligands

(2017) Souvik Roy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

[FeFe]-Hydrogenase H-Cluster Mimics with Various −S(CH2)nS– Linker Lengths (n = 2–8): A Systematic Study

(2017) Hassan Abul-Futouh et al.   INORGANIC CHEMISTRY

Reaction of the diiron toluenedithiolate hexacarbonyl complex with 1,1-bis(diphenylphosphino)methane

(2017) Xu-Feng Liu   JOURNAL OF COORDINATION CHEMISTRY

Aminophosphine-substituted diiron dithiolate complexes: Synthesis, crystal structure, and electrocatalytic investigation

(2017) Yu-Long Li et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

[FeFe]-Hydrogenase and its organic molecule mimics—Artificial and bioengineering application for hydrogenproduction

(2017) Motonori Watanabe et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS

Dynamic Flexibility of Hydrogenase Active Site Models Studied with 2D-IR Spectroscopy

(2017) Peter A. Eckert et al.   JOURNAL OF PHYSICAL CHEMISTRY A

2-(Diphenylphosphino)benzaldehyde or isopropyldiphenylphosphine substituted diiron dithiolate complexes

(2017) Yu-Dong Sheng et al.   POLYHEDRON

A comparative study of the electrochemical and proton-reduction behaviour of diphosphine-dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2) n S}] (M = Fe, Ru; n = 2, 3)

(2017) Shishir Ghosh et al.   TRANSITION METAL CHEMISTRY

Muonium Chemistry at Diiron Subsite Analogues of [FeFe]-Hydrogenase

(2016) Joseph A. Wright et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water

(2016) Feng Wang et al.   CHEMICAL COMMUNICATIONS

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Synthesis of Diiron(I) Dithiolato Carbonyl Complexes

(2016) Yulong Li et al.   CHEMICAL REVIEWS

Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes

(2016) Robert H. Morris   CHEMICAL REVIEWS

Hydrophilic Quaternary Ammonium-Group-Containing [FeFe]-Hydrogenase Models: Synthesis, Structures, and Electrocatalytic Hydrogen Production

(2016) Li-Cheng Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

[FeFe]-Hydrogenase H-Cluster Mimics with Unique Planar μ-(SCH2)2ER2Linkers (E=Ge and Sn)

(2016) Hassan Abul-Futouh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation and Protonation of Fe2(pdt)(CNR)6, Electron-Rich Analogues of Fe2(pdt)(CO)6

(2016) Xiaoyuan Zhou et al.   INORGANIC CHEMISTRY

Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe 2 (CO) 4 (μ-H){κ 2 -Ph 2 PC(Me 2 )PPh 2 }(μ-pdt)] + as a proton-reduction catalyst

(2016) Shishir Ghosh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Encapsulating Subsite Analogues of the [FeFe]-Hydrogenases in Micelles Enables Direct Water Interactions

(2016) Robby Fritzsch et al.   Journal of Physical Chemistry Letters

Synthesis and structural analysis of (μ-SCH2CH2CH2S-μ)Fe2(CO)5(2-C5H4NPPh2)

(2016) Xu-Feng Liu   MOLECULAR CRYSTALS AND LIQUID CRYSTALS

Dimeric FeFe-hydrogenase mimics bearing carboxylic acids: Synthesis and electrochemical investigation

(2016) Benjamin R. Garrett et al.   POLYHEDRON

Photochemical reactivity of a binuclear Fe(I)–Fe(I) hydrogenase model compound with cyano ligands

(2016) Andrew Hunt et al.   POLYHEDRON

Synthesis and structures of diiron dithiolate complexes with 1,2-bis(diphenylphosphino)acetylene or tris(2-methoxyphenyl)phosphine

(2016) Xu-Feng Liu   POLYHEDRON

Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase

(2016) Allen M. Lunsford et al.   Chemical Science

Secondary coordination sphere accelerates hole transfer for enhanced hydrogen photogeneration from [FeFe]-hydrogenase mimic and CdSe QDs in water

(2016) Min Wen et al.   Scientific Reports

[NiFeSe]-Hydrogenase Chemistry

(2015) Claire Wombwell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hybrid [FeFe]-Hydrogenases with Modified Active Sites Show Remarkable Residual Enzymatic Activity

(2015) Judith F. Siebel et al.   BIOCHEMISTRY

Intramolecular CH Activation and Metallacycle Aromaticity in the Photochemistry of [FeFe]-Hydrogenase Model Compounds in Low-Temperature Frozen Matrices

(2015) Wyatt A. Thornley et al.   CHEMISTRY-A EUROPEAN JOURNAL

Utilization of Non-Innocent Redox Ligands in [FeFe] Hydrogenase Modeling for Hydrogen Production

(2015) Yu-Chiao Liu et al.   COMMENTS ON INORGANIC CHEMISTRY

Hydrogen-activating models of hydrogenases

(2015) Tao Xu et al.   COORDINATION CHEMISTRY REVIEWS

Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{μ-(XCH2)2CRR′}] hydrogenase models (X = S, Se)

(2015) Ralf Trautwein et al.   DALTON TRANSACTIONS

Biomimetic peptide-based models of [FeFe]-hydrogenases: utilization of phosphine-containing peptides

(2015) Souvik Roy et al.   DALTON TRANSACTIONS

Effect of Bridgehead Steric Bulk on the Intramolecular C–H Heterolysis of [FeFe]-Hydrogenase Active Site Models Containing a P2N2 Pendant Amine Ligand

(2015) Dehua Zheng et al.   INORGANIC CHEMISTRY

Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties

(2015) Ryan D. Bethel et al.   INORGANIC CHEMISTRY

DFT Dissection of the Reduction Step in H2 Catalytic Production by [FeFe]-Hydrogenase-Inspired Models: Can the Bridging Hydride Become More Reactive Than the Terminal Isomer?

(2015) Giulia Filippi et al.   INORGANIC CHEMISTRY

Artificially maturated [FeFe] hydrogenase from Chlamydomonas reinhardtii: a HYSCORE and ENDOR study of a non-natural H-cluster

(2015) Agnieszka Adamska-Venkatesh et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Synthesis, spectroscopic characterization, and crystal structures of diiron pentacarbonyl complexes with monosubstituted tris(3-chlorophenyl)phosphine or cyclohexyldiphenylphosphine ligands

(2015) Xu-Feng Liu   TRANSITION METAL CHEMISTRY

Enhancement of the Efficiency of Photocatalytic Reduction of Protons to Hydrogen via Molecular Assembly

(2014) Li-Zhu Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Heptacarbonylbis(μ-propane-1,3-dithiolato)triiron(I,II)(2Fe—Fe)

(2014) Mingqiang Hu et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

A phosphoramidite-based [FeFe]H2ase functional mimic displaying fast electrocatalytic proton reduction

(2014) Sofia Derossi et al.   DALTON TRANSACTIONS

CO Substitution Reactions of Diiron Complexes [{(μ-SCH2)2X}Fe2(CO)6] and [{(μ-SeCH2)2X}Fe2(CO)6] (X = O, CH2) with Ph2PCl/Me3NO to Give Ph2PCl-, Ph2PNMe2-, and Ph2PP(=O)Ph2-Substituted Complexes Related to [FeFe] Hydrogenases

(2014) Li-Cheng Song et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models

(2014) Brian C. Manor et al.   INORGANIC CHEMISTRY

TDDFT modeling of the CO-photolysis of Fe2(S2C3H6)(CO)6, a model of the [FeFe]-hydrogenase catalytic site

(2014) Luca Bertini et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

Synthesis, Characterization, and Crystal Structure of Tertiary Phosphine-Substituted Diiron Propanedithiolate Complexes

(2014) Pei-Hua Zhao et al.   JOURNAL OF CLUSTER SCIENCE

Alkynyl-Phosphine Substituted Fe2S2 Clusters: Synthesis, Structure and Spectroelectrochemical Characterization of a Cluster with a Class III Mixed-Valence [FeFe]3+ Core

(2014) Gregory L. Newman et al.   JOURNAL OF CLUSTER SCIENCE

Facile synthesis, X-ray analysis, and spectroscopic studies of di-iron propanedithiolate complexes with tris(aromatic)phosphine ligands

(2014) Pei-Hua Zhao et al.   JOURNAL OF COORDINATION CHEMISTRY

Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (111)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM

(2014) Brian Chmielowiec et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Pyridyl- and pyrimidyl-phosphine-substituted [FeFe]-hydrogenase mimics: Synthesis, charaterization and properties

(2014) Hong-Hua Cui et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

New Reactions of Terminal Hydrides on a Diiron Dithiolate

(2014) Wenguang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic O2 Reduction by [Fe-Fe]-Hydrogenase Active Site Models

(2014) Subal Dey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic Control of the Protonation Rates of Fe–Fe Bonds

(2014) Aušra Jablonskytė et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigation of the Ultrafast Dynamics Occurring during Unsensitized Photocatalytic H2 Evolution by an [FeFe]-Hydrogenase Subsite Analogue

(2014) Pim W. J. M. Frederix et al.   ORGANOMETALLICS

Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates

(2014) Maria E. Carroll et al.   ORGANOMETALLICS

New Systematic Route to Mixed-Valence Triiron Clusters Derived from Dinuclear Models of the Active Site of [Fe–Fe]-Hydrogenases

(2014) Laetitia Beaume et al.   ORGANOMETALLICS

Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site

(2014) James C. Lansing et al.   ORGANOMETALLICS

Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

(2014) Danielle J. Crouthers et al.   ORGANOMETALLICS

Iron carbonyl cluster complexes with monophosphine ligands: synthesis, characterization, and crystal structure

(2014) Pei-Hua Zhao et al.   TRANSITION METAL CHEMISTRY

Exceptional Poly(acrylic acid)-Based Artificial [FeFe]-Hydrogenases for Photocatalytic H2Production in Water

(2013) Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controllable Electrochemical Synthesis of Mono- and Di-Substituted Diphosphine Complexes Related to [Fe-Fe]-Hydrogenase

(2013) WENWEN JIANG   ASIAN JOURNAL OF CHEMISTRY

Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

(2013) Shishir Ghosh et al.   CHEMICAL COMMUNICATIONS

Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides

(2013) R. Morris Bullock et al.   CHEMICAL COMMUNICATIONS

Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the HredState?

(2013) Wenguang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of [FeFe]-hydrogenase models involving the formation of hydrides related to proton reduction and hydrogen oxidation

(2013) Ning Wang et al.   DALTON TRANSACTIONS

Mechanistic studies on proton transfer in a [FeFe] hydrogenase mimic complex

(2013) Ying Wang et al.   DALTON TRANSACTIONS

Models of the iron-only hydrogenase: a comparison of chelate and bridge isomers of Fe2(CO)4{Ph2PN(R)PPh2}(μ-pdt) as proton-reduction catalysts

(2013) Shishir Ghosh et al.   DALTON TRANSACTIONS

Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT

(2013) Nils Leidel et al.   DALTON TRANSACTIONS

Excited State Properties of Diiron Dithiolate Hydrides: Implications in the Unsensitized Photocatalysis of H2 Evolution

(2013) Luca Bertini et al.   INORGANIC CHEMISTRY

Synthesis and Crystal Structures of Diiron Dithiolate Complexes Containing Diphosphine Ligands

(2013) Xu-Feng Liu et al.   JOURNAL OF CLUSTER SCIENCE

Time-Resolved Infrared Studies of a Trimethylphosphine Model Derivative of [FeFe]-Hydrogenase

(2013) Melissa Johnson et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Synthesis and characterization of [FeFe]-hydrogenase mimics appended with a 2-phenylazopyridine ligand

(2013) Raphael A. Seidel et al.   Journal of Sulfur Chemistry

Catalytic Activation of H2 under Mild Conditions by an [FeFe]-Hydrogenase Model via an Active μ-Hydride Species

(2013) Ning Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis

(2013) Wenguang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

The employment of a hydrophilic tris(morpholino)phosphine ligand in diiron propane-1,3-dithiolate complexes for potentially water-soluble iron-only hydrogenase active-site mimics

(2013) Shang Gao et al.   NEW JOURNAL OF CHEMISTRY

Pendant amine bases speed up proton transfers to metals by splitting the barriers

(2012) Ying Wang et al.   CHEMICAL COMMUNICATIONS

A photoactive basket-like metal–organic tetragon worked as an enzymatic molecular flask for light driven H2production

(2012) Cheng He et al.   CHEMICAL COMMUNICATIONS

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Electrochemical and Theoretical Investigations of the Role of the Appended Base on the Reduction of Protons by [Fe2(CO)4(κ2-PNPR)(μ-S(CH2)3S] (PNPR={Ph2PCH2}2NR, R=Me, Ph)

(2012) Sondes Lounissi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photocatalytic Water Reduction and Study of the Formation of FeIFe0 Species in Diiron Catalyst Sytems

(2012) Xueqiang Li et al.   ChemSusChem

Photoswitchable electrochemical behaviour of a [FeFe] hydrogenase model with a dithienylethene derivative

(2012) Hui-Min Wen et al.   DALTON TRANSACTIONS

Efficient [FeFe] hydrogenase mimic dyads covalently linking to iridium photosensitizer for photocatalytic hydrogen evolution

(2012) Hong-hua Cui et al.   DALTON TRANSACTIONS

Electron transfer and hydrogen generation from a molecular dyad: platinum(ii) alkynyl complex anchored to [FeFe] hydrogenase subsite mimic

(2012) Wen-Guang Wang et al.   DALTON TRANSACTIONS

Mixed-valence [FeIFeII] hydrogenase active site model complexes stabilized by a bidentate carborane bis-phosphine ligand

(2012) Michael Karnahl et al.   DALTON TRANSACTIONS

Encapsulating [FeFe]-hydrogenase model compounds in peptide hydrogels dramatically modifies stability and photochemistry

(2012) Pim W. J. M. Frederix et al.   DALTON TRANSACTIONS

Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2′-bipyridyl ligand

(2012) Souvik Roy et al.   DALTON TRANSACTIONS

Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as active site models of [FeFe]-hydrogenases

(2012) Li-Cheng Song et al.   DALTON TRANSACTIONS

Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound

(2012) Sohail Muhammad et al.   INORGANIC CHEMISTRY

Solution-phase photochemistry of a [FeFe]hydrogenase model compound: Evidence of photoinduced isomerisation

(2012) Rafal Kania et al.   JOURNAL OF CHEMICAL PHYSICS

Preparation, structures and electrochemical property of diiron dithiolate complexes with hydrophilic N-donor ligands

(2012) Ya-Nan Feng et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Time-Resolved Vibrational Spectroscopy of [FeFe]-Hydrogenase Model Compounds

(2012) Jamie L. Bingaman et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Multi-edge X-ray Absorption Spectroscopy. 1. X-ray Absorption near-Edge Structure Analysis of a Biomimetic Model of FeFe-Hydrogenase

(2012) Logan J. Giles et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase

(2012) Chung-Hung Hsieh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unsensitized Photochemical Hydrogen Production Catalyzed by Diiron Hydrides

(2012) Wenguang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe2(dithiolate)(CO)2(PMe3)4

(2012) Riccardo Zaffaroni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates

(2012) Matthew T. Olsen et al.   ORGANOMETALLICS

Synthesis, Structural Characterization, and Properties of Some Functionalized Phosphine-Containing Diiron Complexes As Models for the Active Site of [FeFe]-Hydrogenases

(2012) Li-Cheng Song et al.   ORGANOMETALLICS

Electrochemical and Theoretical Studies of the Impact of the Chelating Ligand on the Reactivity of [Fe2(CO)4(κ2-LL)(μ-pdt)]+ Complexes with Different Substrates (LL = IMe-CH2-IMe, dppe; IMe = 1-Methylimidazol-2-ylidene)

(2012) Dounia Chouffai et al.   ORGANOMETALLICS

Pentacarbonyl-1κ2C,2κ3C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ4S,S′:S,S′)iron(I)(Fe—Fe)

(2011) Jinli Zhu et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

μ-Propane-1,3-dithiolato-κ4S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe)

(2011) Bang-Shao Yin et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution

(2011) Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereochemistry of electrophilic attack at 34e− dimetallic complexes: the case of diiron dithiolato carbonyls + MeS+

(2011) Matthew T. Olsen et al.   CHEMICAL COMMUNICATIONS

Approaches to efficient molecular catalyst systems for photochemical H2 production using [FeFe]-hydrogenase active site mimics

(2011) Mei Wang et al.   DALTON TRANSACTIONS

An Oxidized Active Site Model for the FeFe Hydrogenase: Reduction with Hydrogen Gas

(2011) Steven L. Matthews et al.   INORGANIC CHEMISTRY

A Theoretical Study on the Enhancement of Functionally Relevant Electron Transfers in Biomimetic Models of [FeFe]-Hydrogenases

(2011) Claudio Greco et al.   INORGANIC CHEMISTRY

Flash and Continuous Photolysis Kinetic Studies of the Iron–Iron Hydrogenase Model (μ-pdt)[Fe(CO)3]2in Different Solvents

(2011) Jon Marhenke et al.   INORGANIC CHEMISTRY

Oxidatively Induced Reactivity of [Fe2(CO)4(κ2-dppe)(μ-pdt)]: an Electrochemical and Theoretical Study of the Structure Change and Ligand Binding Processes

(2011) Dounia Chouffai et al.   INORGANIC CHEMISTRY

Importance of the Protein Framework for Catalytic Activity of [FeFe]-Hydrogenases

(2011) Philipp Knörzer et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Diiron propanedithiolate complex bearing the pyridyl-functionalized phosphine ligand axially coordinated to a photosensitizer zinc tetraphenylporphyrin

(2011) Xu-Feng Liu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Paramagnetic Bridging Hydrides of Relevance to Catalytic Hydrogen Evolution at Metallosulfur Centers

(2011) Aušra Jablonskytė et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Terahertz, infrared and Raman vibrational assignments of [FeFe]-hydrogenase model compounds

(2011) Christopher J. Stromberg et al.   VIBRATIONAL SPECTROSCOPY

Diiron species containing a cyclic PPh2NPh2diphosphine related to the [FeFe]H2ases active site

(2010) Sondès Lounissi et al.   CHEMICAL COMMUNICATIONS

Photocatalytic Hydrogen Evolution by [FeFe] Hydrogenase Mimics in Homogeneous Solution

(2010) Wen-Guang Wang et al.   Chemistry-An Asian Journal

Synthesis, structures and electrochemistry studies of 2Fe2S–Fe(ii)(S–2N)2 models for H-cluster of [FeFe]-hydrogenase

(2010) Ming-Qiang Hu et al.   DALTON TRANSACTIONS

Mechanistic aspects of the protonation of [FeFe]-hydrogenase subsite analogues

(2010) Aušra Jablonskytė et al.   DALTON TRANSACTIONS

Electrocatalytic dihydrogen evolution mechanism of [Fe2(CO)4(κ2-Ph2PCH2CH2PPh2)(μ-S(CH2)3S)] and related models of the [FeFe]-hydrogenases active site: a DFT investigation

(2010) Claudio Greco et al.   DALTON TRANSACTIONS

Mechanism of electrocatalytic hydrogen production by a di-iron model of iron–iron hydrogenase: A density functional theory study of proton dissociation constants and electrode reduction potentials

(2010) Panida Surawatanawong et al.   DALTON TRANSACTIONS

Protonation of [FeFe]-hydrogenase sub-site analogues: revealing mechanism using FTIR stopped-flow techniques

(2010) Joseph A. Wright et al.   FARADAY DISCUSSIONS

Investigation on the Protonation of a Trisubstituted [Fe2(CO)3(PPh3)(κ2-phen)(μ-pdt)] Complex: Rotated versus Unrotated Intermediate Pathways

(2010) Pierre-Yves Orain et al.   INORGANIC CHEMISTRY

A Carbonyl-Rich Bridging Hydride Complex Relevant to the Fe−Fe Hydrogenase Active Site

(2010) Steven L. Matthews et al.   INORGANIC CHEMISTRY

Determination of the Photolysis Products of [FeFe]Hydrogenase Enzyme Model Systems using Ultrafast Multidimensional Infrared Spectroscopy

(2010) Andrew I. Stewart et al.   INORGANIC CHEMISTRY

Synthesis and structural characterization of a diiron propanedithiolate complex [(μ-PDT)Fe2(CO)5]2[(η5-Ph2PC5H4)2Fe] containing a bidentate phosphine ligand 1,1′-bis(diphenylphosphino)ferrocene

(2010) Xu-Feng Liu et al.   JOURNAL OF COORDINATION CHEMISTRY

Non-innocent bma ligand in a dissymetrically disubstituted diiron dithiolate related to the active site of the [FeFe] hydrogenases

(2010) Youtao Si et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Femtosecond to Microsecond Photochemistry of a [FeFe]hydrogenase Enzyme Model Compound

(2010) Spyridon Kaziannis et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Stepwise [FeFe]-hydrogenase H-cluster assembly revealed in the structure of HydAΔEFG

(2010) David W. Mulder et al.   NATURE

Diphosphine Mobility at a Binuclear Metal Center: A Concerted Double Trigonal-Twist in Bis(dithiolate) Complexes [M2(CO)4(μ-dppm){μ-S(CH2)nS}] (M = Fe, Ru;n= 2, 3)

(2010) Graeme Hogarth et al.   ORGANOMETALLICS

CO Affinity and Bonding Properties of [FeFe] Hydrogenase Active Site Models. A DFT Study

(2010) Luca Bertini et al.   ORGANOMETALLICS

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Isomerization of the hydride complexes [HFe2(SR)2(PR3)x(CO)6−x]+(x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases

(2009) Bryan E. Barton et al.   DALTON TRANSACTIONS

Mechanistic investigations into electrocatalytic substitution reactions of two diiron hexacarbonyl complexes by triphenyl phosphine ligand

(2009) Xianghua Zeng et al.   ELECTROCHIMICA ACTA

Hydrogen Activation by Biomimetic Diiron Dithiolates

(2009) Matthew T. Olsen et al.   INORGANIC CHEMISTRY

Influence of Sulf-Oxygenation on CO/L Substitution and Fe(CO)3Rotation in Thiolate-Bridged Diiron Complexes

(2009) Bin Li et al.   INORGANIC CHEMISTRY

Preparation, Facile Deprotonation, and Rapid H/D Exchange of the μ-Hydride Diiron Model Complexes of the [FeFe]-Hydrogenase Containing a Pendant Amine in a Chelating Diphosphine Ligand

(2009) Ning Wang et al.   INORGANIC CHEMISTRY

Synthesis, characterization and electrocatalysis of diiron propanediselenolate derivatives as the active site models of [FeFe]-hydrogenases

(2009) Li-Cheng Song et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Synthesis and characterization of carboxy-functionalized diiron model complexes of [FeFe]-hydrogenases: Decarboxylation of Ph2PCH2COOH promoted by a diiron azadithiolate complex

(2009) Zhenbo Zhao et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Modeling [FeFe] hydrogenase: Synthesis and protonation of a diiron dithiolate complex containing a phosphine-N-heterocyclic-carbene ligand

(2009) Didier Morvan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Terminal pyridine-N ligation at [FeFe] hydrogenase active-site mimic

(2009) Yue Zhang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Review of electrochemical studies of complexes containing the Fe2S2 core characteristic of [FeFe]-hydrogenases including catalysis by these complexes of the reduction of acids to form dihydrogen

(2009) Greg A.N. Felton et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

DFT/TDDFT Exploration of the Potential Energy Surfaces of the Ground State and Excited States of Fe2(S2C3H6)(CO)6: A Simple Functional Model of the [FeFe] Hydrogenase Active Site

(2009) Luca Bertini et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities

(2009) Tianbiao Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One- to Two-Electron Reduction of an [FeFe]-Hydrogenase Active Site Mimic: The Critical Role of Fluxionality of the [2Fe2S] Core

(2009) Greg A. N. Felton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Diiron Diselenolato Complexes Including Iron Hydrogenase Models

(2009) Mohammad K. Harb et al.   ORGANOMETALLICS

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution

(2009) A. M. Kluwer et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models

(2008) Michael L. Singleton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[FeFe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes

(2008) Zachariah M. Heiden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Models of the iron-only hydrogenase: Synthesis and protonation of bridge and chelate complexes [Fe2(CO)4{Ph2P(CH2)nPPh2}(μ-pdt)] (n=2–4) – evidence for a terminal hydride intermediate

(2008) Fatima I. Adam et al.   COMPTES RENDUS CHIMIE

Diiron chelate complexes relevant to the active site of the iron-only hydrogenase

(2008) Salah Ezzaher et al.   COMPTES RENDUS CHIMIE

The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes

(2008) Michael L. Singleton et al.   COMPTES RENDUS CHIMIE

Electrocatalysis of hydrogen evolution by synthetic diiron units using weak acids as the proton source: Pathways of doubtful relevance to enzymic catalysis by the diiron subsite of [FeFe] hydrogenase

(2008) Stacey J. Borg et al.   COMPTES RENDUS CHIMIE

The chemistry of [M3(CO)10(μ-dppm)](M=Ru, Os): Activating and maintaining the trinuclear core

(2008) Shariff E. Kabir et al.   COORDINATION CHEMISTRY REVIEWS

CO-Migration in the Ligand Substitution Process of the Chelating Diphosphite Diiron Complex (μ-pdt)[Fe(CO)3][Fe(CO){(EtO)2PN(Me)P(OEt)2}]

(2008) Ning Wang et al.   INORGANIC CHEMISTRY

Series of Mixed Valent Fe(II)Fe(I) Complexes That Model the HoxState of [FeFe]Hydrogenase: Redox Properties, Density-Functional Theory Investigation, and Reactivities with Extrinsic CO

(2008) Christine M. Thomas et al.   INORGANIC CHEMISTRY

New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases

(2008) Matthew T. Olsen et al.   INORGANIC CHEMISTRY

Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6from CO-Free Iron Sources

(2008) Phillip I. Volkers et al.   INORGANIC CHEMISTRY

Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges

(2008) Aaron K. Justice et al.   INORGANIC CHEMISTRY

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY

Synthesis, Structure, and Electrocatalysis of Diiron C-Functionalized Propanedithiolate (PDT) Complexes Related to the Active Site of [FeFe]-Hydrogenases

(2008) Li-Cheng Song et al.   INORGANIC CHEMISTRY

Refining the Active Site Structure of Iron−Iron Hydrogenase Using Computational Infrared Spectroscopy

(2008) Jesse W. Tye et al.   INORGANIC CHEMISTRY

Theoretical Studies on the Redox Potentials of Fe Dinuclear Complexes as Models for Hydrogenase

(2008) Lindsay E. Roy et al.   INORGANIC CHEMISTRY

Multiple-Timescale Photoreactivity of a Model Compound Related to the Active Site of [FeFe]-Hydrogenase

(2008) Anna R. Ridley et al.   INORGANIC CHEMISTRY

Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]HSubsite of [FeFe]H2ase

(2008) Salah Ezzaher et al.   INORGANIC CHEMISTRY

Photochemical studies of iron-only hydrogenase model compounds

(2008) Jessie Brown-McDonald et al.   INORGANICA CHIMICA ACTA

Electrochemical study of the role of a H-bridged, unsymmetrically disubstituted diiron complex in proton reduction catalysis

(2008) Salah Ezzaher et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Synthesis and structural characterization of the mono- and diphosphine-containing diiron propanedithiolate complexes related to [FeFe]-hydrogenases. Biomimetic H2 evolution catalyzed by (μ-PDT)Fe2(CO)4[(Ph2P)2N(n-Pr)]

(2008) Li-Cheng Song et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Photoelectron spectroscopy of dithiolatodiironhexacarbonyl models for the active site of [Fe–Fe] hydrogenases: Insight into the reorganization energy of the “rotated” structure in the enzyme

(2008) Benjamin J. Petro et al.   JOURNAL OF MOLECULAR STRUCTURE

Pendant bases as proton transfer relays in diiron dithiolate complexes inspired by [Fe–Fe] hydrogenase active site

(2008) Zhen Wang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Structure and Vibrational Dynamics of Model Compounds of the [FeFe]−Hydrogenase Enzyme System via Ultrafast Two-Dimensional Infrared Spectroscopy

(2008) A. I. Stewart et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site

(2008) Matthew T. Olsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

(2008) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dithiomethylether as a Ligand in the Hydrogenase H-Cluster

(2008) Arti S. Pandey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular self-assembly of a [2Fe2S] complex with a hydrophilic phosphine ligand

(2007) Ping Li et al.   CRYSTENGCOMM