Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe 2 (CO) 4 (μ-H){κ 2 -Ph 2 PC(Me 2 )PPh 2 }(μ-pdt)] + as a proton-reduction catalyst

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Title
Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe 2 (CO) 4 (μ-H){κ 2 -Ph 2 PC(Me 2 )PPh 2 }(μ-pdt)] + as a proton-reduction catalyst
Authors
Keywords
[FeFe]-hydrogenase, Diphosphine, Dithiolate, Diiron, Chelating, Biomimetic, DFT
Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 812, Issue -, Pages 247-258
Publisher
Elsevier BV
Online
2015-10-05
DOI
10.1016/j.jorganchem.2015.09.036

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