Bioinspired Molecular Electrocatalysts for H2 Production: Chemical Strategies

The Role of Green and Blue Hydrogen in the Energy Transition—A Technological and Geopolitical Perspective

(2021) Michel Noussan et al.   Sustainability

An [FeFe]‐Hydrogenase Mimic Immobilized through Simple Physiadsorption and Active for Aqueous H 2 Production

(2021) Md Estak Ahmed et al.   ChemElectroChem

Proton Shuttle Mediated by (SCH2)2P═O Moiety in [FeFe]-Hydrogenase Mimics: Electrochemical and DFT Studies

(2021) Laith R. Almazahreh et al.   ACS Catalysis

The catalytic cycle of [FeFe] hydrogenase: A tale of two sites

(2021) James A. Birrell et al.   COORDINATION CHEMISTRY REVIEWS

Current State of [FeFe]-hydrogenase Research - Biodiversity and Spectroscopic Investigations

(2020) Henrik Land et al.   ACS Catalysis

The hydrogen solution?

(2020) Sonja van Renssen   Nature Climate Change

Proton Transfer Mechanisms in Bimetallic Hydrogenases

(2020) Hulin Tai et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

(2020) Ashta C. Ghosh et al.   COORDINATION CHEMISTRY REVIEWS

Influence of Dithiolate Bridges on the Structures and Electrocatalytic Performance of Small Bite-Angle PNP-Chelated Diiron Complexes Fe2(μ-xdt)(CO)4{κ2-(Ph2P)2NR} Related to [FeFe]-Hydrogenases

(2019) Pei-Hua Zhao et al.   ORGANOMETALLICS

Cysteine SH and glutamate COOH contributions to [NiFe] hydrogenase proton transfer revealed by highly sensitive FT-IR spectroscopy

(2019) Hulin Tai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unifying Activity, Structure, and Spectroscopy of [NiFe] Hydrogenases: Combining Techniques To Clarify Mechanistic Understanding

(2019) Philip A. Ash et al.   ACCOUNTS OF CHEMICAL RESEARCH

Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

(2019) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of the Metal Ion in Bio-Inspired Hydrogenase Models: Investigation of a Homodinuclear FeFe Complex vs Its Heterodinuclear NiFe Analogue

(2019) Lianke Wang et al.   ACS Catalysis

The Molecular Proceedings of Biological Hydrogen Turnover

(2018) Michael Haumann et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrochemical proton reductions in varying acidic media by a simple synthetic hydrogenase mimic

(2018) Shang Gao et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

CO-Bridged H-Cluster Intermediates in the Catalytic Mechanism of [FeFe]-Hydrogenase CaI

(2018) Michael W. Ratzloff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[FeFe]-Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water

(2018) William P. Brezinski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]-Hydrogenase Model: Low pH Enables Catalysis through an Enzyme-Relevant Mechanism

(2018) Md Estak Ahmed et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomimetics of [NiFe]-Hydrogenase: Nickel- or Iron-Centered Proton Reduction Catalysis?

(2017) Hao Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

(2017) Edward J. Reijerse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

(2017) Martin Winkler et al.   Nature Communications

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

(2016) David Schilter et al.   CHEMICAL REVIEWS

Structure and function of [NiFe] hydrogenases

(2016) Hideaki Ogata et al.   JOURNAL OF BIOCHEMISTRY

Identification of a Catalytic Iron-Hydride at the H-Cluster of [FeFe]-Hydrogenase

(2016) David W. Mulder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts

(2016) Shengda Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase

(2016) Deborah Brazzolotto et al.   Nature Chemistry

An iron-iron hydrogenase mimic with appended electron reservoir for efficient proton reduction in aqueous media

(2016) R. Becker et al.   Science Advances

Synthesis and Electrocatalytic Property of Diiron Hydride Complexes Derived from a Thiolate-Bridged Diiron Complex

(2015) Dawei Yang et al.   INORGANIC CHEMISTRY

Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site

(2015) Geoffrey M. Chambers et al.   INORGANIC CHEMISTRY

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy

(2015) Hideaki Ogata et al.   Nature Communications

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Mimicking hydrogenases: From biomimetics to artificial enzymes

(2014) Trevor R. Simmons et al.   COORDINATION CHEMISTRY REVIEWS

Mechanistic Insights into the Catalysis of Electrochemical Proton Reduction by a Diiron Azadithiolate Complex

(2014) Marc Bourrez et al.   INORGANIC CHEMISTRY

Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel

(2014) Mioy T. Huynh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site

(2014) James C. Lansing et al.   ORGANOMETALLICS

Kinetic and thermodynamic aspects of the electrocatalysis of acid reduction in organic solvent using molecular diiron-dithiolate compounds

(2013) François Quentel et al.   ELECTROCHIMICA ACTA

Excited State Properties of Diiron Dithiolate Hydrides: Implications in the Unsensitized Photocatalysis of H2 Evolution

(2013) Luca Bertini et al.   INORGANIC CHEMISTRY

Biomimetic assembly and activation of [FeFe]-hydrogenases

(2013) G. Berggren et al.   NATURE

A Novel [FeFe] Hydrogenase Model with a (SCH2)2P═O Moiety

(2013) Laith R. Almazahreh et al.   ORGANOMETALLICS

Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2′-bipyridyl ligand

(2012) Souvik Roy et al.   DALTON TRANSACTIONS

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe2(dithiolate)(CO)2(PMe3)4

(2012) Riccardo Zaffaroni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation

(2012) Katharina Weber et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Active-Site Models for the Nickel–Iron Hydrogenases: Effects of Ligands on Reactivity and Catalytic Properties

(2011) Maria E. Carroll et al.   INORGANIC CHEMISTRY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

A Carbonyl-Rich Bridging Hydride Complex Relevant to the Fe−Fe Hydrogenase Active Site

(2010) Steven L. Matthews et al.   INORGANIC CHEMISTRY

Hydride-Containing Models for the Active Site of the Nickel−Iron Hydrogenases

(2010) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Models of the iron-only hydrogenase: Synthesis and protonation of bridge and chelate complexes [Fe2(CO)4{Ph2P(CH2)nPPh2}(μ-pdt)] (n=2–4) – evidence for a terminal hydride intermediate

(2008) Fatima I. Adam et al.   COMPTES RENDUS CHIMIE

Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2Production Than the Isomeric Bridging Hydride

(2008) Bryan E. Barton et al.   INORGANIC CHEMISTRY

Electrochemical Insights into the Mechanisms of Proton Reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] Complexes Related to the [2Fe]H Subsite of [FeFe]Hydrogenase

(2007) Jean-François Capon et al.   CHEMISTRY-A EUROPEAN JOURNAL