Palladium-catalyzed amination of 2,3,3-trifluoroallyl esters: synthesis of trifluoromethylenamines via an intramolecular fluorine shift and CF3 group construction

cis-Specific Hydrofluorination of Alkenylarenes under Palladium Catalysis through an Ionic Pathway

(2014) Enrico Emer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective CF Bond Activation of Hexafluoropropylene on Palladium(0): Formation of a Cationic η2-Perfluoroallylpalladium Complex

(2014) Masato Ohashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Double Alkylation of 3-Aryl-2-fluoroallyl Esters with Malonate Nucleophiles through the Carbon–Fluorine Bond Cleavage

(2014) Mitsuaki Yamamoto et al.   ORGANIC LETTERS

Enantioselective Allylic Amination of Trifluoromethyl Group Substituted Racemic and Unsymmetrical 1,3-Disubstituted Allylic Esters by Palladium Catalysts

(2014) Motoi Kawatsura et al.   ORGANIC LETTERS

Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination

(2014) Matthew H. Katcher et al.   ORGANOMETALLICS

Iron-catalyzed [2 + 2 + 2] cycloaddition of trifluoromethyl group substituted unsymmetrical internal alkynes

(2014) Maki Minakawa et al.   RSC Advances

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt Fluorocarbenes: Cycloaddition Reactions with Tetrafluoroethylene and Reactivity of the Perfluorometallacyclic Products

(2013) Daniel J. Harrison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition

(2013) Masato Ohashi et al.   ORGANOMETALLICS

Acid-Promoted Selective Carbon–Fluorine Bond Activation and Functionalization of Hexafluoropropene by Nickel Complexes Supported with Phosphine Ligands

(2013) Wengang Xu et al.   ORGANOMETALLICS

Titanium-Catalyzed Vinylic and Allylic CF Bond Activation-Scope, Limitations and Mechanistic Insight

(2012) Moritz F. Kuehnel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Base-Free Suzuki-Miyaura Coupling Reactions of Fluorinated Alkenes and Arenes via a Palladium Fluoride Key Intermediate

(2012) Masato Ohashi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Substitution and Cross-Coupling of Benzylic Fluorides

(2012) George Blessley et al.   ORGANIC LETTERS

Tandem C–F and C–H Bond Activation in Fluoroolefins Promoted by a Bis(diethylphosphino)methane-Bridged Diiridium Complex: Role of Water in the Activation Processes

(2012) Michael E. Slaney et al.   ORGANOMETALLICS

An Update on Recent Stoichiometric and Catalytic C–F Bond Cleavage Reactions by Lanthanide and Group 4 Transition-Metal Complexes

(2012) Marcus Klahn et al.   ORGANOMETALLICS

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Allylic Fluorination

(2011) Charlotte Hollingworth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds

(2011) Masato Ohashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Aryl and Trifluoromethyl Group Substituted Unsymmetrical Internal Alkynes

(2011) Motoi Kawatsura et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regioselective [2 + 2 + 2] Cyclotrimerization of Trifluoromethyl Group Substituted Internal Alkynes

(2011) Motoi Kawatsura et al.   ORGANIC LETTERS

Breaking C–F Bonds via Nucleophilic Attack of Coordinated Ligands: Transformations from C–F to C–X Bonds (X= H, N, O, S)

(2011) Ainara Nova et al.   ORGANOMETALLICS

Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes

(2011) Jean-François Paquin   SYNLETT

Regioselective synthesis of trifluoromethyl group containing allylic amines by palladium-catalyzed allylic amination and sequential isomerization

(2011) Takuya Hirakawa et al.   TETRAHEDRON

A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

(2010) Michael Teltewskoi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed C-F Activation of Fluoroalkenes

(2010) Moritz F. Kühnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic investigation of vinylic carbon–fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF

(2010) Bradley M. Kraft et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides

(2010) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes

(2010) Shuifa Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biaryl Phosphites: New Efficient Adaptative Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions

(2009) Montserrat Diéguez et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Substitution of Allylic Fluorides

(2009) Amaruka Hazari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Regioselectivity of the protonation of captodative enamines bearing a CF3 group

(2009) Alexander Yu. Rulev et al.   JOURNAL OF FLUORINE CHEMISTRY

Highly Diastereo- and Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with Substituted Allyl Carbonates

(2009) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective synthesis of α-trifluoromethyl-β-aryl enamines or vinylogous guanidinium salts by treatment of β-halo-β-trifluoromethylstyrenes with secondary amines under different conditions

(2009) Vasiliy M. Muzalevskiy et al.   TETRAHEDRON

Regioselective synthesis of trifluoromethyl group substituted allylic amines via palladium-catalyzed allylic amination

(2008) Motoi Kawatsura et al.   TETRAHEDRON LETTERS

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION