Chiral 3,3,3′,3′-Tetramethyl-1,1′-Spirobiindanyl Cyclopentadienyl (TMSCp) Ligands: Design, Synthesis, and Applications

Advances in Exploring Cyclopentadienyl (Cp) Rhodium Catalysts Featuring Diastereotopic or Enantiotopic Cp Faces for Asymmetric C–H Activation

(2023) Jun Wang et al.   SYNTHESIS-STUTTGART

A Class of Readily Tunable Planar‐Chiral Cyclopentadienyl Rhodium(III) Catalysts for Asymmetric C–H Activation

(2022) Xiaoqiang Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of optical active tetramethyl-1,1′-spirobiindane-based iodoarenes and evaluation of their use as axially chiral organocatalysts

(2022) Linxi Yao et al.   TETRAHEDRON LETTERS

Oxygen‐linked Cyclopentadienyl Rh(III) Complexes‐Catalyzed Asymmetric C−H Arylation of Benzo[h]quinolines with 1‐Diazonaphthoquinones

(2021) Chong-Qing Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene

(2021) Andrey V. Kolos et al.   ORGANOMETALLICS

Synthesis of Chiral Tertiary Amine–Thioureas Based on Spirobi­indane and Application in Catalytic Asymmetric Michael Addition Reaction

(2020) Zhao Han et al.   SYNTHESIS-STUTTGART

A New Class of C2‐Symmetric Chiral Cp Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application

(2020) Hao Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divergent Synthesis of Tunable Cyclopentadienyl Ligands and Their Application in Rh-Catalyzed Enantioselective Synthesis of Isoindolinone

(2020) Wen-Jun Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Asymmetric C–H Activation of N-Methoxybenzamide with Quinone and Its Application in the Asymmetric Synthesis of a Dihydrolycoricidine Analogue

(2020) Xiaoqiang Yan et al.   ORGANIC LETTERS

Chiral cyclopentadienyl ligands: design, syntheses and applications in asymmetric catalysis

(2020) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C–H Amidation

(2020) Caitlin M. B. Farr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric CpxRh(III)-Catalyzed Acrylic Acid C–H Functionalization with Allenes Provides Chiral γ-Lactones

(2020) Shou-Guo Wang et al.   ACS Catalysis

Chiral Bicyclo[2.2.2]octane‐Fused CpRh Complexes: Synthesis and Potential Use in Asymmetric C−H Activation

(2020) Guozhu Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Spirocyclic Phosphoric Acids and Their Growing Applications

(2020) Xufeng Lin et al.   CHINESE JOURNAL OF CHEMISTRY

Chiral CpxRh complexes for C–H functionalization reactions

(2020) Quannan Wang et al.   Science Bulletin

Enantioselective Synthesis of C-N Axially Chiral N-Aryloxindoles by Asymmetric Rhodium-Catalyzed Dual C-H Activation

(2019) Honghe Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N ‐Methoxybenzamide: A Versatile Directing Group for Palladium‐, Rhodium‐ and Ruthenium‐Catalyzed C−H Bond Activations

(2019) Dnyaneshwar D. Subhedar et al.   ADVANCED SYNTHESIS & CATALYSIS

RhI, IrIII ,and CoIII Complexes with Atropchiral Biaryl Cyclopentadienyl Ligands: Syntheses, Structures, and Catalytic Activities

(2019) Coralie Duchemin et al.   ORGANOMETALLICS

Towards the online computer-aided design of catalytic pockets

(2019) Laura Falivene et al.   Nature Chemistry

Atroposelective Phosphoric Acid Catalyzed Three-Component Cascade Reaction: Enantioselective Synthesis of Axially Chiral N-Arylindoles

(2019) Lei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

(2018) Evgeniya A. Trifonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent-Dependent Asymmetric Synthesis of Alkynyl and Monofluoroalkenyl Isoindolinones by CpRhIII -Catalyzed C−H Activation

(2018) Teng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles

(2018) Shou-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Application of Hexamethyl-1,1′-spirobiindane-Based Phosphine-Oxazoline Ligands in Ni-Catalyzed Asymmetric Arylation of Cyclic Aldimines

(2018) Weiye Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and application of a new hexamethyl-1,1′-spirobiindane-based chiral bisphosphine (HMSI-PHOS) ligand in asymmetric allylic alkylation

(2018) Shirui Chang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tailored trisubstituted chiral CpxRhIII catalysts for kinetic resolutions of phosphinic amides

(2018) Y. Sun et al.   Chemical Science

Rhodium-Catalyzed Asymmetric Addition of Organoboronic Acids to Aldimines Using Chiral Spiro Monophosphite-Olefin Ligands: Method Development and Mechanistic Studies

(2018) Huanyu Shan et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and application of a new chiral monodentate spiro phosphoramidite ligand based on hexamethyl-1,1′-spirobiindane backbone in asymmetric hydroamination/arylation of alkenes

(2018) Huanyu Shan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis and Optical Resolution of 3,3,3′,3′-Tetramethyl-1,1′-spirobiindane-7,7′-diol

(2018) Xufeng Lin et al.   SYNTHESIS-STUTTGART

Iron-Catalyzed Enantioselective Si–H Bond Insertions

(2018) Haorui Gu et al.   ORGANIC LETTERS

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

(2017) G. Smits et al.   Chemical Science

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE