Studying, Promoting, Exploiting, and Predicting Catalyst Dynamics: the Next Frontier in Heterogeneous Catalysis

Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO 2 hydrogenation

(2022) Jie Zhu et al.   Science Advances

The concept of active site in heterogeneous catalysis

(2022) Charlotte Vogt et al.   Nature Reviews Chemistry

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

(2022) H. Frey et al.   SCIENCE

Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses

(2022) Janis Timoshenko et al.   Nature Catalysis

Interpretable machine learning for knowledge generation in heterogeneous catalysis

(2022) Jacques A. Esterhuizen et al.   Nature Catalysis

Reaction-Mediated Transformation of Working Catalysts

(2022) Gang Wan et al.   ACS Catalysis

Bridging the Gap between the X-ray Absorption Spectroscopy and the Computational Catalysis Communities in Heterogeneous Catalysis: A Perspective on the Current and Future Research Directions

(2022) Rachita Rana et al.   ACS Catalysis

Structural evolution of Cu2O nanocube electrocatalysts for the CO2 reduction reaction

(2022) Qingye Ren et al.   Nano Energy

Operando unraveling photothermal-promoted dynamic active-sites generation in NiFe2O4 for markedly enhanced oxygen evolution

(2021) Likun Gao et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts

(2021) Mengyao Ouyang et al.   Nature Communications

Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction

(2021) Yuanyuan Li et al.   Nature Communications

Direct observation of charge separation in an organic light harvesting system by femtosecond time-resolved XPS

(2021) Friedrich Roth et al.   Nature Communications

A‐Site Management Prompts the Dynamic Reconstructed Active Phase of Perovskite Oxide OER Catalysts

(2021) Yu Sun et al.   Advanced Energy Materials

Redirecting dynamic surface restructuring of a layered transition metal oxide catalyst for superior water oxidation

(2021) Jian Wang et al.   Nature Catalysis

Reversible catalysis

(2021) Vincent Fourmond et al.   Nature Reviews Chemistry

Insights of the Dynamic Copper Active Sites in Ethylene Oxychlorination Studied by the Multivariate UV–vis–NIR Resolution Kinetic Approach

(2021) Hongfei Ma et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

In-situ and operando spectroscopies for the characterization of catalysts and of mechanisms of catalytic reactions

(2021) Francisco Zaera   JOURNAL OF CATALYSIS

Exploration of Dynamic Structure–Activity Relationship of a Platinum Nanoparticle in the CO Oxidation Reaction

(2021) Xiao-Yan Li et al.   Journal of Physical Chemistry C

Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts

(2021) Feng Li et al.   Nature Catalysis

Following the structure of copper-zinc-alumina across the pressure gap in carbon dioxide hydrogenation

(2021) Arik Beck et al.   Nature Catalysis

Effects of the Catalyst Dynamic Changes and Influence of the Reaction Environment on the Performance of Electrochemical CO 2 Reduction

(2021) Jiayi Chen et al.   ADVANCED MATERIALS

Voltage cycling process for the electroconversion of biomass-derived polyols

(2021) Dohyung Kim et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Dynamic restructuring of supported metal nanoparticles and its implications for structure insensitive catalysis

(2021) Charlotte Vogt et al.   Nature Communications

Variable Temperature and Pressure Operando MAS NMR for Catalysis Science and Related Materials

(2020) Nicholas R. Jaegers et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ensembles of Metastable States Govern Heterogeneous Catalysis on Dynamic Interfaces

(2020) Zisheng Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO 2 Reduction to Formate

(2020) Paolo Lamagni et al.   ADVANCED FUNCTIONAL MATERIALS

Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction

(2020) Shi Fang et al.   Nature Communications

Renewable power surges as pandemic scrambles global energy outlook, new report finds

(2020) Warren Cornwall   SCIENCE

Structural changes in noble metal nanoparticles during CO oxidation and their impact on catalyst activity

(2020) See Wee Chee et al.   Nature Communications

Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide

(2020) Christopher R. O’Connor et al.   Nature Communications

Dynamic co-catalysis of Au single atoms and nanoporous Au for methane pyrolysis

(2020) Wei Xi et al.   Nature Communications

Structural Rearrangements of Subnanometer Cu Oxide Clusters Govern Catalytic Oxidation

(2020) Geng Sun et al.   ACS Catalysis

Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation

(2020) Xiaoben Zhang et al.   Nature Catalysis

Understanding of K and Mg co-promoter effect in ethylene oxychlorination by operando UV–vis-NIR spectroscopy

(2020) Hongfei Ma et al.   CATALYSIS TODAY

Resonance-Promoted Formic Acid Oxidation via Dynamic Electrocatalytic Modulation

(2020) Joshua Gopeesingh et al.   ACS Catalysis

Dynamic Surface Reconstruction of Single-Atom Bimetallic Alloy under Operando Electrochemical Conditions

(2020) Xiaokang Liu et al.   NANO LETTERS

Dynamic evolution and reversibility of single-atom Ni(II) active site in 1T-MoS2 electrocatalysts for hydrogen evolution

(2020) Brian Pattengale et al.   Nature Communications

The Catalytic Mechanics of Dynamic Surfaces: Stimulating Methods for Promoting Catalytic Resonance

(2020) Manish Shetty et al.   ACS Catalysis

Dynamic Control of Elementary Step Energetics via Pulsed Illumination Enhances Photocatalysis on Metal Nanoparticles

(2020) Ji Qi et al.   ACS Energy Letters

Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2

(2020) Florian Maurer et al.   Nature Catalysis

Unveiling the Activity Origin of Iron Nitride as Catalytic Material for Efficient Hydrogenation of CO 2 to C 2+ Hydrocarbons

(2020) Bohang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction-driven surface reconstruction of ZnAl2O4 boosts the methanol selectivity in CO2 catalytic hydrogenation

(2020) Xinbao Zhang et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Functional Role of Fe-Doping in Co-Based Perovskite Oxide Catalysts for Oxygen Evolution Reaction

(2019) Bae-Jung Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Genesis and Stability of Hydronium Ions in Zeolite Channels

(2019) Meng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Negative Charging of Au Nanoparticles during Methanol Synthesis from CO₂/H₂ on a Au/ZnO Catalyst: Insights from Operando Infrared and Near-ambient Pressure XPS and XAS

(2019) R. Juergen Behm et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Infrared Spectroscopy as a Tool for Monitoring Molecular Catalyst for Hydroformylation in Continuous Processes

(2019) J. M. Dreimann et al.   ACS Catalysis

Principles of Dynamic Heterogeneous Catalysis: Surface Resonance and Turnover Frequency Response

(2019) Matthew Alexander Ardagh et al.   ACS Catalysis

Fischer–Tropsch Synthesis to Olefins: Catalytic Performance and Structure Evolution of Co2C-Based Catalysts under a CO2 Environment

(2019) Tiejun Lin et al.   ACS Catalysis

Toward Efficient Carbon and Water Cycles: Emerging Opportunities with Single‐Site Catalysts Made of 3d Transition Metals

(2019) Gang Wan et al.   ADVANCED MATERIALS

Engineering of Ruthenium-Iron Oxide Colloidal Heterostructures: Improved Yields in CO2 Hydrogenation to Hydrocarbons

(2019) Aisulu Aitbekova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Dehydrogenation of Cyclohexane by Cu vs Pd Clusters: Selectivity Control by Specific Cluster Dynamics

(2019) Avik Halder et al.   ChemCatChem

Shift of the Optimum Binding Energy at Higher Rates of Catalysis

(2019) Hideshi Ooka et al.   Journal of Physical Chemistry Letters

Operando Near-Ambient Pressure X-ray Photoelectron Spectroscopy Study of the CO Oxidation Reaction on the Oxide/Metal Model Catalyst ZnO/Pt(111)

(2019) Hang Liu et al.   ACS Catalysis

Investigating the dynamic structural changes on Cu/CeO2 catalysts observed during CO2 hydrogenation

(2019) Pramod Sripada et al.   JOURNAL OF CATALYSIS

Enhanced Stability of Pt-Cu Single-Atom Alloy Catalysts: In Situ Characterization of the Pt/Cu(111) Surface in an Ambient Pressure of CO

(2018) Juan Pablo Simonovis et al.   Journal of Physical Chemistry C

Local Fluxionality of Surface-Deposited Cluster Catalysts: The Case of Pt7 on Al2O3

(2018) Huanchen Zhai et al.   Journal of Physical Chemistry Letters

Heterogeneous single-atom catalysis

(2018) Aiqin Wang et al.   Nature Reviews Chemistry

Single-Atom Alloys as a Reductionist Approach to the Rational Design of Heterogeneous Catalysts

(2018) Georgios Giannakakis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dynamics of Surface Alloys: Rearrangement of Pd/Ag(111) Induced by CO and O2

(2018) Matthijs A. van Spronsen et al.   Journal of Physical Chemistry C

Dynamic Phase Diagram of Catalytic Surface of Hexagonal Boron Nitride under Conditions of Oxidative Dehydrogenation of Propane

(2018) Zisheng Zhang et al.   Journal of Physical Chemistry Letters

Fluoride-Induced Dynamic Surface Self-Reconstruction Produces Unexpectedly Efficient Oxygen-Evolution Catalyst

(2018) Bowei Zhang et al.   NANO LETTERS

Three-Dimensional Quantification of the Facet Evolution of Pt Nanoparticles in a Variable Gaseous Environment

(2018) Thomas Altantzis et al.   NANO LETTERS

Sabatier Principle for Interfacial (Heterogeneous) Enzyme Catalysis

(2018) Jeppe Kari et al.   ACS Catalysis

Perovskites in catalysis and electrocatalysis

(2017) Jonathan Hwang et al.   SCIENCE

Grand challenges for catalysis in the Science and Technology Roadmap on Catalysis for Europe: moving ahead for a sustainable future

(2017) P. Lanzafame et al.   Catalysis Science & Technology

Heterogeneous Catalysis: Understanding for Designing, and Designing for Applications

(2016) Avelino Corma   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis

(2016) Franklin (Feng) Tao et al.   CHEMICAL REVIEWS

Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction

(2016) Shuyi Zhang et al.   NANO LETTERS

Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts

(2016) John C. Matsubu et al.   Nature Chemistry

Dynamic restructuring drives catalytic activity on nanoporous gold–silver alloy catalysts

(2016) Branko Zugic et al.   NATURE MATERIALS

Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design

(2016) Jeffrey Greeley   Annual Review of Chemical and Biomolecular Engineering

Highly Active and Stable CeO2-Promoted CuCl2/Al2O3 Oxychlorination Catalysts Developed by Rational Design Using a Rate Diagram of the Catalytic Cycle

(2016) K. R. Rout et al.   ACS Catalysis

Quick-EXAFS setup at the SuperXAS beamline forin situX-ray absorption spectroscopy with 10 ms time resolution

(2016) Oliver Müller et al.   JOURNAL OF SYNCHROTRON RADIATION

Catalytically Active and Spectator Ce3+in Ceria-Supported Metal Catalysts

(2015) René Kopelent et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis

(2015) Andrew J. Medford et al.   JOURNAL OF CATALYSIS

Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting

(2015) Daniel Friebel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Temperature and Catalyst Concentration on Polyglycerol during Synthesis

(2015) Carolina Ardila-Suárez et al.   International Journal of Polymer Science

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

(2013) Xiao-Feng Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tuning Selectivity in Propylene Epoxidation by Plasmon Mediated Photo-Switching of Cu Oxidation State

(2013) A. Marimuthu et al.   SCIENCE

Recent Advances in the Application of Electron Tomography to Materials Chemistry

(2012) Rowan Leary et al.   ACCOUNTS OF CHEMICAL RESEARCH

New Challenges in Heterogeneous Catalysis for the 21st Century

(2012) Francisco Zaera   CATALYSIS LETTERS

Exploring the environmental transmission electron microscope

(2012) Jakob B. Wagner et al.   MICRON

Quick-scanning x-ray absorption spectroscopy system with a servo-motor-driven channel-cut monochromator with a temporal resolution of 10 ms

(2012) T. Nonaka et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

Exceptional Activity for Methane Combustion over Modular Pd@CeO2 Subunits on Functionalized Al2O3

(2012) M. Cargnello et al.   SCIENCE

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts

(2012) M. Behrens et al.   SCIENCE

In-situ characterization of water–gas shift catalysts using time-resolved X-ray diffraction

(2009) José A. Rodriguez et al.   CATALYSIS TODAY

Towards the computational design of solid catalysts

(2009) J. K. Nørskov et al.   Nature Chemistry

Reactions at Surfaces: From Atoms to Complexity (Nobel Lecture)

(2008) Gerhard Ertl   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION