Reversible catalysis

Electrochemical Characterization of a Complex FeFe Hydrogenase, the Electron-Bifurcating Hnd From Desulfovibrio fructosovorans

(2021) Aurore Jacq-Bailly et al.   Frontiers in Chemistry

A safety cap protects hydrogenase from oxygen attack

(2021) Martin Winkler et al.   Nature Communications

Reversible H2 oxidation and evolution by hydrogenase embedded in a redox polymer film

(2021) Steffen Hardt et al.   Nature Catalysis

Enhanced Electrosynthetic Hydrogen Evolution by Hydrogenases Embedded in a Redox‐Active Hydrogel

(2020) John Charles Ruth et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible interconversion between methanol-diamine and diamide for hydrogen storage based on manganese catalyzed (de)hydrogenation

(2020) Zhihui Shao et al.   Nature Communications

The roles of long-range proton-coupled electron transfer in the directionality and efficiency of [FeFe]-hydrogenases

(2020) Oliver Lampret et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

(2020) Hui Chen et al.   CHEMICAL REVIEWS

Mechanisms for achieving high speed and efficiency in biomolecular machines

(2019) Jason A. Wagoner et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea

(2019) Yinjun Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

What would it take for renewably powered electrosynthesis to displace petrochemical processes?

(2019) Phil De Luna et al.   SCIENCE

Development and Assessment of a Criterion for the Application of Brønsted–Evans–Polanyi Relations for Dissociation Catalytic Reactions at Surfaces

(2019) Zhao-Bin Ding et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Understanding and Design of Bidirectional and Reversible Catalysts of Multielectron, Multistep Reactions

(2019) Vincent Fourmond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interpreting the Electrocatalytic Voltammetry of Homogeneous Catalysts by the Foot of the Wave Analysis and Its Wider Implications

(2019) Vincent C.-C. Wang et al.   ACS Catalysis

Redox (in)activations of metalloenzymes, a protein film voltammetry approach

(2019) Melisa del Barrio et al.   ChemElectroChem

Ethylene glycol as an efficient and reversible liquid-organic hydrogen carrier

(2019) You-Quan Zou et al.   Nature Catalysis

Theory of Nonequilibrium Free Energy Transduction by Molecular Machines

(2019) Aidan I. Brown et al.   CHEMICAL REVIEWS

Complete Protection of O2-Sensitive Catalysts in Thin Films

(2019) Huaiguang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Opposing Pressures of Speed and Efficiency Guide the Evolution of Molecular Machines

(2019) Jason A Wagoner et al.   MOLECULAR BIOLOGY AND EVOLUTION

Shift of the Optimum Binding Energy at Higher Rates of Catalysis

(2019) Hideshi Ooka et al.   Journal of Physical Chemistry Letters

Strategies to break linear scaling relationships

(2019) Javier Pérez-Ramírez et al.   Nature Catalysis

Reversible and Selective CO2 to HCO2 − Electrocatalysis near the Thermodynamic Potential

(2019) Drew W. Cunningham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning Catalytic Bias of Hydrogen Gas Producing Hydrogenases

(2019) Jacob H. Artz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Creating a Low-Potential Redox Polymer for Efficient Electroenzymatic CO2 Reduction

(2018) Mengwei Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivation of standard [NiFe]-hydrogenase and bioelectrochemical catalysis of proton reduction and hydrogen oxidation in a mediated-electron-transfer system

(2018) Saeko Shiraiwa et al.   BIOELECTROCHEMISTRY

Allocating and Splitting Free Energy to Maximize Molecular Machine Flux

(2018) Aidan I. Brown et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Engineering an [FeFe]-Hydrogenase: Do Accessory Clusters Influence O2 Resistance and Catalytic Bias?

(2018) Giorgio Caserta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry of Systems Approaching Reversibility

(2018) Jean-Michel Savéant   ACS Catalysis

Designing electrochemically reversible H2 oxidation and production catalysts

(2018) Arnab Dutta et al.   Nature Reviews Chemistry

Trajectory and Cycle-Based Thermodynamics and Kinetics of Molecular Machines: The Importance of Microscopic Reversibility

(2018) R. Dean Astumian   ACCOUNTS OF CHEMICAL RESEARCH

His-Ligation to the [4Fe–4S] Subcluster Tunes the Catalytic Bias of [FeFe] Hydrogenase

(2018) Patricia Rodríguez-Maciá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonequilibrium Energetics of Molecular Motor Kinesin

(2018) Takayuki Ariga et al.   PHYSICAL REVIEW LETTERS

Nitrogenase Bioelectrocatalysis: From Understanding Electron-Transfer Mechanisms to Energy Applications

(2018) Rong Cai et al.   ACS Energy Letters

Transient Catalytic Voltammetry of Sulfite Oxidase Reveals Rate Limiting Conformational Changes

(2017) Ting Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Molecular Catalysis of Electrochemical Reactions: Catalyst Benchmarking and Optimization Strategies

(2017) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Retuning the Catalytic Bias and Overpotential of a [NiFe]-Hydrogenase via a Single Amino Acid Exchange at the Electron Entry/Exit Site

(2017) Hope Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interplay between CN– Ligands and the Secondary Coordination Sphere of the H-Cluster in [FeFe]-Hydrogenases

(2017) Oliver Lampret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allocating dissipation across a molecular machine cycle to maximize flux

(2017) Aidan I. Brown et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Influence of the [4Fe–4S] cluster coordinating cysteines on active site maturation and catalytic properties of C. reinhardtii [FeFe]-hydrogenase

(2017) Leonie Kertess et al.   Chemical Science

High-Power Formate/Dioxygen Biofuel Cell Based on Mediated Electron Transfer Type Bioelectrocatalysis

(2017) Kento Sakai et al.   ACS Catalysis

The Physiological Functions and Structural Determinants of Catalytic Bias in the [FeFe]-Hydrogenases CpI and CpII of Clostridium pasteurianum Strain W5

(2017) Jesse B. Therien et al.   Frontiers in Microbiology

Towards an intelligent design of molecular electrocatalysts

(2017) Cyrille Costentin et al.   Nature Reviews Chemistry

Thermodynamic Hydricity of Transition Metal Hydrides

(2016) Eric S. Wiedner et al.   CHEMICAL REVIEWS

A Critical Review on Hydrogen Evolution Electrocatalysis: Re-exploring the Volcano-relationship

(2016) Aleksandar R. Zeradjanin et al.   ELECTROANALYSIS

Molecular Motors: Power Strokes Outperform Brownian Ratchets

(2016) Jason A. Wagoner et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts

(2016) Eric S. Wiedner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An autonomous chemically fuelled small-molecule motor

(2016) Miriam R. Wilson et al.   NATURE

Achieving Reversible H2/H+ Interconversion at Room Temperature with Enzyme-Inspired Molecular Complexes: A Mechanistic Study

(2016) Nilusha Priyadarshani et al.   ACS Catalysis

A Redox Hydrogel Protects the O2-Sensitive [FeFe]-Hydrogenase fromChlamydomonas reinhardtiifrom Oxidative Damage

(2015) Alaa Alsheikh Oughli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions

(2015) Yan Jiao et al.   CHEMICAL SOCIETY REVIEWS

The Role of Solvent and the Outer Coordination Sphere on H2Oxidation Using [Ni(PCy2NPyz2)2]2+

(2015) Arnab Dutta et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen

(2015) Simone Raugei et al.   INORGANIC CHEMISTRY

Examining the Linearity of Transition State Scaling Relations

(2015) Philipp N. Plessow et al.   Journal of Physical Chemistry C

Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with pKa for Mechanistic Investigation of a Nickel-Based Hydrogen Evolution Catalyst

(2015) Eric S. Rountree et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Protein Film Electrochemistry Provides a Direct Measure of the Tetrathionate/Thiosulfate Reduction Potential

(2015) Julia M. Kurth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible catalytic dehydrogenation of alcohols for energy storage

(2015) Peter J. Bonitatibus et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts

(2015) Ming-Hsun Ho et al.   ACS Catalysis

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Reversible Interconversion of CO2 and Formate by a Molybdenum-Containing Formate Dehydrogenase

(2014) Arnau Bassegoda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A redox hydrogel protects hydrogenase from high-potential deactivation and oxygen damage

(2014) Nicolas Plumeré et al.   Nature Chemistry

Amino acid modified Ni catalyst exhibits reversible H2oxidation/production over a broad pH range at elevated temperatures

(2014) Arnab Dutta et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Volcano plots in hydrogen electrocatalysis – uses and abuses

(2014) Paola Quaino et al.   Beilstein Journal of Nanotechnology

Benchmarking the Stability of Oxygen Evolution Reaction Catalysts: The Importance of Monitoring Mass Losses

(2014) Rasmus Frydendal et al.   ChemElectroChem

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

(2013) Sigolène Canaguier et al.   CHEMICAL COMMUNICATIONS

A proton channel allows a hydrogen oxidation catalyst to operate at a moderate overpotential with water acting as a base

(2013) Sheri Lense et al.   CHEMICAL COMMUNICATIONS

Controlling proton movement: electrocatalytic oxidation of hydrogen by a nickel(ii) complex containing proton relays in the second and outer coordination spheres

(2013) Parthapratim Das et al.   DALTON TRANSACTIONS

The origins of enzyme kinetics

(2013) Athel Cornish-Bowden   FEBS LETTERS

pH-Dependent Reduction Potentials and Proton-Coupled Electron Transfer Mechanisms in Hydrogen-Producing Nickel Molecular Electrocatalysts

(2013) Samantha Horvath et al.   INORGANIC CHEMISTRY

Steady-State Catalytic Wave-Shapes for 2-Electron Reversible Electrocatalysts and Enzymes

(2013) Vincent Fourmond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst

(2013) Arnab Dutta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two Pathways for Electrocatalytic Oxidation of Hydrogen by a Nickel Bis(diphosphine) Complex with Pendant Amines in the Second Coordination Sphere

(2013) Jenny Y. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theory of multiple proton–electron transfer reactions and its implications for electrocatalysis

(2013) Marc T. M. Koper   Chemical Science

Determining the Overpotential for a Molecular Electrocatalyst

(2013) Aaron M. Appel et al.   ACS Catalysis

Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic

(2012) Stuart E. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Role of Pendant Amines in the Breaking and Forming of Molecular Hydrogen Catalyzed by Nickel Complexes

(2012) Simone Raugei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Understanding and Tuning the Catalytic Bias of Hydrogenase

(2012) Abbas Abou Hamdan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

O2-independent formation of the inactive states of NiFe hydrogenase

(2012) Abbas Abou Hamdan et al.   Nature Chemical Biology

Electrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases

(2012) S. V. Hexter et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The Moderately Efficient Enzyme: Evolutionary and Physicochemical Trends Shaping Enzyme Parameters

(2011) Arren Bar-Even et al.   BIOCHEMISTRY

Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces

(2011) Isabela C. Man et al.   ChemCatChem

The [NiFe]-Hydrogenase of the CyanobacteriumSynechocystissp. PCC 6803 Works Bidirectionally with a Bias to H2Production

(2011) Chelsea L. McIntosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rates of Intra- and Intermolecular Electron Transfers in Hydrogenase Deduced from Steady-State Activity Measurements

(2011) Sébastien Dementin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A universal pathway for kinesin stepping

(2011) Bason E Clancy et al.   NATURE STRUCTURAL & MOLECULAR BIOLOGY

Thermodynamic efficiency and mechanochemical coupling of F1-ATPase

(2011) S. Toyabe et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Reversibility and efficiency in electrocatalytic energy conversion and lessons from enzymes

(2011) F. A. Armstrong et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

[Ni(PPh2NBn2)2(CH3CN)]2+ as an Electrocatalyst for H2 Production: Dependence on Acid Strength and Isomer Distribution

(2011) Aaron M. Appel et al.   ACS Catalysis

How to Conceptualize Catalytic Cycles? The Energetic Span Model

(2010) Sebastian Kozuch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines

(2010) Jenny Y. Yang et al.   CHEMICAL COMMUNICATIONS

Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis

(2010) Marc T.M. Koper   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations

(2010) Egill Skúlason et al.   Journal of Physical Chemistry C

“If Pigs Could Fly” Chemistry: A Tutorial on the Principle of Microscopic Reversibility

(2009) Donna G. Blackmond   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Degree of Rate Control: How Much the Energies of Intermediates and Transition States Control Rates

(2009) Carsten Stegelmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards the computational design of solid catalysts

(2009) J. K. Nørskov et al.   Nature Chemistry

Kinesin’s backsteps under mechanical load

(2009) Changbong Hyeon et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake

(2009) A. Le Goff et al.   SCIENCE

Direct Electrochemistry of Redox Enzymes as a Tool for Mechanistic Studies

(2008) Christophe Léger et al.   CHEMICAL REVIEWS

Kinetics of Redox Polymer-Mediated Enzyme Electrodes

(2008) Joshua W. Gallaway et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY