Nickel-catalyzed hydromonofluoromethylation of unactivated alkenes for expedient construction of primary alkyl fluorides

Catalytic remote hydrohalogenation of internal alkenes

(2022) Xiang Li et al.   Nature Chemistry

Diverse Synthesis of Chiral Trifluoromethylated Alkanes via Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Unactivated Olefins

(2022) Wenqing Guo et al.   ORGANIC LETTERS

Chiral Alkyl Amine Synthesis via Catalytic Enantioselective Hydroalkylation of Enecarbamates

(2021) Deyun Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diversity‐Oriented Synthesis of Aliphatic Fluorides via Reductive C(sp3)–C(sp3) Cross‐Coupling Fluoroalkylation

(2021) Jie Sheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations

(2021) Shan Wang et al.   Nature Communications

Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations

(2021) Xiangyu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of Monofluoroalkenes as Molecular Platform for Diversity-Oriented Syntheses of Tertiary Aliphatic Fluorides via Nickel/Manganese-Dual Catalysis

(2021) Yanlin Li et al.   CCS Chemistry

Divergent, stereospecific mono- and difluoromethylation of boronic esters

(2020) Varinder Kumar Aggarwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Enabled Nickel-Catalyzed Redox-Relay Migratory Hydroarylation of Alkenes with Arylborons

(2020) Yuli He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The fluorination of C-H bonds: developments and perspectives

(2019) Veronique Gouverneur et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Deoxyfluorination of Alcohols with N ‐Tosyl‐4‐chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature

(2019) Junkai Guo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis

(2019) Naoki Noto et al.   ACS Catalysis

Copper-Catalyzed Regioselective Borylfluoromethylation of Alkenes

(2019) Nuo-Yi Wu et al.   ACS Catalysis

Synthesis of Monofluoromethyl Selenoethers of Aryl and Alkyl from Organoselenocyanate via One‐Pot Reaction

(2019) Yuan Cao et al.   ADVANCED SYNTHESIS & CATALYSIS

Rapid Access to Highly Functionalized Alkyl Boronates by NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes

(2019) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Monofluoroalkyl Halides for Late-Stage Monofluoroalkylation

(2018) Jie Sheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design

(2018) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Terminal C(sp 3 ) H alkylation of internal alkenes via Ni/H-catalyzed isomerization

(2018) Zhen-Yu Wang et al.   TETRAHEDRON LETTERS

Radical Fluoroalkylation Reactions

(2018) Sebastián Barata-Vallejo et al.   ACS Catalysis

Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation

(2018) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

CuI-Catalyzed Fluorodesulfurization for the Synthesis of Monofluoromethyl Aryl Ethers

(2017) Yang Geng et al.   JOURNAL OF ORGANIC CHEMISTRY

Exploiting a “Beast” in Carbenoid Chemistry: Development of a Straightforward Direct Nucleophilic Fluoromethylation Strategy

(2017) Giovanna Parisi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective Benzylic C–H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins

(2017) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation

(2016) David A. Petrone et al.   CHEMICAL REVIEWS

The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations

(2016) Chuanfa Ni et al.   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Monofluoromethylation of Aryl Boronic Acids

(2015) Yi-Ming Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Suzuki Cross-Couplings of Unactivated 1-Fluoro-1-haloalkanes: Synthesis of Chiral β-, γ-, δ-, and ε-Fluoroalkanes

(2015) Xiaojian Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates

(2015) Zhengbiao He et al.   ORGANIC LETTERS

Mild Copper-Catalyzed Fluorination of Alkyl Triflates with Potassium Fluoride

(2014) Hester Dang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis

(2014) Michael G. Campbell et al.   CHEMICAL REVIEWS

Natural and engineered biosynthesis of fluorinated natural products

(2014) Mark C. Walker et al.   CHEMICAL SOCIETY REVIEWS

Efficient Synthesis of Secondary Alkyl Fluorides via Suzuki Cross-Coupling Reaction of 1-Halo-1-fluoroalkanes

(2014) Xiaojian Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Highly Enantioselective Monofluoromethylation of C2-Arylindoles Using FBSM under Chiral Phase-Transfer Catalysis

(2013) Kohei Matsuzaki et al.   ORGANIC LETTERS

Direct monofluoromethylation of O-, S-, N-, and P-nucleophiles with PhSO(NTs)CH2F: the accelerating effect of α-fluorine substitution

(2013) Xiao Shen et al.   Chemical Science

Core Values: Elucidating the Role of Seed Structure in the Synthesis of Symmetrically Branched Nanocrystals

(2012) Christopher J. DeSantis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group

(2012) Yanchuan Zhao et al.   ORGANIC LETTERS

Organic fluorine compounds: a great opportunity for enhanced materials properties

(2011) Ricarda Berger et al.   CHEMICAL SOCIETY REVIEWS

Palladium(0)-Mediated Rapid Methylation and Fluoromethylation on Carbon Frameworks by Reacting Methyl and Fluoromethyl Iodide with Aryl and Alkenyl Boronic Acid Esters: Useful for the Synthesis of [11C]CH3C- and [18F]FCH2C-Containing PET Tracers (PET=Positron Emission Tomography)

(2009) Hisashi Doi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Electrophilic Monofluoromethylation

(2008) G. K. Surya Prakash et al.   ORGANIC LETTERS

Stereoselective Monofluoromethylation ofN-tert-Butylsulfinyl Ketimines Using Pregenerated Fluoro(phenylsulfonyl)methyl Anion

(2008) Jun Liu et al.   ORGANIC LETTERS