Synthesis of N-CF3 Amidines/Imidates/Thioimidates via N-CF3 Nitrilium Ions

General Synthesis of N-Trifluoromethyl Compounds with N-Trifluoromethyl Hydroxylamine Reagents

(2022) Shuai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of N-perfluoroalkyl-3,4-disubstituted pyrroles by rhodium-catalyzed transannulation of N-fluoroalkyl-1,2,3-triazoles with terminal alkynes

(2021) Olga Bakhanovich et al.   Beilstein Journal of Organic Chemistry

Antimicrobial Peptides and Copper(II) Ions: Novel Therapeutic Opportunities

(2021) Jasmin Portelinha et al.   CHEMICAL REVIEWS

Smart Materials for Microrobots

(2021) Fernando Soto et al.   CHEMICAL REVIEWS

Synthesis of N-CF3 Alkynamides and Derivatives Enabled by Ni-Catalyzed Alkynylation of N-CF3 Carbamoyl Fluorides

(2021) Christian D.-T. Nielsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of N-trifluoromethyl amides from carboxylic acids

(2021) Jianbo Liu et al.   Chem

An N ‐Trifluoromethylation/Cyclization Strategy for Accessing Diverse N ‐Trifluoromethyl Azoles from Nitriles and 1,3‐Dipoles

(2021) Ru Zhong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N ‐Trifluoromethyl Hydrazines, Indoles and Their Derivatives

(2020) Samir Bouayad‐Gervais et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver‐Mediated N ‐Trifluoromethylation of Amides and Peptides

(2020) Zhenzhen Zhang et al.   CHINESE JOURNAL OF CHEMISTRY

Direct Synthesis of Thiocarbamoyl Fluorides and Trifluoromethylamines Through Fluorinative Desulfurization

(2019) Killian Onida et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Straightforward access to N-trifluoromethyl amides, carbamates, thiocarbamates and ureas

(2019) Thomas Scattolin et al.   NATURE

A rhodium-catalyzed transannulation of N-(per)fluoroalkyl-1,2,3-triazoles under microwave conditions – a general route to N-(per)fluoroalkyl-substituted five-membered heterocycles

(2018) Vladimir Motornov et al.   CHEMICAL COMMUNICATIONS

The main and recent syntheses of the N -CF 3 motif

(2018) Thierry Milcent et al.   COMPTES RENDUS CHIMIE

Synthesis of Chloro(phenyl)trifluoromethyliodane and Catalyst-Free Electrophilic Trifluoromethylations

(2018) Cong Xu et al.   ORGANIC LETTERS

Azolate Anions in Ionic Liquids: Promising and Under-utilized Components of the Ionic Liquid Toolbox

(2018) Max Eric Easton et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes

(2017) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrilium ions – synthesis and applications

(2017) Tom van Dijk et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Trifluoromethylation of Nitrosoarenes with Sodium Triflinate

(2017) Angela van der Werf et al.   ORGANIC LETTERS

Azidoperfluoroalkanes: Synthesis and Application in Copper(I)-Catalyzed Azide-Alkyne Cycloaddition

(2016) Zsófia E. Blastik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me4 N)SCF3

(2016) Thomas Scattolin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and Reactivity of Trifluoromethyl Iodonium Salts

(2016) Johnathan N. Brantley et al.   ACS Central Science

Electrophilic Amination of Fluoroalkyl Groups on Azodicarboxylate Derivatives

(2015) Marius Mamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrophilic N-Trifluoromethylation of N–H Ketimines

(2015) Gang Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Base-Stabilized Nitrilium Ions as Convenient Imine Synthons

(2015) Tom van Dijk et al.   ORGANIC LETTERS

Silver-Mediated N-Trifluoromethylation of Sulfoximines

(2015) Fan Teng et al.   ORGANIC LETTERS

Facile Synthesis of Phosphaamidines and Phosphaamidinates using Nitrilium Ions as an Imine Synthon

(2014) Tom van Dijk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

(2014) Chuanfa Ni et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent

(2012) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The New Age of Electrophilic Perfluoro­alk­ylation Reactions

(2012) Yohan Macé et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

A Ritter-Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine Reagents

(2010) Katrin Niedermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-trifluoromethylazoles

(2009) T. M. Sokolenko et al.   Chemistry of Heterocyclic Compounds

Toward the Synthesis of the RareN-(Trifluoromethyl)amides and theN-(Difluoromethylene)-N-(trifluoromethyl)amines [RN(CF3)CF2R′] Using BrF3

(2009) Youlia Hagooly et al.   JOURNAL OF ORGANIC CHEMISTRY

Systematic optimization of long-range corrected hybrid density functionals

(2008) Jeng-Da Chai et al.   JOURNAL OF CHEMICAL PHYSICS

Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections

(2008) Jeng-Da Chai et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS