Mechanism-based ligand design for copper-catalysed enantioconvergent C(sp3)–C(sp) cross-coupling of tertiary electrophiles with alkynes

Quaternary stereocentres via catalytic enantioconvergent nucleophilic substitution reactions of tertiary alkyl halides

(2021) Zhaobin Wang et al.   Nature Chemistry

Copper-Catalyzed Asymmetric Radical 1,2-Carboalkynylation of Alkenes with Alkyl Halides and Terminal Alkynes

(2020) Xiao-Yang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective hydrogenation of dialkyl ketones

(2020) Feng-Hua Zhang et al.   Nature Catalysis

Copper‐Catalyzed Enantioconvergent Cross‐Coupling of Racemic Alkyl Bromides with Azole C(sp2)–H Bonds

(2020) Xiao-Long Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting attractive non-covalent interactions for the enantioselective catalysis of reactions involving radical intermediates

(2020) Rupert S. J. Proctor et al.   Nature Chemistry

Using nature’s blueprint to expand catalysis with Earth-abundant metals

(2020) R. Morris Bullock et al.   SCIENCE

Catalytic enantioselective synthesis of chiral tetraarylmethanes

(2020) Xingguang Li et al.   Nature Catalysis

An enantioconvergent halogenophilic nucleophilic substitution (SN2X) reaction

(2019) Xin Zhang et al.   SCIENCE

Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals

(2019) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistically Guided Predictive Models for Ligand and Initiator Effects in Copper-Catalyzed Atom Transfer Radical Polymerization (Cu-ATRP)

(2019) Cheng Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Reactions Involving Radicals

(2019) Qiang-Shuai Gu et al.   ACCOUNTS OF CHEMICAL RESEARCH

A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

(2019) Xiao-Yang Dong et al.   Nature Chemistry

Pd Metal Catalysts for Cross-Couplings and Related Reactions in the 21st Century: A Critical Review

(2018) Andrea Biffis et al.   CHEMICAL REVIEWS

Formal enantioconvergent substitution of alkyl halides via catalytic asymmetric photoredox radical coupling

(2018) Jiangtao Li et al.   Nature Communications

Quaternary stereocentres via an enantioconvergent catalytic SN1 reaction

(2018) Alison E. Wendlandt et al.   NATURE

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Antibacterial and β-Lactamase Inhibitory Activity of Monocyclic β-Lactams

(2017) Lena Decuyper et al.   MEDICINAL RESEARCH REVIEWS

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Construction of Chiral Tri- and Tetra-Arylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters

(2016) Kouhei Tsuchida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Enantioselective Formation of All-Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group

(2014) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemical Synthesis of β-Lactams: Asymmetric Catalysis and Other Recent Advances

(2014) Cody Ross Pitts et al.   CHEMICAL REVIEWS

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

On the mechanism of activation of copper-catalyzed atom transfer radical polymerization

(2013) Abdirisak Ahmed Isse et al.   ELECTROCHIMICA ACTA

Copper's Contribution to Amination Catalysis

(2013) S. R. Chemler   SCIENCE

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchona Alkaloid Amides/Dialkylzinc Catalyzed Enantioselective Desymmetrization of Aziridines with Phosphites

(2012) Masashi Hayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monocyclic β-Lactams: New Structures for New Biological Activities

(2011) P. Galletti et al.   CURRENT MEDICINAL CHEMISTRY

A New Family of Cinchona-Derived Amino Phosphine Precatalysts: Application to the Highly Enantio- and Diastereoselective Silver-Catalyzed Isocyanoacetate Aldol Reaction

(2011) Filippo Sladojevich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of All-Carbon Quaternary Centers by Branch-Selective Pd-Catalyzed Allyl–Allyl Cross-Coupling

(2011) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Stereoablative Alkylation of 3-Halooxindoles: Facile Access to Oxindoles with C3 All-Carbon Quaternary Stereocenters

(2009) Sandy Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ab Initio Evaluation of the Thermodynamic and Electrochemical Properties of Alkyl Halides and Radicals and Their Mechanistic Implications for Atom Transfer Radical Polymerization

(2008) Ching Yeh Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY