Catalyst‐Dependent Stereospecific [3,3]‐Sigmatropic Rearrangement of Sulfoxide‐Ynamides: Divergent Synthesis of Chiral Medium‐Sized N , S ‐Heterocycles

Synthesis of Axially Chiral N ‐Arylindoles via Atroposelective Cyclization of Ynamides Catalyzed by Chiral Brønsted Acids

(2022) Ze‐Shu Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Review on Synthesis, Reactions and Biological Properties of Seven Member Heterocyclic Compounds: Azepine, Azepane, Azepinone

(2021) Manvinder Kaur et al.   CURRENT ORGANIC CHEMISTRY

Gold-Catalyzed Intermolecular Alkyne Oxyarylation for C3 Functionalization of Benzothiophenes

(2021) Paige A. Rist et al.   ORGANIC LETTERS

Gold-catalysed cycloisomerisation of ynamides to access 2,2-disubstituted tetrahydrothiophene motifs

(2021) Parmjit Heer et al.   SYNLETT

A Synthetic Route to Benzothiazocines with Two or Three Carbon Stereocenters via Copper‐Catalyzed Intramolecular N‐Arylation

(2021) Mickael Choury et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Brønsted Acid Catalyzed Dearomatization by Intramolecular Hydroalkoxylation/Claisen Rearrangement: Diastereo‐ and Enantioselective Synthesis of Spirolactams

(2021) Peng‐Fei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper‐Catalyzed Asymmetric Diyne Cyclization via [1,2]‐Stevens‐Type Rearrangement for the Synthesis of Chiral Chromeno[3,4‐ c ]pyrroles

(2021) Feng‐Lin Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Claisen rearrangement triggered by transition metal-catalyzed alkyne alkoxylation

(2021) Chong-Yang Shi et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis of Cyclopentenones with C4-Quaternary Stereocenters via Stereospecific [3,3]-Sigmatropic Rearrangement and Applications in Total Synthesis of Sesquiterpenoids

(2021) Weiping Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric dearomatization catalysed by chiral Brønsted acids via activation of ynamides

(2021) Ying-Qi Zhang et al.   Nature Chemistry

Ynamide Smiles Rearrangement Triggered by Visible-Light-Mediated Regioselective Ketyl–Ynamide Coupling: Rapid Access to Functionalized Indoles and Isoquinolines

(2020) Ze-Shu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-catalyzed cycloisomerization of sulfur ylides to dihydrobenzothiepines

(2020) Nuno Maulide et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Asymmetric Reaction of Alkenyl Diynes with Styrenes by Formal [3 + 2] Cycloaddition via Cu-Containing All-Carbon 1,3-Dipoles: Access to Chiral Pyrrole-Fused Bridged [2.2.1] Skeletons

(2020) Feng-Lin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper‐Catalyzed Azide‐Ynamide Cyclization for Generation of α‐Imino Copper Carbenes: Divergent and Enantioselective Access to Polycyclic N‐Heterocycles

(2020) Longwu Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in the synthetic chemistry of 1,5 ‐benzothiazepines : A minireview

(2020) Varsha Devi et al.   JOURNAL OF HETEROCYCLIC CHEMISTRY

Synthesis of Medium-Sized Heterocycles by Transition-Metal-Catalyzed Intramolecular Cyclization

(2020) Mickael Choury et al.   MOLECULES

Transition Metal-Catalyzed Tandem Reactions of Ynamides for Divergent N-Heterocycle Synthesis

(2020) Feng-Lin Hong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Z‐Selective  α‐Arylation of α,β‐Unsaturated Nitriles via [3,3]‐Sigmatropic Rearrangement

(2020) Mengyuan Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Medium-Sized Rings by Gold Catalysis

(2020) Ronald L. Reyes et al.   CHEMICAL REVIEWS

Chemoselective Alpha‐Deuteration of Amides Via Retro‐ene Reaction

(2020) Vincent Porte et al.   CHEMISTRY-A EUROPEAN JOURNAL

Exploiting Remarkable Reactivities of Ynamides: Opportunities in Designing Catalytic Enantioselective Reactions

(2020) Jian Luo et al.   ACS Catalysis

Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts

(2019) Daniel Kaiser et al.   CHEMICAL REVIEWS

Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement

(2019) Bo Zhou et al.   Nature Communications

Reversal of Regioselectivity in Ynamide Chemistry

(2019) Bo Zhou et al.   ACS Catalysis

Nickel-Catalyzed [5+2] Cycloaddition of 10π-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12π-Electron Nonaromatic Benzothiepines

(2019) Tasuku Inami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Conia-Ene-Type Carbocyclization of Ynamide Cyclohexanones: Regiodivergent Synthesis of Morphans and Normorphans

(2019) Yin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of Donor/Donor Copper Carbenes through Copper-Catalyzed Diyne Cyclization: Enantioselective and Divergent Synthesis of Chiral Polycyclic Pyrroles

(2019) Feng-Lin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Synthesis of Selenoesters by Oxyarylation of Selenoalkynes under Mild Conditions

(2018) Lucas L. Baldassari et al.   ORGANIC LETTERS

Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement

(2018) Dainis Kaldre et al.   SCIENCE

Synthesis of Benzimidazole-Fused Medium-Sized N,S -Heterocycles via Palladium-Catalyzed Cyclizations

(2018) Alexandra Basilio Lopes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Redox-Neutral α-Arylation of Alkyl Nitriles with Aryl Sulfoxides: A Rapid Electrophilic Rearrangement

(2017) Li Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Arylations of Vinyl Cation Intermediates

(2016) Daniel Kaiser et al.   ADVANCED SYNTHESIS & CATALYSIS

Brønsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes

(2016) Daniel Kaiser et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry

(2016) Minghao Feng et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Regioselective functionalisation of dibenzothiophenes through gold-catalysed intermolecular alkyne oxyarylation

(2015) Matthew J. Barrett et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Sulfone promoted Rh(iii)-catalyzed C–H activation and base assisted 1,5-H shift strategy for the construction of seven-membered rings

(2015) Dianpeng Chen et al.   Organic Chemistry Frontiers

A Brønsted Acid Catalyzed Redox Arylation

(2014) Bo Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ynamides in Ring Forming Transformations

(2013) Xiao-Na Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transfer of Sulfur: From Simple to Diverse

(2013) Hui Liu et al.   Chemistry-An Asian Journal

[3,3]-Sigmatropic Rearrangement versus Carbene Formation in Gold-Catalyzed Transformations of Alkynyl Aryl Sulfoxides: Mechanistic Studies and Expanded Reaction Scope

(2013) Biao Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective formation of medium-ring heterocycles of biological relevance by intramolecular cyclization

(2011) K. C. Majumdar   RSC Advances

Gold- or Platinum-Catalyzed Synthesis of Sulfur Heterocycles: Access to Sulfur Ylides without Using Sacrificial Functionality

(2009) Paul W. Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Intermolecular Oxyarylation of Alkynes: Unexpected Regiochemistry in the Alkylation of Arenes

(2009) Ana B. Cuenca et al.   ORGANIC LETTERS

1,5-Benzothiazepine, a versatile pharmacophore: A review

(2008) Jitender B. Bariwal et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY