Synthesis of Cyclopentenones with C4-Quaternary Stereocenters via Stereospecific [3,3]-Sigmatropic Rearrangement and Applications in Total Synthesis of Sesquiterpenoids

Navigating the Pauson–Khand Reaction in Total Syntheses of Complex Natural Products

(2021) Zhen Yang   ACCOUNTS OF CHEMICAL RESEARCH

Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones

(2021) Jan Bartáček et al.   Beilstein Journal of Organic Chemistry

A Concise Total Synthesis of (+)‐Waihoensene Guided by Quaternary Center Analysis

(2020) Cheng Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution of Pauson-Khand Reaction: Strategic Applications in Total Syntheses of Architecturally Complex Natural Products (2016–2020)

(2020) Sijia Chen et al.   Catalysts

Gold(I)-Catalyzed Synthesis of Highly Substituted 1,4-Dicarbonyl Derivatives via Sulfonium [3,3]-Sigmatropic Rearrangement

(2020) Weiping Zhou et al.   ORGANIC LETTERS

Brønsted Acid Catalyzed 1,2-Silyl Shift in Propargyl Silanes: Synthesis of Silyl Dienes and Silyl Indenes

(2019) Mikus Puriņš et al.   JOURNAL OF ORGANIC CHEMISTRY

Quaternary-centre-guided synthesis of complex polycyclic terpenes

(2019) Pengfei Hu et al.   NATURE

Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts

(2019) Daniel Kaiser et al.   CHEMICAL REVIEWS

Vinyl Cation Stabilization by Silicon Enables a Formal Metal-Free α-Arylation of Alkyl Ketones

(2019) Amandine Pons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent development of ortho -C–H functionalization of aryl sulfoxides through [3,3] sigmatropic rearrangement

(2018) Tomoyuki Yanagi et al.   TETRAHEDRON LETTERS

Formation of quaternary centres by copper catalysed asymmetric conjugate addition to β-substituted cyclopentenones with the aid of a quantitative structure–selectivity relationship

(2018) Ruchuta Ardkhean et al.   Chemical Science

Structures and Synthesis of Hitoyopodins: Bioactive Aromatic Sesquiterpenoids Produced by the Mushroom Coprinopsis cinerea

(2018) Junnosuke Otaka et al.   ORGANIC LETTERS

Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement

(2018) Dainis Kaldre et al.   SCIENCE

Nazarov reaction: current trends and recent advances in the synthesis of natural compounds and their analogs

(2017) Maxim G. Vinogradov et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective synthesis of C3 alkylated and arylated benzothiophenes

(2017) Harry J. Shrives et al.   Nature Communications

Redox-Neutral Arylations of Vinyl Cation Intermediates

(2016) Daniel Kaiser et al.   ADVANCED SYNTHESIS & CATALYSIS

C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks

(2016) Alexander P. Pulis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement

(2016) Yangbin Liu et al.   CHEMICAL COMMUNICATIONS

Synthesis of Chiral Cyclopentenones

(2016) Svilen P. Simeonov et al.   CHEMICAL REVIEWS

Metal-Free Approach to Biaryls from Phenols and Aryl Sulfoxides by Temporarily Sulfur-Tethered Regioselective C–H/C–H Coupling

(2016) Tomoyuki Yanagi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free CH–CH-Type Cross-Coupling of Arenes and Alkynes Directed by a Multifunctional Sulfoxide Group

(2016) José A. Fernández-Salas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

All-carbon quaternary centers in natural products and medicinal chemistry: recent advances

(2016) Taotao Ling et al.   TETRAHEDRON

Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products

(2016) Andrei V. Iosub et al.   ACS Catalysis

Sulfoxide-Directed Metal-Freeortho-Propargylation of Aromatics and Heteroaromatics

(2015) Andrew J. Eberhart et al.   CHEMISTRY-A EUROPEAN JOURNAL

Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements

(2014) Amanda C. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Brønsted Acid Catalyzed Redox Arylation

(2014) Bo Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective palladium catalyzed conjugate additions of ortho-substituted arylboronic acids to β,β-disubstituted cyclic enones: total synthesis of herbertenediol, enokipodin A and enokipodin B

(2014) Jeffrey Buter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Heck Reactions with Vinyl Sulfoxides, Sulfides and Sulfones

(2013) Daniel G. Bachmann et al.   ADVANCED SYNTHESIS & CATALYSIS

Nucleophilicortho-Propargylation of Aryl Sulfoxides: An Interrupted Pummerer/Allenyl Thio-Claisen Rearrangement Sequence

(2013) Andrew J. Eberhart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reagent Control of [1,2]-Wagner-Meerwein Shift Chemoselectivity Following the Nazarov Cyclization: Application to the Total Synthesis of Enokipodin B

(2013) David Lebœuf et al.   CHEMISTRY-A EUROPEAN JOURNAL

[3,3]-Sigmatropic Rearrangement versus Carbene Formation in Gold-Catalyzed Transformations of Alkynyl Aryl Sulfoxides: Mechanistic Studies and Expanded Reaction Scope

(2013) Biao Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Claisen Rearrangement of Enolphosphonates: Construction of Vicinal Tertiary and All-Carbon Quaternary Centers

(2012) Jiajing Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Allenyl Oxindoles and Spirooxindoles by a Catalytic Enantioselective Saucy-Marbet Claisen Rearrangement

(2012) Trung Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

(2012) Aditya L. Gottumukkala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters

(2011) Kotaro Kikushima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfoxide-Mediated α-Arylation of Carbonyl Compounds

(2011) Xueliang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NucleophilicOrthoAllylation of Aryl and Heteroaryl Sulfoxides

(2011) Andrew J. Eberhart et al.   ORGANIC LETTERS

Charge-Accelerated Sulfonium [3,3]-Sigmatropic Rearrangements

(2011) Nuno Maulide et al.   SYNTHESIS-STUTTGART

Beyond the Pummerer Reaction: Recent Developments in Thionium Ion Chemistry

(2010) Laura H. S. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of 2-(2,2,2-Trifluoroethylidene)-1,3-dithiane 1-Oxide with Ketones under Pummerer Conditions and Its Application to the Synthesis of 3-Trifluoromethyl-Substituted Five-Membered Heteroarenes

(2010) Takayuki Kobatake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

Enantioselective Catalysis of the Aza-Cope Rearrangement by a Chiral Supramolecular Assembly

(2009) Casey J. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Syntheses of Enokipodins A and B Utilizing Palladium-Catalyzed Addition of An Arylboronic Acid to An Allene

(2009) Masahiro Yoshida et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Intermolecular Oxyarylation of Alkynes: Unexpected Regiochemistry in the Alkylation of Arenes

(2009) Ana B. Cuenca et al.   ORGANIC LETTERS

2-(2,2,2-Trifluoroethylidene)-1,3-dithiane Monoxide as a Trifluoromethylketene Equivalent

(2009) Suguru Yoshida et al.   ORGANIC LETTERS

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones

(2008) Tricia L. May et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Total Synthesis of Clavirolide C. Applications of Cu-Catalyzed Asymmetric Conjugate Additions and Ru-Catalyzed Ring-Closing Metathesis

(2008) M. Kevin Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Claisen Rearrangements with a Hydrogen-Bond Donor Catalyst

(2008) Christopher Uyeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Meerwein−Eschenmoser Claisen Rearrangement: Asymmetric Synthesis of Allyl Oxindoles

(2008) Elizabeth C. Linton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY