Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement

Enantioselective Synthesis of Medium-Sized Lactams via Chiral α,β-Unsaturated Acylammonium Salts

(2018) Guowei Kang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic [1,3] O-to-C Rearrangement: Rapid Access to Bridged Bicyclic Systems

(2018) Jiantao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Photocatalytic Synthesis of Medium-Sized Lactams through C-C Bond Cleavage

(2018) Na Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Organocatalytic Four-Atom Ring Expansion of Cyclobutanones: Synthesis of Benzazocinones

(2018) Yirong Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis

(2017) Gwilherm Evano et al.   SYNTHESIS-STUTTGART

Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

(2017) Wen-Bo Shen et al.   Nature Communications

Reversal of Regioselectivity in Catalytic Arene-Ynamide Cyclization: Direct Synthesis of Valuable Azepino[4,5-b]indoles and β-Carbolines and DFT Calculations

(2017) Long Li et al.   ACS Catalysis

Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines

(2016) Wen-Bo Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Palladium-Catalyzed Carbonylation Approach to Eight-Membered Lactam Derivatives with Antitumor Activity

(2016) Raffaella Mancuso et al.   CHEMISTRY-A EUROPEAN JOURNAL

Flexible Tetrahydropyran Synthesis from Homopropargylic Alcohols Using Sequential Pd–Au Catalysis

(2016) Jungjoon Kim et al.   ORGANIC LETTERS

Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium-Ring Lactams

(2015) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement

(2015) Hongmiao Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines

(2015) Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition–Fragmentation Strategy

(2015) Megan H. Shaw et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of α-Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

(2015) Chao Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric synthesis and biological activities of natural product (+)-balasubramide and its derivatives

(2015) Jun Li et al.   NATURAL PRODUCT RESEARCH

Synthesis of Oxazocenones via Gold(I)-Catalyzed 8-Endo-Dig Hydroalkoxylation of Alkynamides

(2015) Stephen S. Scully et al.   ORGANIC LETTERS

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

(2015) Shangze Wu et al.   Chemical Science

Magical Chiral Spiro Ligands

(2015) Jianhua Xie et al.   ACTA CHIMICA SINICA

Gold-Catalyzed Carboalkoxylations of 2-Ethynylbenzyl Ethers to form 1- and 2-Indanones Chemoselectively: Effects of Ligands and Solvents

(2014) Chiou-Dong Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements

(2014) Amanda C. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

1,2-N-Migration in a Gold-Catalysed Synthesis of Functionalised Indenes by the 1,1-Carboalkoxylation of Ynamides

(2014) Holly V. Adcock et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diels–Alder Reactions of Allene with Benzene and Butadiene: Concerted, Stepwise, and Ambimodal Transition States

(2014) Hung V. Pham et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism and Selectivity of N-Triflylphosphoramide Catalyzed (3+ + 2) Cycloaddition between Hydrazones and Alkenes

(2014) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ynamides in Ring Forming Transformations

(2013) Xiao-Na Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Construction of Eight-Membered Carbocycles through Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers

(2013) Tomohiro Iwai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Concerted Nature of the Cyclization of Squalene Oxide to the Protosterol Cation

(2013) B. Andes Hess et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Ynamides to Highly Substituted Benzo[b]furans: Gold(I)-Catalyzed 5-endo-dig-Cyclization/Rearrangement of Alkylic Oxonium Intermediates

(2013) Maria Camila Blanco Jaimes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes

(2013) Weiwei Zi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition

(2013) Wanxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Eight-Membered Lactones: Intermolecular [6+2] Cyclization of Amphoteric Molecules with Siloxy Alkynes

(2012) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids

(2012) Ruth K. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodefined N,O-Acetals: Pd-Catalyzed Synthesis from Homopropargylic Amines and Utility in the Flexible Synthesis of 2,6-Substituted Piperidines

(2012) Haejin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

π-Acid Mediated Insertion of Alkynes into Carbon–Heteroatom σ-Bonds

(2012) Paul Davies et al.   SYNTHESIS-STUTTGART

Palladium-catalyzed intramolecular C–H amidation: synthesis and biological activities of indolobenzazocin-8-ones

(2012) Sasiwadee Boonya-udtayan et al.   TETRAHEDRON

Hidden Brønsted Acid Catalysis: Pathways of Accidental or Deliberate Generation of Triflic Acid from Metal Triflates

(2011) Tuan Thanh Dang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ynamides: Versatile Tools in Organic Synthesis

(2010) Gwilherm Evano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ynamides: A Modern Functional Group for the New Millennium

(2010) Kyle A. DeKorver et al.   CHEMICAL REVIEWS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Formal Alkyne Aza-Prins Cyclization: Gold(I)-Catalyzed Cycloisomerization of Mixed N,O-Acetals Generated from Homopropargylic Amines to Highly Substituted Piperidines

(2009) Cheoljae Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed [4+2+2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings

(2009) Robert T. Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Diphosphine and Monodentate Phosphorus Ligands on a Spiro Scaffold for Transition-Metal-Catalyzed Asymmetric Reactions

(2008) Jian-Hua Xie et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent excursions to the borderlands between the realms of concerted and stepwise: carbocation cascades in natural products biosynthesis

(2008) Dean J. Tantillo   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Sequence of Intramolecular Carbonylation and Asymmetric Hydrogenation Reactions: Highly Regio- and Enantioselective Synthesis of Medium Ring Tricyclic Lactams

(2008) Shui-Ming Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis

(2007) Christopher G. Nasveschuk et al.   ORGANIC & BIOMOLECULAR CHEMISTRY