How the electron-deficient Cp ligand facilitates Rh-catalyzed annulations with alkynes

The Pauli Repulsion-Lowering Concept in Catalysis

(2021) Trevor A. Hamlin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Origin of the α‐Effect in S N 2 Reactions

(2021) Thomas Hansen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How Lewis Acids Catalyze Diels-Alder Reactions

(2020) Pascal Vermeeren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Complexes in C–H Activation Reactions

(2020) Qun Zhao et al.   CHEMICAL REVIEWS

Rhodium‐Catalyzed Ortho‐Bromination of O‐Phenyl Carbamates Accelerated by a Secondary Amide‐Pendant Cyclopentadienyl Ligand

(2020) Jin Tanaka et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bonding Analysis of the Shortest Bond between Two Atoms Heavier than Hydrogen and Helium: O22+

(2020) Mingxing Fu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

(2020) Noam I. Saper et al.   Nature Chemistry

Understanding chemical reactivity using the activation strain model

(2020) Pascal Vermeeren et al.   Nature Protocols

Iridium(III) Catalysts with an Amide‐Pendant Cyclopentadienyl Ligand: Double Aromatic Homologation Reactions of Benzamides by Fourfold C−H Activation

(2020) Eiki Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral cyclopentadienyl ligands: design, syntheses and applications in asymmetric catalysis

(2020) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalyzed acid-assisted asymmetric hydrogenation of oximes to hydroxylamines

(2020) Josep Mas-Roselló et al.   SCIENCE

Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydroboration of Disubstituted Alkenes

(2020) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal-catalyzed C–H allylation reactions

(2020) Subhabrata Dutta et al.   Chem

Aerobic Oxidative Olefination of Benzamides with Styrenes Catalyzed by a Moderately Electron-Deficient CpRh(III) Complex with a Pendant Amide

(2019) Ryo Yoshimura et al.   JOURNAL OF ORGANIC CHEMISTRY

Oxidative Annulation of Acetanilides with Alkynes Catalyzed by Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides

(2019) Ryo Yoshimura et al.   Asian Journal of Organic Chemistry

How Dihalogens Catalyze Michael Addition Reactions

(2019) Trevor A. Hamlin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(III)-Catalyzed C–H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols

(2019) Erik J. T. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes

(2019) Honghui Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Energy Decomposition Analyses Reveal the Origins of Catalyst and Nucleophile Effects on Regioselectivity in Nucleopalladation of Alkenes

(2019) Xiaotian Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Lossen Rearrangement/Alkenylation or Annulation Cascade of Heterole Carboxamides with Alkynes Catalyzed by CpRhIII Complexes with Pendant Amides

(2019) Takayuki Yamada et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aerobic Oxidative Cross-Coupling of Substituted Acrylamides with Alkenes Catalyzed by an Electron-Deficient CpRhIII Complex

(2019) Ryo Yoshimura et al.   JOURNAL OF ORGANIC CHEMISTRY

Comparison of the Reactivities and Selectivities of Group 9 [Cp*MIII ] Catalysts in C−H Functionalization Reactions

(2018) Juhyeon Park et al.   Chemistry-An Asian Journal

Recent Advances in [Cp*MIII ] (M = Co, Rh, Ir)-Catalyzed Intramolecular Annulation Through C-H Activation

(2018) Augustin Peneau et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes

(2018) Weidong Lin et al.   ACS Catalysis

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Mechanistically Guided Design of Ligands that Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions

(2018) Andy A Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization

(2018) Tiffany Piou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Tandem [2+2+2] Annulation-Lactamization of Anilides with Two Alkynoates via Cleavage of Two Adjacent C−H or C−H/C−O bonds

(2016) Miho Fukui et al.   Chemistry-An Asian Journal

Defining the contributions of permanent electrostatics, Pauli repulsion, and dispersion in density functional theory calculations of intermolecular interaction energies

(2016) Paul R. Horn et al.   JOURNAL OF CHEMICAL PHYSICS

Assessing Ion–Water Interactions in the AMOEBA Force Field Using Energy Decomposition Analysis of Electronic Structure Calculations

(2016) Yuezhi Mao et al.   Journal of Chemical Theory and Computation

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroarene-Directed Oxidative sp2 C–H Bond Allylation with Aliphatic Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)rhodium(III) Complex

(2016) Yuji Takahama et al.   ORGANIC LETTERS

Probing non-covalent interactions with a second generation energy decomposition analysis using absolutely localized molecular orbitals

(2016) Paul R. Horn et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation

(2015) Fedor Romanov-Michailidis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

(2015) Tiffany Piou et al.   NATURE

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions

(2014) Yuki Hoshino et al.   ADVANCED SYNTHESIS & CATALYSIS

The Oxidative Annulation of Tertiary Benzyl Alcohols with Internal Alkynes using an (Electron-Deficient η5-Cyclopenta- dienyl)Rhodium(III) Catalyst under Ambient Conditions

(2014) Miho Fukui et al.   ADVANCED SYNTHESIS & CATALYSIS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

The activation strain model and molecular orbital theory: understanding and designing chemical reactions

(2014) Israel Fernández et al.   CHEMICAL SOCIETY REVIEWS

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances in molecular quantum chemistry contained in the Q-Chem 4 program package

(2014) Yihan Shao et al.   MOLECULAR PHYSICS

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Catalytic [2+2+1] Cross-Cyclotrimerization of Silylacetylenes and Two Alkynyl Esters To Produce Substituted Silylfulvenes

(2011) Yu Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis

(2011) Todd K. Hyster et al.   Chemical Science

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrophilic, Ambiphilic, and Nucleophilic C−H Bond Activation: Understanding the Electronic Continuum of C−H Bond Activation Through Transition-State and Reaction Pathway Interaction Energy Decompositions

(2010) Daniel H. Ess et al.   ORGANOMETALLICS

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH