Diastereodivergent Synthesis of Chiral α-Aminoketones via a Catalytic O–H Insertion/Barnes–Claisen Rearrangement Reaction

Synergistic Pd(0)/Rh(II) Dual Catalytic [6 + 3] Dipolar Cycloaddition for the Synthesis of Monocyclic Nine-Membered N,O-Heterocycles and Their Alder-ene Rearrangement to Fused Bicyclic Compounds

(2021) Kyu Ree Lee et al.   ORGANIC LETTERS

Copper and Rhodium Relay Catalysis for Selective Access to cis-2,3-Dihydroazepines

(2021) You Li et al.   ORGANIC LETTERS

Tandem Insertion/[1,3]-rearrangement: Highly Enantioselective Construction of α-Aminoketones

(2020) Yushuang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α‐(2‐Hydroxyphenyl)‐α‐Aminoketones by Rhodium‐Catalyzed Tandem Reaction of 1‐Sulfonyl‐1,2,3‐Triazoles and Benzoquinone‐Derived Alcohols

(2020) Zefeng Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Tandem Rh(II) and Chiral Squaramide Relay Catalysis: Enantioselective Synthesis of Dihydro-β-carbolines via Insertion to C–H Bond and Aza-Michael Reaction

(2019) Shanmugam Rajasekar et al.   ORGANIC LETTERS

Cyclization Reaction of 4-Acyl-1-sulfonyl-1,2,3-triazoles Possessing Phenyl Rings through Generation of Electron-Deficient Carbenoids

(2019) Qiang Zhao et al.   CHEMISTRY LETTERS

Rhodium(II)‐Catalyzed Intramolecular Transannulation of 4‐Methoxycyclohexa‐2,5‐dienone Tethered 1‐Sulfonyl‐1,2,3‐Triazoles: Synthesis of Azaspiro[5.5]undecane Derivatives

(2019) Cheng‐Zhi Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rh(II)-Catalyzed Denitrogenative Transannulation of N-Sulfonyl-1,2,3-triazolyl Cyclohexadienones for the Synthesis of Benzofurans and Cyclopropa[cd]indole-carbaldehydes

(2019) Geetanjali S. Sontakke et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers

(2019) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of [3a,7a]-Dihydroindoles by a Tandem Arene Cyclopropanation/3,5-Sigmatropic Rearrangement Reaction

(2018) Sidney M. Wilkerson-Hill et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones

(2018) Haifeng Zheng et al.   Nature Communications

Synthesis of Piperidine Derivatives by Rhodium- Catalyzed Tandem Reaction of N -Sulfonyl-1,2,3-Triazole and Vinyl Ether

(2018) Sisi Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemoselectivity Switching in the Rhodium-Catalyzed Reactions of 4-Substituted-1-sulfonyl-1,2,3-triazoles with Allenols: Noticeable Differences between 4-Acyl- and 4-Aryl-Triazoles

(2018) Pedro Almendros et al.   ADVANCED SYNTHESIS & CATALYSIS

Bimetallic Rhodium(II)/Indium(III) Relay Catalysis for Tandem Insertion/Asymmetric Claisen Rearrangement

(2018) Yushuang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 2-Substituted 2-Amino Ketones by Rhodium-Catalyzed Reaction ofN-Sulfonyl-1,2,3-triazoles with 2-Alkenols

(2017) Tomoya Miura et al.   HELVETICA CHIMICA ACTA

Recent Advances in the Synthesis of Heterocycles and Related Substances Based on α-Imino Rhodium Carbene Complexes Derived fromN-Sulfonyl-1,2,3-triazoles

(2016) Yu Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of α-methylene-δ-oxo-γ-amino esters via Rh(ii)-catalyzed coupling of 1-sulfonyl-1,2,3-triazoles with Morita–Baylis–Hillman adducts

(2016) Hyun Ji Jeon et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(II)/Mg(OtBu)2-Catalyzed Tandem One-Pot Synthesis of 1,4-Oxazepines and 1,4-Oxazines from N-Sulfonyl-1,2,3-triazoles and Glycidols

(2016) Young Ok Ko et al.   ORGANIC LETTERS

Synthesis of 5-Iodo-1,2,3,4-tetrahydropyridines by Rhodium-Catalyzed Tandem Nucleophilic Attacks Involving 1-Sulfonyl-1,2,3-triazoles and Iodides

(2016) Zengming Man et al.   ORGANIC LETTERS

Enantioselective Intermolecular C–H Functionalization of Allylic and Benzylic sp3 C–H Bonds Using N-Sulfonyl-1,2,3-triazoles

(2016) Robert W. Kubiak et al.   ORGANIC LETTERS

Tandem O–H Insertion/[1,3]-Alkyl Shift of Rhodium Azavinyl Carbenoids with Benzylic Alcohols: A Route To Convert C–OH Bonds into C–C Bonds

(2016) Pengbing Mi et al.   ORGANIC LETTERS

Synthesis of BenzofuransviaTandem Rhodium-Catalyzed C(sp3)H Insertion and Copper-Catalyzed Dehydrogenation

(2015) Lin Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(II) Azavinyl Carbenes and their Recent Application to Organic Synthesis

(2015) Samantha C. Hockey et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Cyclization of sulfide, ether or tertiary amine-tethered N-sulfonyl-1,2,3-triazoles: a facile synthetic protocol for 3-substituted isoquinolines or dihydroisoquinolines

(2015) Yu Jiang et al.   CHEMICAL COMMUNICATIONS

Synthesis of β-Amino-α,β-unsaturated Ketone Derivatives via Sequential Rhodium-Catalyzed Sulfur Ylide Formation/Rearrangement

(2015) Jun He et al.   JOURNAL OF ORGANIC CHEMISTRY

CuI/RhII-Catalyzed Tandem Convergent Multicomponent Reaction for the Regio- and Stereocontrolled Synthesis of γ-Oxo-β-amino Esters

(2015) Da Jung Jung et al.   ORGANIC LETTERS

Rhodium-Azavinylcarbene: A Versatile Synthon-Enabling Divergent Synthesis of Nitrogen Heterocycles

(2015) Yefeng Tang et al.   SYNLETT

Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles

(2014) Erica E. Schultz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Transannulation of NH-1,2,3-Triazoles with Olefins

(2014) Sen Wai Kwok et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles

(2014) Kai Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

(2014) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

One-Pot Synthesis of 2,5-Dihydropyrroles from Terminal Alkynes, Azides, and Propargylic Alcohols by Relay Actions of Copper, Rhodium, and Gold

(2014) Tomoya Miura et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Examination of the Scope and Stereochemistry of the Ireland-Claisen Rearrangement of Boron Ketene Acetals

(2014) Curtis A. Seizert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Claisen Rearrangement of Gosteli-Type Allyl Vinyl Ethers: Total Synthesis of (−)-9,10-Dihydroecklonialactone B

(2014) Julia Becker et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of trans-Cycloalkenes via Enantioselective Cyclopropanation and Skeletal Rearrangement

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(II)-Catalyzed Stereocontrolled Synthesis of 2-Tetrasubstituted Saturated Heterocycles from 1-Sulfonyl-1,2,3-triazoles

(2014) Alistair Boyer   ORGANIC LETTERS

Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and Indanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones

(2014) Hongjuan Shen et al.   ORGANIC LETTERS

Recent Advances in Transition-Metal-Catalyzed Denitrogenative Transformations­ of 1,2,3-Triazoles and Related Compounds

(2014) Pazhamalai Anbarasan et al.   SYNTHESIS-STUTTGART

Rhodium-Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4-Alkenyl-1-sulfonyl-1,2,3-triazoles with Dienes

(2013) Brendan T. Parr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes throughN-Sulfonyl-1,2,3-Triazole Intermediates

(2013) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Reactivity of Rhodium-Iminocarbenes Derived fromN-Sulfonyl Triazoles

(2013) Anton V. Gulevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Denitrogenative [2,3] Sigmatropic Rearrangement: An Efficient Entry to Sulfur-Containing Quaternary Centers

(2013) Dongari Yadagiri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aza-Belluš-Claisen Rearrangement-Enabled Synthesis of Racemic Tapentadol and Its Stereoisomers

(2013) Donghu Bai et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles

(2013) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Claisen Rearrangement of Aliphatic Allyl Vinyl Ethers from 1912 to 2012: 100 Years of Electrophilic Catalysis

(2013) Martin Hiersemann et al.   SYNTHESIS-STUTTGART

Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

(2012) Mikhail Zibinsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems

(2011) Buddhadeb Chattopadhyay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes

(2011) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Rhodium(II)N-Triflyl Azavinyl Carbenes

(2010) Neil Grimster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gosteli−Claisen Rearrangement: Substrate Synthesis, Simple Diastereoselectivity, and Kinetic Studies

(2009) Julia Rehbein et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles

(2009) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective bismuth triflate catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

(2008) Thierry Ollevier et al.   CANADIAN JOURNAL OF CHEMISTRY

Attempts To Improve the Overall Stereoselectivity of the Ireland−Claisen Rearrangement

(2008) Chi-Li Chen et al.   ORGANIC LETTERS