Ion Migration in Organic–Inorganic Hybrid Perovskite Solar Cells: Current Understanding and Perspectives

Halide Ion Migration in Perovskite Nanocrystals and Nanostructures

(2021) Prashant V. Kamat et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ion Migration Accelerated Reaction between Oxygen and Metal Halide Perovskites in Light and Its Suppression by Cesium Incorporation

(2021) Dongxu Lin et al.   Advanced Energy Materials

Grain Size Influences Activation Energy and Migration Pathways in MAPbBr3 Perovskite Solar Cells

(2021) Lucie McGovern et al.   Journal of Physical Chemistry Letters

Layer-by-layer anionic diffusion in two-dimensional halide perovskite vertical heterostructures

(2021) Akriti et al.   Nature Nanotechnology

Atomic-scale imaging of CH3NH3PbI3 structure and its decomposition pathway

(2021) Shulin Chen et al.   Nature Communications

Halide Engineering for Mitigating Ion Migration and Defect States in Hot-Cast Perovskite Solar Cells

(2021) Ritesh Kant Gupta et al.   ACS Sustainable Chemistry & Engineering

Cost-Effective High-Performance Charge-Carrier-Transport-Layer-Free Perovskite Solar Cells Achieved by Suppressing Ion Migration

(2021) Tao Ye et al.   ACS Energy Letters

Impedance Spectroscopy for Metal Halide Perovskite Single Crystals: Recent Advances, Challenges, and Solutions

(2021) Mohammad Adil Afroz et al.   ACS Energy Letters

Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes

(2021) Hanul Min et al.   NATURE

Is formamidinium (FA) always more stable than methylammonium (MA)?

(2020) Haotong Wei et al.   CHEMISTRY OF MATERIALS

Lattice‐Matching Structurally‐Stable 1D@3D Perovskites toward Highly Efficient and Stable Solar Cells

(2020) Peng Liu et al.   Advanced Energy Materials

Ion Migration‐Induced Amorphization and Phase Segregation as a Degradation Mechanism in Planar Perovskite Solar Cells

(2020) Diego Di Girolamo et al.   Advanced Energy Materials

First-Principles Study on the Oxygen–Light-Induced Iodide Vacancy Formation in FASnI3 Perovskite

(2020) Zhengxiang Li et al.   Journal of Physical Chemistry C

Suppressing Ion Migration across Perovskite Grain Boundaries by Polymer Additives

(2020) Yuhui Ma et al.   ADVANCED FUNCTIONAL MATERIALS

Revealing Electrical‐Poling‐Induced Polarization Potential in Hybrid Perovskite Photodetectors

(2020) Chuntao Lan et al.   ADVANCED MATERIALS

Interface charge accumulation dynamics in 3D and quasi-2D perovskite solar cells

(2020) Guilin Liu et al.   JOURNAL OF PHYSICS D-APPLIED PHYSICS

Lattice Compression Increases the Activation Barrier for Phase Segregation in Mixed-Halide Perovskites

(2020) Loreta A. Muscarella et al.   ACS Energy Letters

Discerning the Role of an A-Site Cation and X-Site Anion for Ion Conductivity Tuning in Hybrid Perovskites by Photoelectrochemical Impedance Spectroscopy

(2020) Priya Srivastava et al.   Journal of Physical Chemistry C

Influence of phenylethylammonium iodide as additive in the formamidinium tin iodide perovskite on interfacial characteristics and charge carrier dynamics

(2019) Jonas Horn et al.   APL Materials

Direct Evidence of Ion-Migration-Induced Degradation of Ultrabright Perovskite Light-Emitting Diodes

(2019) Hyunho Lee et al.   ACS Applied Materials & Interfaces

High‐Performance Solution‐Processed Organo‐Metal Halide Perovskite Unipolar Resistive Memory Devices in a Cross‐Bar Array Structure

(2019) Keehoon Kang et al.   ADVANCED MATERIALS

Verification and mitigation of ion migration in perovskite solar cells

(2019) Jin-Wook Lee et al.   APL Materials

Planar perovskite solar cells with long-term stability using ionic liquid additives

(2019) Sai Bai et al.   NATURE

Probe-induced resistive switching memory based on organic-inorganic lead halide perovskite materials

(2019) Abbas Shaban et al.   ORGANIC ELECTRONICS

Suppressed Ion Migration in Reduced-Dimensional Perovskites Improves Operating Stability

(2019) Ziru Huang et al.   ACS Energy Letters

Highly Stable and Efficient FASnI 3 ‐Based Perovskite Solar Cells by Introducing Hydrogen Bonding

(2019) Xiangyue Meng et al.   ADVANCED MATERIALS

Understanding the Improvement of Stability in Self-Assembled Multiple Quantum Wells Perovskite Light-Emitting Diode

(2019) Cheng Li et al.   Journal of Physical Chemistry Letters

The physics of ion migration in perovskite solar cells: Insights into hysteresis, device performance, and characterization

(2019) Dongchen Lan   PROGRESS IN PHOTOVOLTAICS

Suppressing the ions-induced degradation for operationally stable perovskite solar cells

(2019) Xiaodong Li et al.   Nano Energy

Grain Boundary Modification via F4TCNQ To Reduce Defects of Perovskite Solar Cells with Excellent Device Performance

(2018) Cong Liu et al.   ACS Applied Materials & Interfaces

Effect of Fullerene Passivation on the Charging and Discharging Behavior of Perovskite Solar Cells: Reduction of Bound Charges and Ion Accumulation

(2018) Yen-Chen Shih et al.   ACS Applied Materials & Interfaces

Interstitial Occupancy by Extrinsic Alkali Cations in Perovskites and Its Impact on Ion Migration

(2018) Jie Cao et al.   ADVANCED MATERIALS

Ion-Migration Inhibition by the Cation-π Interaction in Perovskite Materials for Efficient and Stable Perovskite Solar Cells

(2018) Dong Wei et al.   ADVANCED MATERIALS

Synergies of Electrochemical Metallization and Valance Change in All-Inorganic Perovskite Quantum Dots for Resistive Switching

(2018) Yan Wang et al.   ADVANCED MATERIALS

Grain-Boundary “Patches” by In Situ Conversion to Enhance Perovskite Solar Cells Stability

(2018) Lang Liu et al.   ADVANCED MATERIALS

How the formation of interfacial charge causes hysteresis in perovskite solar cells

(2018) Stefan A. L. Weber et al.   Energy & Environmental Science

Universal Approach toward Hysteresis-Free Perovskite Solar Cell via Defect Engineering

(2018) Dae-Yong Son et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Local Observation of Phase Segregation in Mixed-Halide Perovskite

(2018) Xiaofeng Tang et al.   NANO LETTERS

Maximizing and stabilizing luminescence from halide perovskites with potassium passivation

(2018) Mojtaba Abdi-Jalebi et al.   NATURE

Perovskite seeding growth of formamidinium-lead-iodide-based perovskites for efficient and stable solar cells

(2018) Yicheng Zhao et al.   Nature Communications

Inverted Current–Voltage Hysteresis in Perovskite Solar Cells

(2018) Fan Wu et al.   ACS Energy Letters

Impact of Surfaces on Photoinduced Halide Segregation in Mixed-Halide Perovskites

(2018) Rebecca A. Belisle et al.   ACS Energy Letters

Chemical sintering reduced grain boundary defects for stable planar perovskite solar cells

(2018) Jun Xi et al.   Nano Energy

Extrinsic ion migration in perovskite solar cells

(2017) Zhen Li et al.   Energy & Environmental Science

Pinning Down the Anomalous Light Soaking Effect toward High-Performance and Fast-Response Perovskite Solar Cells: The Ion-Migration-Induced Charge Accumulation

(2017) Teng Zhang et al.   Journal of Physical Chemistry Letters

Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites

(2017) Connor G. Bischak et al.   NANO LETTERS

Gold and iodine diffusion in large area perovskite solar cells under illumination

(2017) S. Cacovich et al.   Nanoscale

Microseconds, milliseconds and seconds: deconvoluting the dynamic behaviour of planar perovskite solar cells

(2017) Adam Pockett et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Diffusion engineering of ions and charge carriers for stable efficient perovskite solar cells

(2017) Enbing Bi et al.   Nature Communications

Dimensional Engineering of a Graded 3D-2D Halide Perovskite Interface Enables Ultrahigh V oc Enhanced Stability in the p-i-n Photovoltaics

(2017) Yang Bai et al.   Advanced Energy Materials

Profiling the organic cation-dependent degradation of organolead halide perovskite solar cells

(2017) Teng Zhang et al.   Journal of Materials Chemistry A

Improved carriers injection capacity in perovskite solar cells by introducing A-site interstitial defects

(2017) Pengjun Zhao et al.   Journal of Materials Chemistry A

Effects of organic cations on the defect physics of tin halide perovskites

(2017) Tingting Shi et al.   Journal of Materials Chemistry A

Vacancy dipole interactions and the correlation with monovalent cation dependent ion movement in lead halide perovskite solar cell materials

(2017) M. Pazoki et al.   Nano Energy

Light-Induced Anion Phase Segregation in Mixed Halide Perovskites

(2017) Michael C. Brennan et al.   ACS Energy Letters

Ion Migration Heals Trapping Centers in CH3NH3PbBr3 Perovskite

(2017) Supriya Ghosh et al.   ACS Energy Letters

Suppressed Ion Migration in Low-Dimensional Perovskites

(2017) Yun Lin et al.   ACS Energy Letters

Relationship between ion migration and interfacial degradation of CH3NH3PbI3 perovskite solar cells under thermal conditions

(2017) Seongtak Kim et al.   Scientific Reports

Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability

(2016) Yongbo Yuan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Flexible Hybrid Organic–Inorganic Perovskite Memory

(2016) Chungwan Gu et al.   ACS Nano

Not All That Glitters Is Gold: Metal-Migration-Induced Degradation in Perovskite Solar Cells

(2016) Konrad Domanski et al.   ACS Nano

Inhibition of Ion Migration for Reliable Operation of Organolead Halide Perovskite-Based Metal/Semiconductor/Metal Broadband Photodetectors

(2016) Ki Chang Kwon et al.   ADVANCED FUNCTIONAL MATERIALS

Iodine Migration and its Effect on Hysteresis in Perovskite Solar Cells

(2016) Cheng Li et al.   ADVANCED MATERIALS

Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells

(2016) Weijun Ke et al.   ADVANCED MATERIALS

π-Conjugated Lewis Base: Efficient Trap-Passivation and Charge-Extraction for Hybrid Perovskite Solar Cells

(2016) Yuze Lin et al.   ADVANCED MATERIALS

Fast Diffusion of Native Defects and Impurities in Perovskite Solar Cell Material CH3NH3PbI3

(2016) Dongwen Yang et al.   CHEMISTRY OF MATERIALS

Efficient n-type dopants with extremely low doping ratios for high performance inverted perovskite solar cells

(2016) Zhengyang Bin et al.   Energy & Environmental Science

Grain boundary dominated ion migration in polycrystalline organic–inorganic halide perovskite films

(2016) Yuchuan Shao et al.   Energy & Environmental Science

Interface-Dependent Ion Migration/Accumulation Controls Hysteresis in MAPbI3 Solar Cells

(2016) Igal Levine et al.   Journal of Physical Chemistry C

Spatially Non-uniform Trap State Densities in Solution-Processed Hybrid Perovskite Thin Films

(2016) Sergiu Draguta et al.   Journal of Physical Chemistry Letters

Iodine Migration and Degradation of Perovskite Solar Cells Enhanced by Metallic Electrodes

(2016) Cristina Besleaga et al.   Journal of Physical Chemistry Letters

Hysteresis, Stability, and Ion Migration in Lead Halide Perovskite Photovoltaics

(2016) Kenjiro Miyano et al.   Journal of Physical Chemistry Letters

Resistance random access memory

(2016) Ting-Chang Chang et al.   Materials Today

In Situ TEM Analysis of Organic–Inorganic Metal-Halide Perovskite Solar Cells under Electrical Bias

(2016) Quentin Jeangros et al.   NANO LETTERS

Direct–indirect character of the bandgap in methylammonium lead iodide perovskite

(2016) Eline M. Hutter et al.   NATURE MATERIALS

Ultrafast ion migration in hybrid perovskite polycrystalline thin films under light and suppression in single crystals

(2016) Jie Xing et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells

(2016) D. P. McMeekin et al.   SCIENCE

Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis

(2016) Philip Calado et al.   Nature Communications

Critical Role of Grain Boundaries for Ion Migration in Formamidinium and Methylammonium Lead Halide Perovskite Solar Cells

(2016) Jae S. Yun et al.   Advanced Energy Materials

Understanding the relationship between ion migration and the anomalous hysteresis in high-efficiency perovskite solar cells: A fresh perspective from halide substitution

(2016) Teng Zhang et al.   Nano Energy

In situ observation of heat-induced degradation of perovskite solar cells

(2016) G. Divitini et al.   Nature Energy

Working Principles of Perovskite Photodetectors: Analyzing the Interplay Between Photoconductivity and Voltage-Driven Energy-Level Alignment

(2015) Konrad Domanski et al.   ADVANCED FUNCTIONAL MATERIALS

Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges

(2015) Joseph Berry et al.   ADVANCED MATERIALS

Theory of Hydrogen Migration in Organic-Inorganic Halide Perovskites

(2015) David A. Egger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Significance of Ion Conduction in a Hybrid Organic-Inorganic Lead-Iodide-Based Perovskite Photosensitizer

(2015) Tae-Youl Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation

(2015) Jon M. Azpiroz et al.   Energy & Environmental Science

Understanding the rate-dependent J–V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field

(2015) W. Tress et al.   Energy & Environmental Science

Hysteresis-less inverted CH3NH3PbI3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency

(2015) Jin Hyuck Heo et al.   Energy & Environmental Science

Anomalously large interface charge in polarity-switchable photovoltaic devices: an indication of mobile ions in organic–inorganic halide perovskites

(2015) Yong Zhao et al.   Energy & Environmental Science

Characterization of Planar Lead Halide Perovskite Solar Cells by Impedance Spectroscopy, Open-Circuit Photovoltage Decay, and Intensity-Modulated Photovoltage/Photocurrent Spectroscopy

(2015) Adam Pockett et al.   Journal of Physical Chemistry C

Perovskite Solar Cells: Do We Know What We Do Not Know?

(2015) David A. Egger et al.   Journal of Physical Chemistry Letters

Modeling Anomalous Hysteresis in Perovskite Solar Cells

(2015) Stephan van Reenen et al.   Journal of Physical Chemistry Letters

First-Principles Study of Ion Diffusion in Perovskite Solar Cell Sensitizers

(2015) Jun Haruyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability

(2015) Monojit Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Photoluminescence Quantum Yield in Band Gap Tunable Bromide Containing Mixed Halide Perovskites

(2015) Carolin M. Sutter-Fella et al.   NANO LETTERS

Chloride Incorporation Process in CH3NH3PbI3–xClx Perovskites via Nanoscale Bandgap Maps

(2015) Jungseok Chae et al.   NANO LETTERS

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals

(2015) D. Shi et al.   SCIENCE

Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics

(2015) Eric T. Hoke et al.   Chemical Science

Enhancing grain boundary ionic conductivity in mixed ionic–electronic conductors

(2015) Ye Lin et al.   Nature Communications

Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells

(2015) Cheng Bi et al.   Nature Communications

Ionic transport in hybrid lead iodide perovskite solar cells

(2015) Christopher Eames et al.   Nature Communications

Ion Migration and the Role of Preconditioning Cycles in the Stabilization of the J -V Characteristics of Inverted Hybrid Perovskite Solar Cells

(2015) Michele De Bastiani et al.   Advanced Energy Materials

Mapping Electric Field-Induced Switchable Poling and Structural Degradation in Hybrid Lead Halide Perovskite Thin Films

(2015) Tomas Leijtens et al.   Advanced Energy Materials

Photovoltaic Switching Mechanism in Lateral Structure Hybrid Perovskite Solar Cells

(2015) Yongbo Yuan et al.   Advanced Energy Materials

Light-Induced Self-Poling Effect on Organometal Trihalide Perovskite Solar Cells for Increased Device Efficiency and Stability

(2015) Yehao Deng et al.   Advanced Energy Materials

Revealing Underlying Processes Involved in Light Soaking Effects and Hysteresis Phenomena in Perovskite Solar Cells

(2015) Chen Zhao et al.   Advanced Energy Materials

Silver Iodide Formation in Methyl Ammonium Lead Iodide Perovskite Solar Cells with Silver Top Electrodes

(2015) Yuichi Kato et al.   Advanced Materials Interfaces

Stabilized Wide Bandgap MAPbBrxI3-xPerovskite by Enhanced Grain Size and Improved Crystallinity

(2015) Miao Hu et al.   Advanced Science

Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber

(2014) Wan-Jian Yin et al.   APPLIED PHYSICS LETTERS

Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells

(2014) E. L. Unger et al.   Energy & Environmental Science

Hysteresis Analysis Based on the Ferroelectric Effect in Hybrid Perovskite Solar Cells

(2014) Jing Wei et al.   Journal of Physical Chemistry Letters

Anomalous Hysteresis in Perovskite Solar Cells

(2014) Henry J. Snaith et al.   Journal of Physical Chemistry Letters

Parameters Affecting I–V Hysteresis of CH3NH3PbI3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO2 Layer

(2014) Hui-Seon Kim et al.   Journal of Physical Chemistry Letters

Improved light absorption and charge transport for perovskite solar cells with rough interfaces by sequential deposition

(2014) Lingling Zheng et al.   Nanoscale

Giant switchable photovoltaic effect in organometal trihalide perovskite devices

(2014) Zhengguo Xiao et al.   NATURE MATERIALS

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells

(2014) Yuchuan Shao et al.   Nature Communications

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles

(2011) J. Suntivich et al.   SCIENCE