Understanding Halide Counterion Effects in Enantioselective Ruthenium-Catalyzed Carbonyl (α-Aryl)allylation: Alkynes as Latent Allenes and Trifluoroethanol-Enhanced Turnover in The Conversion of Ethanol to Higher Alcohols via Hydrogen Auto-transfer

Ethanol: Unlocking an Abundant Renewable C2‐Feedstock for Catalytic Enantioselective C‐C Coupling

(2021) Michael Joseph Krische et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Cycloadditions to Form Five-, Six-, and Seven-Membered Rings

(2021) Rosalie S. Doerksen et al.   CHEMICAL REVIEWS

Diastereo- and Enantioselective Ruthenium-Catalyzed C-C Coupling of 1-Arylpropynes and Alcohols: Alkynes as Chiral Allylmetal Precursors in Carbonyl anti-(α-Aryl)allylation

(2021) Ming Xiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

(2021) Catherine Gazolla Santana et al.   ACS Catalysis

Borrowing Hydrogen for Organic Synthesis

(2021) Benjamin G. Reed-Berendt et al.   ACS Central Science

Allenes and Dienes as Chiral Allylmetal Pronucleophiles in Catalytic Enantioselective C=X Addition: Historical Perspective and State‐of‐The‐Art Survey

(2021) Ming Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Ruthenium-BINAP-Catalyzed Carbonyl Reductive Coupling of Alkoxyallenes: Convergent Construction of syn-sec,tert-Diols via (Z)-σ-Allylmetal Intermediates

(2021) Ming Xiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room‐Temperature Guerbet Reaction with Unprecedented Catalytic Efficiency and Enantioselectivity

(2020) Teng Wei Ng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Control of Absolute Stereochemistry in Transition‐Metal‐Catalyzed Hydrogen Borrowing Reactions

(2020) Timothy Kwok et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper‐Catalyzed Borylative Couplings with C−N Electrophiles

(2020) Fabien J. T. Talbot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium Complex Catalyzed C2-Extension of Primary Alcohols with Ethanol via Hydrogen Autotransfer Reaction

(2020) Masaki Kobayashi et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Catalyzed Intermolecular Hydrofunctionalization of Allenes: Easy Access to Allylic Structures via the Selective Formation of C–N, C–C, and C–O Bonds

(2020) Rémi Blieck et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Synthesis of Cyclohexanes by Hydrogen Borrowing Annulations

(2019) Roly Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis

(2019) Rosalie S. Doerksen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols

(2019) Suhas Shahaji Gawali et al.   ACS Omega

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Catalytic nucleophilic ‘umpoled’ π-allyl reagents

(2018) Kim Spielmann et al.   CHEMICAL SOCIETY REVIEWS

Selection between Diastereomeric Kinetic vs Thermodynamic Carbonyl Binding Modes Enables Enantioselective Iridium-Catalyzed anti-(α-Aryl)allylation of Aqueous Fluoral Hydrate and Difluoroacetaldehyde Ethyl Hemiacetal

(2018) James M. Cabrera et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals

(2018) Benjamin G. Reed-Berendt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Biorefining of Ethanol from Wine Waste to Butanol and Higher Alcohols: Modeling the Life Cycle Assessment and Process Design

(2018) Rita Mazzoni et al.   ACS Sustainable Chemistry & Engineering

Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C–H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation

(2017) Michael Holmes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbonyl anti-(α-Amino)allylation via Ruthenium Catalyzed Hydrogen Autotransfer: Use of an Acetylenic Pyrrole as an Allylmetal Pronucleophile

(2017) Wandi Zhang et al.   ORGANIC LETTERS

Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates

(2017) Alexander P. Pulis et al.   Chemical Science

Hexafluoroisopropanol as a highly versatile solvent

(2017) Ignacio Colomer et al.   Nature Reviews Chemistry

Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges

(2016) Adrien Quintard et al.   CHEMICAL COMMUNICATIONS

Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxymethylation beyond Carbonylation: Enantioselective Iridium-Catalyzed Reductive Coupling of Formaldehyde with Allylic Acetates via Enantiotopic π-Facial Discrimination

(2016) Victoria J. Garza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Quaternary Stereocenters via Chromium Catalysis

(2016) Yang Xiong et al.   ORGANIC LETTERS

Homogeneous Ethanol to Butanol Catalysis—Guerbet Renewed

(2016) Hope Aitchison et al.   ACS Catalysis

A remarkable solvent effect of fluorinated alcohols on transition metal catalysed C–H functionalizations

(2016) J. Wencel-Delord et al.   Organic Chemistry Frontiers

Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination

(2015) Brannon Sam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

(2015) Qin Yang et al.   CHEMICAL SOCIETY REVIEWS

Bioethanol production from biomass: carbohydrate vs syngas fermentation

(2015) David Kennes et al.   JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY

Alkyne Hydroacylation: Switching Regioselectivity by Tandem Ruthenium Catalysis

(2015) Qing-An Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C–C Coupling of a Simple Propargyl Ether with Primary Alcohols: Enantioselective Homoaldol Addition via Redox-Triggered (Z)-Siloxyallylation

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

(2015) Matthew N. Grayson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent applications of chiral allenes in axial-to-central chirality transfer reactions

(2015) Robynne K. Neff et al.   TETRAHEDRON

Enhancement of stereoselectivities in asymmetric synthesis using fluorinated solvents, auxiliaries, and catalysts

(2015) Tsuyuka Sugiishi et al.   RSC Advances

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates

(2014) Zhuozhen Tan et al.   CHEMICAL COMMUNICATIONS

Cross-Metathesis/Isomerization/Allylboration Sequence for a Diastereoselective Synthesis ofAnti-Homoallylic Alcohols from Allylbenzene Derivatives and Aldehydes

(2014) Rémy Hemelaere et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition

(2014) Boyoung Y. Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates

(2014) Hua-Xing Huo et al.   Organic Chemistry Frontiers

NBO 6.0: Natural bond orbital analysis program

(2013) Eric D. Glendening et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Bond Order Analysis Based on the Laplacian of Electron Density in Fuzzy Overlap Space

(2013) Tian Lu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Enantioselective Synthesis of Anti Homoallylic Alcohols from Terminal Alkynes and Aldehydes Based on Concomitant Use of a Cationic Iridium Complex and a Chiral Phosphoric Acid

(2013) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF3-Bearing All-Carbon Quaternary Centers

(2013) Brannon Sam et al.   ORGANIC LETTERS

ωB97X-V: A 10-parameter, range-separated hybrid, generalized gradient approximation density functional with nonlocal correlation, designed by a survival-of-the-fittest strategy

(2013) Narbe Mardirossian et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Iridium-Catalyzed Synthesis of ω-Hydroxy Homoallylic Alcohols

(2013) Yasushi Obora et al.   SYNTHESIS-STUTTGART

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure influence of chiral 1,1′-biscarboline-N,N′-dioxide on the enantioselective allylation of aldehydes with allyltrichlorosilanes

(2012) Bing Bai et al.   TETRAHEDRON

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Nature and strength of C–H⋯O interactions involving formyl hydrogen atoms: computational and experimental studies of small aldehydes

(2011) Tejender S. Thakur et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Amplification of Anti-Diastereoselectivity via Curtin−Hammett Effects in Ruthenium-Catalyzed Hydrohydroxyalkylation of 1,1-Disubstituted Allenes: Diastereoselective Formation of All-Carbon Quaternary Centers

(2010) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenamide Hydro−Hydroxyalkylation: 1,2-Amino Alcohols via Ruthenium-Catalyzed Carbonylanti-Aminoallylation

(2010) Jason R. Zbieg et al.   ORGANIC LETTERS

Direct Ruthenium-Catalyzed C−C Coupling of Ethanol: Diene Hydro-hydroxyethylation To Form All-Carbon Quaternary Centers

(2010) Hoon Han et al.   ORGANIC LETTERS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

anti-Aminoallylation of Aldehydes via Ruthenium-Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols

(2009) Eduardas Skucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

(2009) Yasushi Obora et al.   ORGANIC LETTERS

Ruthenium Catalyzed C−C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes

(2008) Ming-Yu Ngai et al.   ORGANIC LETTERS