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Water-oxidizing complex in Photosystem II: Its structure and relation to manganese-oxide based catalysts

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Iron and manganese oxo complexes, oxo wall and beyond

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Cytochrome P450—The Wonderful Nanomachine Revealed through Dynamic Simulations of the Catalytic Cycle

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Direct Observation of Primary C-H Bond Oxidation by An Oxido-iron(IV) Porphyrin π-Radical Cation Complex in a Fluorinated Carbon Solvent

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Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond

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Bio-inspired Nonheme Iron Oxidation Catalysis. Growing Evidence for the Involvement of Oxoiron(V) Oxidants 
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Small Reorganization Energy for Ligand-Centered Electron-Transfer Reduction of Compound I to Compound II in a Heme Model Study

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Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C–H Bond Activation Reactions

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A High-Valent Manganese(IV)-Oxo-Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity

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Critical Factors in Determining the Heterolytic versus Homolytic Bond Cleavage of Terminal Oxidants by Iron(III) Porphyrin Complexes

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Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

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Mechanisms of Cytochrome P450-Catalyzed Oxidations

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A new look at the role of thiolate ligation in cytochrome P450

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60 years of dioxygen activation

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Tunneling Effect That Changes the Reaction Pathway from Epoxidation to Hydroxylation in the Oxidation of Cyclohexene by a Compound I Model of Cytochrome P450

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Characterization of a selenocysteine-ligated P450 compound I reveals direct link between electron donation and reactivity

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Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes

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O2 Activation by Non-Heme Iron Enzymes

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Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems

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Earth-Abundant Heterogeneous Water Oxidation Catalysts

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To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes

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Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes

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Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective

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Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

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Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

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Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry

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Molecular Designs for Controlling the Local Environments around Metal Ions

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A Balancing Act: Stability versus Reactivity of Mn(O) Complexes

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Manganese Catalyzed C–H Halogenation

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Molecular Catalysts for Water Oxidation

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Enthalpy–Entropy Compensation (EEC) Effect: A Revisit

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Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme RuIVO Complex

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Ferryl Protonation in Oxoiron(IV) Porphyrins and Its Role in Oxygen Transfer

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Significantly shorter Fe–S bond in cytochrome P450-I is consistent with greater reactivity relative to chloroperoxidase

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Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid

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Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

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Influence of Ligand Architecture on Oxidation Reactions by High-Valent Nonheme Manganese Oxo Complexes Using Water as a Source of Oxygen

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Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(v)–oxo complex

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Heme Enzyme Structure and Function

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Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen

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Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

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Temperature and Pressure Effects on C–H Abstraction Reactions Involving Compound I and II Mimics in Aqueous Solution

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Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

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Biological Water Oxidation

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Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex

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Valid entropy–enthalpy compensation: Fine mechanisms at microscopic level

(2013) E.B. Starikov   CHEMICAL PHYSICS LETTERS

Reactive Intermediates in Cytochrome P450 Catalysis

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A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions

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Mechanisms in manganese catalysed oxidation of alkenes with H2O2

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Correlating DFT-Calculated Energy Barriers to Experiments in Nonheme Octahedral FeIVO Species

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Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

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Electron-transfer properties of high-valent metal-oxo complexes

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Detection and Kinetic Characterization of a Highly Reactive Heme–Thiolate Peroxygenase Compound I

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Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes

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Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

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Spectroscopic observation of iodosylarene metalloporphyrin adducts and manganese(V)-oxo porphyrin species in a cytochrome P450 analogue

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The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

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Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

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Selective C–H oxidation catalyzed by metalloporphyrins

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Redox Potentials of Oxoiron(IV) Porphyrin π-Cation Radical Complexes: Participation of Electron Transfer Process in Oxygenation Reactions

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A Highly Reactive Mononuclear Non-Heme Manganese(IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes

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Water as an Oxygen Source: Synthesis, Characterization, and Reactivity Studies of a Mononuclear Nonheme Manganese(IV) Oxo Complex

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Highly efficient photocatalytic oxygenation reactions using water as an oxygen source

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Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

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Hydrogen-Atom Abstraction Reactions by Manganese(V)- and Manganese(IV)-Oxo Porphyrin Complexes in Aqueous Solution

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Effect of Porphyrin Ligands on the Regioselective Dehydrogenation versus Epoxidation of Olefins by Oxoiron(IV) Mimics of Cytochrome P450

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Mechanistic Insights into Hydride-Transfer and Electron-Transfer Reactions by a Manganese(IV)−Oxo Porphyrin Complex

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A Highly Reactive P450 Model Compound I

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Trends in Ground-State Entropies for Transition Metal Based Hydrogen Atom Transfer Reactions

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Laser Flash Photolysis Generation of High-Valent Transition Metal−Oxo Species: Insights from Kinetic Studies in Real Time

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Hydrogen Atom Abstraction and Hydride Transfer Reactions by Iron(IV)-Oxo Porphyrins

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Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

Versatility of biological non-heme Fe(II) centers in oxygen activation reactions

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