A High-Valent Manganese(IV)-Oxo-Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity

Activation of Metal Oxo and Nitrido Complexes by Lewis Acids

(2019) Yingying Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A High Spin Mn(IV)-Oxo Complex Generated via Stepwise Proton and Electron Transfer from Mn(III)–Hydroxo Precursor: Characterization and C–H Bond Cleavage Reactivity

(2019) Sachidulal Biswas et al.   INORGANIC CHEMISTRY

Detection of the site protected 7-coordinate RuV = O species and its chemical reactivity to enable catalytic water oxidation

(2019) Yuliana Pineda-Galvan et al.   JOURNAL OF CATALYSIS

Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C–H Bond Activation Reactions

(2019) Mian Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Isotope Effect Determination Probes the Spin of the Transition State, Its Stereochemistry, and Its Ligand Sphere in Hydrogen Abstraction Reactions of Oxoiron(IV) Complexes

(2018) Debasish Mandal et al.   ACCOUNTS OF CHEMICAL RESEARCH

NMR Studies of a MnIII-hydroxo Adduct Reveal an Equilibrium between MnIII-hydroxo and μ-Oxodimanganese(III,III) Species

(2018) Derek B. Rice et al.   INORGANIC CHEMISTRY

Model of the Oxygen Evolving Complex Which Is Highly Predisposed to O–O Bond Formation

(2018) Yulia Pushkar et al.   Journal of Physical Chemistry Letters

Hydrogen Atom Transfer Reactions of Mononuclear Nonheme Metal–Oxygen Intermediates

(2018) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C–H Bond Oxygenation

(2018) Michela Milan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

(2018) Jireh Joy D. Sacramento et al.   ACCOUNTS OF CHEMICAL RESEARCH

Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal Ions

(2018) Muniyandi Sankaralingam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

(2018) Muniyandi Sankaralingam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structures of the intermediates of Kok’s photosynthetic water oxidation clock

(2018) Jan Kern et al.   NATURE

Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions

(2018) Mian Guo et al.   ACS Central Science

A new look at the role of thiolate ligation in cytochrome P450

(2017) Timothy H. Yosca et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Light-induced structural changes and the site of O=O bond formation in PSII caught by XFEL

(2017) Michihiro Suga et al.   NATURE

Effects of Lewis Acids on Photoredox Catalysis

(2017) Shunichi Fukuzumi et al.   Asian Journal of Organic Chemistry

The O2-Evolving Complex of Photosystem II: Recent Insights from Quantum Mechanics/Molecular Mechanics (QM/MM), Extended X-ray Absorption Fine Structure (EXAFS), and Femtosecond X-ray Crystallography Data

(2016) Mikhail Askerka et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Ruthenium(III)-Oxyl Complex Bearing Strong Radical Character

(2016) Yoshihiro Shimoyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes

(2016) Xenia Engelmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures

(2016) Mohammad Mahdi Najafpour et al.   CHEMICAL REVIEWS

High-Valent Manganese–Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C–H Bond Cleavage

(2016) Regina A. Baglia et al.   INORGANIC CHEMISTRY

The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe–O–M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers

(2016) Ang Zhou et al.   INORGANIC CHEMISTRY

A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion

(2016) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

(2015) Wonwoo Nam   ACCOUNTS OF CHEMICAL RESEARCH

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

(2015) Mayank Puri et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry

(2015) Karin J. Young et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Structure of Photosystem II and the Mechanism of Water Oxidation in Photosynthesis

(2015) Jian-Ren Shen   Annual Review of Plant Biology

Molecular Catalysts for Water Oxidation

(2015) James D. Blakemore et al.   CHEMICAL REVIEWS

Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates

(2015) Shunichi Fukuzumi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structure of the Oxygen Evolving Complex of Photosystem II at Room Temperature

(2015) Katherine M. Davis et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Spectroscopic Identification of an FeIII Center, not FeIV, in the Crystalline Sc–O–Fe Adduct Derived from [FeIV(O)(TMC)]2+

(2015) Jai Prakash et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation

(2015) Zoel Codolà et al.   Nature Communications

Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

(2014) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions

(2014) Seungwoo Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heme Enzyme Structure and Function

(2014) Thomas L. Poulos   CHEMICAL REVIEWS

Mn4Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen

(2014) Junko Yano et al.   CHEMICAL REVIEWS

Unified View of Oxidative C–H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)–Oxo Complex via Lewis Acid-Promoted Electron Transfer

(2014) Jiyun Park et al.   INORGANIC CHEMISTRY

Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen

(2014) Gayan B. Wijeratne et al.   INORGANIC CHEMISTRY

Native structure of photosystem II at 1.95 Å resolution viewed by femtosecond X-ray pulses

(2014) Michihiro Suga et al.   NATURE

Cerium(IV)-driven oxidation of water catalyzed by mononuclear ruthenium complexes

(2014) Masaki Yoshida et al.   RESEARCH ON CHEMICAL INTERMEDIATES

A change in the oxidation state of iron: scandium is not innocent

(2013) Marcel Swart   CHEMICAL COMMUNICATIONS

Enhanced Electron-Transfer Reactivity of Nonheme Manganese(IV)–Oxo Complexes by Binding Scandium Ions

(2013) Heejung Yoon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions

(2013) Junying Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals

(2013) David E. Herbert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

Valence Tautomerism in a High-Valent Manganese–Oxo Porphyrinoid Complex Induced by a Lewis Acid

(2012) Pannee Leeladee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex

(2011) Jiyun Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient water oxidation catalysts based on readily available iron coordination complexes

(2011) Julio Lloret Fillol et al.   Nature Chemistry

An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions

(2010) Florian Felix Pfaff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Water as an Oxygen Source: Synthesis, Characterization, and Reactivity Studies of a Mononuclear Nonheme Manganese(IV) Oxo Complex

(2010) Sarvesh C. Sawant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+

(2010) Yuma Morimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer

(2010) Shunichi Fukuzumi et al.   Nature Chemistry

Water as an Oxygen Source in the Generation of Mononuclear Nonheme Iron(IV) Oxo Complexes

(2009) Yong-Min Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fundamental Electron-Transfer Properties of Non-heme Oxoiron(IV) Complexes

(2007) Yong-Min Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY