Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes

Proton-Coupled Electron Transfer Guidelines, Fair and Square

(2021) Robin Tyburski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Tailoring Toward an Air-Stable Iron(V) Nitrido Complex

(2021) Martin Keilwerth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and Reactivity of a Manganese(VI) Nitrido Complex Bearing a Tetraamido Macrocyclic Ligand

(2021) Huatian Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Semiempirical method for examining asynchronicity in metal–oxido-mediated C–H bond activation

(2021) Suman K. Barman et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Electric Fields in Catalysis: From Enzymes to Molecular Catalysts

(2021) Nadia G. Léonard et al.   ACS Catalysis

Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications

(2021) Rishi G. Agarwal et al.   CHEMICAL REVIEWS

Strategies for switching the mechanism of proton-coupled electron transfer reactions illustrated by mechanistic zone diagrams

(2021) Robin Tyburski et al.   Chemical Science

C−H bond activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex

(2020) Alexander Reckziegel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Relating N-H Bond Strengths to the Overpotential for Catalytic Nitrogen Fixation

(2020) Matthew J. Chalkley et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Isolation of a Bimetallic Cobalt(III) Nitride and Examination of Its Hydrogen Atom Abstraction Chemistry and Reactivity toward H2

(2020) Debabrata Sengupta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of a Manganese(V) Nitride to Ammonia

(2020) Sangmin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electric-Field Mediated Chemistry: Uncovering and Exploiting the Potential of (Oriented) Electric Fields to Exert Chemical Catalysis and Reaction Control

(2020) Sason Shaik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron and manganese oxo complexes, oxo wall and beyond

(2020) Virginia A. Larson et al.   Nature Reviews Chemistry

Oxidation of Ammonia with Molecular Complexes

(2020) Peter L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer

(2019) Dian Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Metal Oxo and Nitrido Complexes by Lewis Acids

(2019) Yingying Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for pKa-Driven Asynchronicity in C–H Activation by a Terminal Co(III)–Oxo Complex

(2019) McKenna K. Goetz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regulating the Basicity of Metal–Oxido Complexes with a Single Hydrogen Bond and Its Effect on C–H Bond Cleavage

(2019) Suman K. Barman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Appended S-Block Metal Ion Crown Ethers on Redox Properties and Catalytic Activity of Mn–Nitride Schiff Base Complexes: Methane Activation

(2019) Ahmad Najafian et al.   INORGANIC CHEMISTRY

An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state

(2018) Markus Kinauer et al.   Chemical Science

A Continuum of Proton-Coupled Electron Transfer Reactivity

(2018) Julia W. Darcy et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cationic Charges Lead to Inverse Free Energy Relationship for N-N Bond Formation by Mn(VI) Nitrides

(2018) Teera Chantarojsiri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH]2+) Unit

(2018) Debanjan Dhar et al.   INORGANIC CHEMISTRY

Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes

(2018) Jireh Joy D. Sacramento et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fast Hydrogen Atom Abstraction by a Hydroxo Iron(III) Porphyrazine

(2017) Hongxin Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe–N2 and Fe–CN Reductions

(2017) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Electronic Structure To Control Manganese Nitride Activation

(2016) Ryan M. Clarke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Proton Coupled Electron Transfer from Metal Hydrides to Titanocene Amides, Hydrazides and Imides: Determination of Thermodynamic Parameters Relevant to Nitrogen Fixation

(2016) Iraklis Pappas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry

(2016) Diana A. Iovan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oriented electric fields as future smart reagents in chemistry

(2016) Sason Shaik et al.   Nature Chemistry

Stepwise N–H bond formation from N2-derived iron nitride, imide and amide intermediates to ammonia

(2016) K. Cory MacLeod et al.   Chemical Science

Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

(2015) Markus G. Scheibel et al.   INORGANIC CHEMISTRY

Proton-Coupled Electron Transfer: Moving Together and Charging Forward

(2015) Sharon Hammes-Schiffer   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of Nitrido Complexes of Ruthenium(VI), Osmium(VI), and Manganese(V) Bearing Schiff Base and Simple Anionic Ligands

(2013) Wai-Lun Man et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450

(2013) T. H. Yosca et al.   SCIENCE

Re-Evaluation of the Proton Affinity of 18-Crown-6 Using Competitive Threshold Collision-Induced Dissociation Techniques

(2012) Yu Chen et al.   ANALYTICAL CHEMISTRY

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

C–H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product

(2010) Ryan E. Cowley et al.   INORGANICA CHIMICA ACTA

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Intramolecular C−H Activation by Putative Terminal Two-Coordinate Manganese(III) Imido Intermediates: Hydrogen Abstraction from a Phenyl Group

(2009) Chengbao Ni et al.   ORGANOMETALLICS

Thermodynamics of Hydrogen Atom Transfer to a High-Valent Iron Imido Complex

(2008) Ismael Nieto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY